Digital Commons Network^™

Phenol Deoxygenation Over Hydrotreating Catalysts, Madelyn R B Ball

Honors Theses and Capstones

Phenol deoxygenation has been investigated as a model reaction for the deoxygenation of fatty acid methyl esters in biodiesel. Hydrodeoxygenated biodiesel is a drop-in fuel for petroleum diesel, and is a premium diesel with a high cetane number. As the first step in this research, two molybdenum catalysts were prepared, characterized and tested in a small-scale reactor. These catalysts were found to produce small amounts of benzene and cyclohexanol in the product stream, and confirmed the activity of the catalyst. A commercial cobalt molybdenum catalyst (Harshaw HT-400) was also tested and benzene, cyclohexanol, and cyclohexane were identified as products. Future …

Bioremediation Of Hydrocarbons Via Geobacillus, Amanda T. Lade

Honors Theses and Capstones

Hydrocarbon remediation is a vital aspect of environmental cleanup, especially in soil and groundwater to ensure the health and safety of the public’s drinking water. A possible solution to this contamination is bioremediation, the use of microorganisms to degrade pollutants. This research analyzes the effectiveness of Geobacillus as a hydrocarbon degrader for the use of bioremediation. Twelve strains were identified from oil-contaminated sources and grown in minimal media with crude oil as the carbon source. Growth was observed in the crude oil samples, demonstrating the possibility of bioremediation of hydrocarbons via Geobacillus.

Developing Genetic Tools For Geobacillus, Brittany Artale

Honors Theses and Capstones

Bacillus and Geobacillus are the primary bacterium used in biotechnology industries due to their ability to excrete extracellular materials such as proteins, enzymes and other byproducts. Bacillus subtilis, has a well-characterized competence machinery, giving way to characterized genetic tools. However, a significant problem associated with working with Bacillus is the regulation of endospore formation. An alternative to Bacillus is Geobacillus, a thermophilic bacterium. Thermophiles offer significant advantages over other bacteria as host organisms in biofuel, bioremediation, and biocatalyst processes. However, the genetic tools and competency associated with Geobacillus is still unknown. Through, genetic engineering the ability …

Forcing Mutual Coherence In Diode Laser Stacks, Jonathan R. Wurtz

Honors Theses and Capstones

This paper will discuss both theoretical and experimental attempts to improve the spatial beam quality of diode laser stacks using an external optical system. An overview and derivation of the mathematics of both the optical system and diode lasers will be discussed. The experimental setup will be presented, as well as the fundamental theoretical and experimental results that suggest the external optical system used for this thesis fails to improve the beam quality of a diode laser stack.

Computationally Efficient Representation Of Statistically Described Material Microstructure For Tractable Forming Simulations, Nicholas Landry

Honors Theses and Capstones

The purpose of this project is to reduce a large statistical distribution of metal microstructure orientations to a manageable distribution to be used in metal forming simulations. Microstructure sensitive simulations at the macro-scale are impractical, because with so many state variables associated with material microstructure data, these simulations are extremely computationally expensive.

The goal was to develop a framework to accurately model plastic material response while representing the material microstructure in a more compact form, reducing 106 or more microstructure orientations to a significantly smaller statistical distribution of representative orientations. This will significantly increase the computational efficiency and make the …

How Teacher Beliefs About Mathematics Affect Student Beliefs About Mathematics, Kelly Smith

Honors Theses and Capstones

No abstract provided.

