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Exploring Energy, Comfort, And Building Health Impacts Of Deep Setback And Normal Occupancy Smart Thermostat Implementation, Zachary Ethan Alderman Dec 2017

Exploring Energy, Comfort, And Building Health Impacts Of Deep Setback And Normal Occupancy Smart Thermostat Implementation, Zachary Ethan Alderman

Graduate Theses and Dissertations

As smart thermostat adoption rates continue to increase, it becomes worthwhile to explore what unanticipated outcomes may result in their use. Specific attention was paid to smart thermostat impacts to deep setback and normal occupancy states in a variety of conditions while complying with the ventilation and temperature requirements of ASHRAE 90.2-2013. Custom weather models and occupancy schedules were generated to efficiently explore a combination of weather conditions, building constructions, and occupancy states. The custom modeling approach was combined with previous experimental data within the Openstudio graphics interface to the EnergyPlus building modeling engine. Results indicate smart thermostats add the …


An Evaluation Of Borehole Hydraulic Conductivity Equations And Field Determined Soil Water Characteristic Curves, Johnathan Dale Blanchard Dec 2017

An Evaluation Of Borehole Hydraulic Conductivity Equations And Field Determined Soil Water Characteristic Curves, Johnathan Dale Blanchard

Graduate Theses and Dissertations

The methods utilized to determine the hydraulic conductivity of compacted clay liners (CCLs) are of importance for safe guarding the environment from landfill leachate. Therefore, the methods utilized in the analysis of the Two Stage Borehole (TSB) test, as described in the ASTM D6391-11 (Method A, B, and C) standard, were evaluated. Data from hydraulic conductivity tests, as performed on three test pads, were utilized to review the ASTM D6391-11 equations. Additionally, two test pads were instrumented with volumetric water content and soil water matric potential sensors to facilitate the determination of field-obtained soil water characteristic curves (SWCCs) and hydraulic …


Evaluation Of Water Resources And Hydraulic Influences In The Restoration Of The Western Part Of The Mesopotamian Marshlands, Ali Kareem Al-Quraishi Dec 2017

Evaluation Of Water Resources And Hydraulic Influences In The Restoration Of The Western Part Of The Mesopotamian Marshlands, Ali Kareem Al-Quraishi

Graduate Theses and Dissertations

The purpose of this study is to assess the water resources and water conveyance system of the western part of the Mesopotamian marshes (Al-Hammar marsh) as well as develop a water conveyance system to distribute water throughout the western Al-Hammar marsh. These processes are significant to identify the current restoration problems and help to create restoration strategies for the marsh. Also, proper management strategy to the Al-Hammar marsh is necessary to preserve the marsh ecosystem, irrigate lands, and provide domestic necessities in the villages.

The overall project is divided into three main chapters which address the current ecological and hydrological …


Free-Space Measurements Of Dielectrics And Three-Dimensional Periodic Metamaterials, Clifford E. Kintner Dec 2017

Free-Space Measurements Of Dielectrics And Three-Dimensional Periodic Metamaterials, Clifford E. Kintner

Graduate Theses and Dissertations

This thesis presents the free-space measurements of a periodic metamaterial structure. The metamaterial unit cell consists of two dielectric sheets intersecting at 90 degrees. The dielectric is a polyetherimide-based material 0.001” thick. Each sheet has a copper capacitively-loaded loop (CLL) structure on the front and a cut-wire structure on the back. Foam material is used to support the unit cells. The unit cell repeats 40 times in the x-direction, 58 times in the y-direction and 5 times in the z-direction. The sample measures 12” × 12” × 1” in total. We use a free-space broadband system comprised of a pair …


Bayesian Model For Detection Of Outliers In Linear Regression With Application To Longitudinal Data, Zahraa Al-Sharea Dec 2017

Bayesian Model For Detection Of Outliers In Linear Regression With Application To Longitudinal Data, Zahraa Al-Sharea

Graduate Theses and Dissertations

Outlier detection is one of the most important challenges with many present-day applications. Outliers can occur due to uncertainty in data generating mechanisms or due to an error in data recording/processing. Outliers can drastically change the study's results and make predictions less reliable. Detecting outliers in longitudinal studies is quite challenging because this kind of study is working with observations that change over time. Therefore, the same subject can produce an outlier at one point in time produce regular observations at all other time points. A Bayesian hierarchical modeling assigns parameters that can quantify whether each observation is an outlier …


A Comparative Life Cycle Assessment Of Nutritionally Equivalent Meals With And Without Pork, Kelli Young Dec 2017

A Comparative Life Cycle Assessment Of Nutritionally Equivalent Meals With And Without Pork, Kelli Young

Graduate Theses and Dissertations

The following report details a life cycle assessment of several dietary and meal scenarios with and without pork. The goal of the LCA was to identify the impacts of greenhouse gas emissions, water use, and land use of pork containing and porkless diets and meal plans in a field-to-fork analysis. The dietary and meal plan scenarios are iso-caloric meaning they contain the same number of calories. The first set of diets is based on a USDA consumption pattern, 2000 kcal per day. This diet was used to create three other dietary scenarios with and without pork. The USDA recommended food …


Seeing Prehistory Through New Lenses: Using Geophysical And Statistical Analysis To Identify Fresh Perspectives Of A 15th Century Mandan Occupation, Amber Marie Mitchum Dec 2017

Seeing Prehistory Through New Lenses: Using Geophysical And Statistical Analysis To Identify Fresh Perspectives Of A 15th Century Mandan Occupation, Amber Marie Mitchum

Graduate Theses and Dissertations

Great Plains prehistoric research has evolved over the course of a century, with many sites like Huff Village (32MO11) in North Dakota recently coming back to the forefront of discussion through new technological applications. Through a majority of its studies and excavations, Huff Village appeared to endure as the final stage in the Middle Missouri tradition. Long thought to reflect only systematically placed long-rectangular structure types of its Middle Missouri predecessors, recent magnetic gradiometry and topographic mapping data revealed circular structure types that deviated from long-held traditions, highlighting new associations with Coalescent groups. A compact system for food capacity was …


Habitat Ecology, Trophic Interactions, And Distribution Of Endangered Himalayan Musk Deer In The Nepal Himalaya, Kapil Kishor Khadka Dec 2017

Habitat Ecology, Trophic Interactions, And Distribution Of Endangered Himalayan Musk Deer In The Nepal Himalaya, Kapil Kishor Khadka

Graduate Theses and Dissertations

This dissertation seeks to explore and assess the habitat selection, trophic interactions and distribution of Himalayan musk deer. Chapter one deals with seasonal diet analysis of musk deer along with the overlap in consumption with livestock during summer. Microhistological technique was employed to assess dietary consumption. Results showed that Abies spectabilis, Pinus wallichiana, and Berberis species constituted the major portion of musk deer’s diet. Dietary breadth measured by the Shannon index was found higher in winter compared to summer. Although musk deer and livestock shared a considerable number of plant species in their diets, the consumption however was significantly different …


Green Chemistry Oxidative Modification Of Peptoids Utilizing Bleach And Tempo, Jesse Leland Roberts Dec 2017

Green Chemistry Oxidative Modification Of Peptoids Utilizing Bleach And Tempo, Jesse Leland Roberts

Graduate Theses and Dissertations

Biotherapeutic drugs, derived from biological molecules such as proteins and DNA, are becoming an integral and exceptionally critical aspect of modern medicine. Compared to common pharmaceutical drugs, biotherapeutics are much larger in size and have greater target specificity, allowing them to treat many chronic diseases ranging from cancer to rheumatoid arthritis. The major issue with protein based therapeutics is that they readily undergo proteolysis, or enzymatic degradation, when administered through subcutaneous injections. Traditionally, biotherapeutic modification procedures have centered on the use of PEG derivatives. This process, called PEGylation, is unfavorable due to the increases in molecular weights of the proteins …


Paleozoic Sandstones In The Tri-State Region, Southern Ozarks: Tectono-Stratigraphic Sequence Development And Compositional Evolution, The Source And Delivery Conundrum, And The Regional Tectonic History, Elvis Chekwube Bello Dec 2017

Paleozoic Sandstones In The Tri-State Region, Southern Ozarks: Tectono-Stratigraphic Sequence Development And Compositional Evolution, The Source And Delivery Conundrum, And The Regional Tectonic History, Elvis Chekwube Bello