Dynamic Testing Procedures For Performance Assessment Of Nuclear Fuel Rods, Travis M. Adams

Honors Theses and Capstones

Existing transportation probabilistic risk assessment for spent nuclear fuel in the United States is based on short-term (decades) on-site storage at power plants before transport. Updated risk assessment estimates will be required as extended on-site storage (centuries) and higher burnup levels in fuel become standard. Nuclear fuel rods under these two conditions are more brittle than rods from short-term storage and intermediate burnup due to several mechanisms, including hydrogen embrittlement. Development of risk assessment requires characterizations of dynamic behavior of these degraded rods under transportation scenarios. This Honors thesis provides an initial literature review for a larger project that will …

Re-Analysis Of The World Data On The Emc Effect And Extrapolation To Nuclear Matter, Stacy E. Karthas

Honors Theses and Capstones

The EMC effect has been investigated by physicists over the past 30 years since it was discovered at CERN. This effect shows that the internal nucleon structure varies when in the nuclear medium. Data from SLAC E139 and JLab E03 103 were studied with the Coulomb correction and directly compared. The Coulomb distortion had a greater impact on the JLab data due to slightly lower energies and different kinematics. The EMC ratio was found to have a dependence on a kinematic variable, which was removed when Coulomb corrections were applied. The methodology was developed to apply Coulomb corrections, which had …

The Goddard Project, Cassandra Denunzio, Robert Galli, Cameron Perl, Andrew Felicetti, Samuel Cordeiro, Kevin Tierney

Honors Theses and Capstones

The goal of this project was to design and build a robotic dog modeled after Goddard from the 2001 television series, The Adventures of Jimmy Neutron Boy Genius. Sheet metal was used for the body of the robot in order to keep the frame lightweight. Goddard travels on two wheels powered by electric motors and two caster wheels. The robot utilizes a Raspberry Pi as its master device and an Arduino Uno in order to control the robot. Essentially, Goddard acts and behaves like an ordinary dog from barking, to moving around, to being a great companion and friend. …

Pile-Soil Interaction In Unsaturated Soil Conditions, Megan Hamilton

Honors Theses and Capstones

The degree of saturation has been proven to significantly affect geotechnical engineering designs for foundations. The changes in water content will influence the way the soil behaves, including its strength and stiffness parameters. These characteristics were analyzed for a uniform silty sand by developing P-Y curves, which relate lateral loading to lateral deformations. These P-Y curves were input into FB-Multipier, a software developed by the Bridge Software Institute. The software is capable of generating deformations as a result of user-defined loading cases. The results indicated that the middle range of degrees of saturation produced the least amount of deformation. This …

Sensitivity Analysis Of A Proposed Model For Removal Efficiency Of Trihalomethanes (Thms) Using Spray Aeration, Aidan Cecchetti

Honors Theses and Capstones

Trihalomethanes (THMs) form in drinking water treatment systems as a byproduct of chlorination and are problematic from a public health perspective due to their carcinogenic potential and their potential for additional formation throughout distribution systems. Recently, regulations have tightened on THMs in an attempt to reduce the risk of exposure for consumers at the far ends of distribution systems. Due to widespread use of chlorine and the reluctance of drinking water providers to overhaul current treatment systems, research has been undertaken to investigate post-treatment removal of THMs. One such method is spray aeration, whereby water is recycled in water storage …

Married Coal Gasification And Biomass Pyrolysis, Michael Balch

Honors Theses and Capstones

This project is a proposal to marry a coal gasification process to a biomass pyrolysis. Coal is pyrolized to produce syngas and a large amount of heat. The syngas is treated and fed to a Fischer-Tropsch process. The excess heat produces steam that is used to pyrolize biomass. The biomass produces char, gas, and vapor. The char and gas are recovered, and the vapor is condensed to produce bio-oil.

The proposed plant has a capacity of 1100 tons of biomass (550 dry tons) per day. I assumed an operating factor of 0.9 The plant could be operational within five years, …

Chosen Multiplication Algorithms And The Ability To Learn New Methods, Catherine A. Tarushka

Honors Theses and Capstones

No abstract provided.