Graduate Theses and Dissertations

The Paleozoic stratigraphic record of the Ozark Region, southern midcontinent has been divided into at least 33 formations, with the most significant thickness of 9692 feet preserved in northwest Arkansas. The potential thickness would have been much greater, but epeirogenic movements and sea-level rise and fall produced regional surfaces of erosion reducing the record. That interplay between tectonics (epeirogenic movements) and eustatic change (transgressive-regressive cycles) preserved in the Ozark sedimentary history provides the basis for recognition of five distinct, but related, tectonostratigraphic units designated TS 1 through TS 5: Late Precambrian-Middle Cambrian (TS 1), Late Cambrian-Earliest Ordovician (TS 2), Early …


An Investigation Of Biological Carbon Sequestration At The Pea Ridge National Military Park, Dorine Reed Bower Dec 2017

An Investigation Of Biological Carbon Sequestration At The Pea Ridge National Military Park, Dorine Reed Bower

Graduate Theses and Dissertations

The direct correlation between increasing levels of atmospheric CO2 and global temperatures is now irrefutable. A 50% increase in atmospheric CO2 levels from a pre-industrial level of 270 ppm to a present-day level of 405 ppm, has resulted in documented record temperatures and a concomitant rising of sea levels from melting ice caps.

The ability of biological/terrestrial ecological systems to store atmospheric carbon is a viable option in the effort to mitigate the climate impacts of rising anthropogenically-caused greenhouse gas emissions. Components of the vegetation and soils in the Pea Ridge National Military Park (the Park) were examined for carbon …


Development And Characterization Of Rice Genotypes For Water Use Efficiency And Drought Resistance, Anuj Kumar Dec 2017

Development And Characterization Of Rice Genotypes For Water Use Efficiency And Drought Resistance, Anuj Kumar

Graduate Theses and Dissertations

Rice, the second largest staple food crop, uses 30% of global fresh water to complete its life cycle worldwide. Water deficits worldwide have become a serious problem affecting rice growth and ultimately grain yield. To solve the water problem globally, improvement of water use efficiency (WUE) and other drought resistance (DR) traits in rice genotypes would be a useful strategy using advanced genomics tools. In this study, our objectives were to 1) analyze phenotypes of the USDA rice mini-core collection (URMC) for WUE and DR related traits, 2) correlate drought response phenes for physiological traits and grain yield in the …


Fungi Of Forests: Examining The Diversity Of Root-Associated Fungi And Their Responses To Acid Deposition, Donald Jay Nelsen Dec 2017

Fungi Of Forests: Examining The Diversity Of Root-Associated Fungi And Their Responses To Acid Deposition, Donald Jay Nelsen

Graduate Theses and Dissertations

Global importance of forests is difficult to overestimate, given their role in oxygen production, ecological roles in nutrient cycling and supporting numerous living species, and economic value for industry and as recreational zones. Fitness of the forest-forming trees strongly depends on microbial communities associated with tree roots. In particular, fungi impact tree fitness: mycorrhizal species provide water and nutrients for the trees in exchange for C, endophytic fungi play key roles in host defense against pathogenic organisms, and saprotrophic fungi decompose dead organic matter and facilitate nutrient cycling. In addition, pathogenic fungal species strongly affect forest fitness. Despite their importance, …


Population Dynamics Of Ouachita Dusky Salamanders (Desmognathus Brimleyorum) In A Managed Forest Landscape, Kelly Marie Halloran Dec 2017

Population Dynamics Of Ouachita Dusky Salamanders (Desmognathus Brimleyorum) In A Managed Forest Landscape, Kelly Marie Halloran

Graduate Theses and Dissertations

With anthropogenic alteration of landscapes increasing world-wide, managed forests are increasingly important as providers of ecosystem services including habitat for numerous wildlife species. It is crucial to maintain a balance between timber production and conservation of biodiversity on managed landscapes. Salamander populations can play key roles in the function and diversity of temperate forest ecosystems. Several studies have reported negative effects of forestry on terrestrial plethodontid salamanders, but less research has focused on stream-dwelling species, evaluated mechanisms driving observed shifts in abundance, or described the dynamics of populations residing in managed forests. Using a Before-After-Control-Impact design, we examined the effects …