A Statistical Analysis Of Electromagnetic Ion Cyclotron (Emic) Waves And Their Correlation To The 11-Year Solar Cycle, Erik A. Lindgren

Honors Theses and Capstones

This thesis presents a statistical analysis of EMIC waves measured at Halley Research Station from 2008 through 2012. An introduction covering the origin of and theory behind EMIC waves is provided, along with a background covering previous statistical research regarding EMIC waves. Guidelines regarding EMIC wave definition and analysis are described along with examples of how they were used. The data shows an increase in the total number of EMIC waves as well as the number and percentage of EMIC waves with maximum frequency above 1 Hz during the 5-year period. The results suggest that the total number of EMIC …

Kinetics Of Lipid Extraction From Microalgae, Brian Mcconnell

Honors Theses and Capstones

No abstract provided.

Cycling Of Molecular Hydrogen In Subarctic Sweden, Victoria Ward

Honors Theses and Capstones

No abstract provided.

Comparison Of Biomass To Bio-Oils Reactor Systems: Direct Conversion Vs. Companion Coal Gasification, Alexandra Eicher

Honors Theses and Capstones

It is well known that the United States’ dependence on crude-oil negatively affects its economy, safety, and environment. To alleviate these negative consequences, a more economical and environmentally-friendly source of fuel, such as biomass, should be explored. The conversion of biomass to bio-oils involves the pyrolysis of biomass at about 500°C, thus requiring a great deal of heat. This heat source could be the excess waste heat from a coal gasifier.

As such, this report specifies the design of an industrial plant that produces bio-oils from biomass by using the waste heat from a coal gasifier. It is designed to …

Nasa Magnetospheric Multiscale Mission Tablesat 1c, Joshua Chabot, Joseph Kelley, Michael Johnson

Honors Theses and Capstones

The NASA Magnetospheric MultiScale (MMS) mission (to be launched in 2014) consists of four spin-stabilized spacecraft flying in precise formation. The MMS spacecraft, which have wire booms up to 60 m long, are analyzed using the UNH MMS TableSat IC, a limited 3-DOF rotation (full spin, limited nutation) table top prototype of the MMS spacecraft. A PID controller is implemented on TableSat IC to observe the effects of spin rate and nutation control on the experimental satellite bus and scaled booms. Nutation and spin are implemented independently and the behavior of the test bed with and without SDP booms is …

Octanol/Water Partitioning Coefficients Of Pcb Mixtures For Environmental Fate And Transport, Phylicia Cicilio

Honors Theses and Capstones

Polychlorinated biphenyls (PCBs) are a human and environmental toxin introduced to the environment from the 1920’s to the 1970’s from manufacturing items such as transformers and capacitors. PCBs remain in the environment today due to their low water solubility and resistance to chemical reaction. Due to their properties PCBs bioaccumulate in the environment and pose health risks to animals and humans, as they are deemed a probable carcinogen by the EPA. Octanol-water partitioning coefficients are a means of measuring how PCBs will travel in the environment, either partitioning to water or into organic carbon. Octanol-water partitioning coefficients will be determined …

Analysis Of Shear Lag In Steel Angle Connectors, Benjamin Sawyer

Honors Theses and Capstones

Previous research has found an empirically based method for calculating the effective net area defined by stress distributions created by tensile loads in steel connections. Based on the results from that method a theoretical alternative is explored to simplify the process of determining the effective net area.

Wireless Water Flow Meter Network In The Great Bay, Braden S. Blanchette

Honors Theses and Capstones

The Oyster Restoration Program alongside the New Hampshire chapter of the Nature Conservancy is working towards developing new oyster beds throughout the Great Bay. Sedimentation is proving to be a vast problem by covering up the beds before they have a chance to grow to a healthy level. The many rivers entering the Great Bay are bringing the sediments from all over the region and limiting the ability of the program to develop the new beds. They need a way to measure the sedimentation rate, by measuring the flow rate of the rivers over a single tidal cycle in various …

Customer Age As A Predictor Of Contact Volume, Tollan Renner

Honors Theses and Capstones

A two stage modeling approach for modeling customer age as a predictor of contact volume was conducted using a real-world data set of approximately 2,000,000 contacts from a company call center. Two models were constructed in the first stage, one a straightforward regression and the other a series of regressions. One was selected as better performing and scaled up to predict calls received from calls answered. The second stage of the modeling included a day of the week covariate and performed the best of the models created. This model uses age bins as model effects, of which the youngest age …

Definitions In Mathematics: What Do High School Students Know?, Julianne Sacco

Honors Theses and Capstones

No abstract provided.

An Analysis Of Differences In Approaches To Systems Of Linear Equations Problems Given Multiple Choice Answers, Amber Lagasse

Honors Theses and Capstones

This descriptive study focuses on the approaches college students (ages 20 -24) use when solving systems of linear equations problems that have multiple choice answers. Participants were from a midsize public university in the northeast. Four approaches were considered – three forwards approaches: 1) substitution, 2) elimination, and 3) graphing, and one backwards approach: plugging in the x and y values from each multiple choice option. Participants solved systems of linear equations problems and answered questions based on their methods in a structured clinical interview. Each participant also filled out a questionnaire. It was shown from the results of this …

Characterizing Electrons In Primary And Secondary Magnetic Islands During Magnetic Reconnection, Jason Shuster

Honors Theses and Capstones

The physics underlying particle-in-cell simulations that are widely employed in studying plasma dynamics are reviewed. Results from a two-dimensional particle-in-cell simulation of fully kinetic, undriven, collisionless magnetic reconnection are studied to compare the electrons in a primary magnetic island formed from an ion current sheet and the electrons in a secondary island formed in an electron current layer. We find that the secondary island is born with a strong out-of-plane current density due to localized peaks in the electron density and out-of-plane electron velocity; the secondary island retains these features as it evolves, distinguishing it from the primary island. For …

Investigation Of New Hampshire Hydropower Potential, Maxwell Murray

Honors Theses and Capstones

The popularity of green and renewable energy has risen sharply in recent years, and hydropower has consistently been the most common form of renewable energy in both the US and the state of New Hampshire. As a result of this strong green movement, government organizations have seen increased pressure to produce figures to the public detailing the amount of hydropower potentially available in the country. Often these figures will depict very attractive numbers for the untapped hydropower potential in the country, yet the data do not seem realistic to anyone familiar with hydropower generation. This paper will attempt to de-rate …

The Analysis Of Ion Flow Between The Human Body And Local Ground, Paul T. Rioux

Honors Theses and Capstones

The project was designed to get a better sense of the phenomenon referred to as Earthing. Earthing is defined as the process where the human body is in contact with the earth and can freely transfer ions between the Earth and itself. Those promoting the idea of earthing say that this transfer of ions is important in maintaining a healthy immune system, and they claim that the recent increase in autoimmune diseases is the result of humans being insulated from the ground because of the shoes they wear and the places in which they live.

Arched Bridges, Lily Beyer

Honors Theses and Capstones

An exploration of arched bridges through history. Influence lines for three-pinned and two-pinned arches for moment and axial load are developed. An analysis of the Chesterfield Brattleboro Bridge is included

Software Engineering For The Mobile Application Market, Jacob Schwartz

Honors Theses and Capstones

One of the goals of the current United States government is to lower healthcare costs. One of the solutions is to alter the behavior of the population to be more physically active and to eat healthier. This project will focus on the latter solution by writing applications for the Android and iOS mobile platforms that will allow a user to monitor their dietary intake to see and correct patterns in their eating behavior.

Phosphate Availability During Sediment Resuspension Events In The Great Bay Estuary, Taylor Langkau

Honors Theses and Capstones

Phosphate is an important nutrient to marine ecosystems such as the Great Bay Estuary. However, its bioavailability is limited due to its tendency to adsorb to marine sediments, especially iron oxides. This paper investigates phosphate dynamics during a simulated storm compared to calm conditions and aims to quantify the mechanisms of phosphate adsorption.