Asynchronous 3d (Async3d): Design Methodology And Analysis Of 3d Asynchronous Circuits, Francis Corpuz Sabado Dec 2017

Asynchronous 3d (Async3d): Design Methodology And Analysis Of 3d Asynchronous Circuits, Francis Corpuz Sabado

Graduate Theses and Dissertations

This dissertation focuses on the application of 3D integrated circuit (IC) technology on asynchronous logic paradigms, mainly NULL Convention Logic (NCL) and Multi-Threshold NCL (MTNCL). It presents the Async3D tool flow and library for NCL and MTNCL 3D ICs. It also analyzes NCL and MTNCL circuits in 3D IC. Several FIR filter designs were implement in NCL, MTNCL, and synchronous architecture to compare synchronous and asynchronous circuits in 2D and 3D ICs. The designs were normalized based on performance and several metrics were measured for comparison. Area, interconnect length, power consumption, and power density were compared among NCL, MTNCL, and …


Agronomic Management Practice Effects On Particulate Organic Matter And Infiltration In A Wheat-Soybean, Double-Crop System In Eastern Arkansas, Johan Desrochers Dec 2017

Agronomic Management Practice Effects On Particulate Organic Matter And Infiltration In A Wheat-Soybean, Double-Crop System In Eastern Arkansas, Johan Desrochers

Graduate Theses and Dissertations

Improving the understanding of conventional and alternative management practices and their interactions on aggregate-derived particulate organic matter (POM) fractions and soil hydraulic properties, particularly infiltration, is instrumental to soil and groundwater management and long-term sustainability in the Lower Mississippi River Delta (LMRD) region of eastern Arkansas. The objective of this long-term wheat (Triticum aestivum L.)-soybean (Glycine max [L.] Merr.), double-crop (WSDC) field study in a silt-loam soil (Glossaquic Fraglossudalf) in the LMRD region of eastern Arkansas was to evaluate the effects of conventional and alternative management practices, including wheat-residue level, residue burning, tillage and irrigation, on i) POM fractions and …


Structural And Elastic Properties Of Degenerate Sno Monolayers At Finite Temperature, Afsana Sharmin Dec 2017

Structural And Elastic Properties Of Degenerate Sno Monolayers At Finite Temperature, Afsana Sharmin

Graduate Theses and Dissertations

Chalcogen-based layered superconductors with a litharge structure such as FeS and FeSe mono-layers undergo structural and superconducting phase transitions that are tunable by doping. Representing another material platform with a litharge structure but without valence d-electrons, SnO monolayers also display a structural ground state with a degenerate rectangular unit cell at zero temperature and a charge-tunable energy barrier that leads to a thermally-controllable structural phase change. Doped SnO monolayers with rectangular degenerate unit cells give rise to two-dimensional multiferroicity. Their two-dimensional elastic energy landscape adopts a basic analytic expression that is employed to discuss this structural transition. The results contained …


Energy From Active Galactic Nuclei And The Effects On Host Spiral Galaxies, Amanda Schilling Dec 2017

Energy From Active Galactic Nuclei And The Effects On Host Spiral Galaxies, Amanda Schilling

Graduate Theses and Dissertations

I have investigated the energy output of active galactic nuclei (AGN) in order to understand how these objects evolve and the impact they may have on host galaxies. First, I looked at a sample of 96 AGN at redshifts $z \sim 2, 3,$ and $4$ which have imaging and thus luminosity measurements in the $griz$ and $JHK$ observed wavebands. For these galaxies, I have co-epochal data across those bands which accounted for variability in AGN luminosity. I used the luminosity measurements in the five bands to construct spectral energy distributions (SED) in the emitted optical-UV bands for each AGN. I …


The Effect Of Preflood Nitrogen And Flood Establishment Timing On Rice Development, Nitrogen Uptake And Grain Yield, Tyler Richmond Dec 2017

The Effect Of Preflood Nitrogen And Flood Establishment Timing On Rice Development, Nitrogen Uptake And Grain Yield, Tyler Richmond

Graduate Theses and Dissertations

Urea-N fertilizer is typically applied at the 5-leaf stage to rice (Oryza sativa L.) grown in a dry-seeded, delayed-flood production system. How long the preflood-N can be delayed without adverse effects on yield potential is poorly understood. The research objective was to determine the effects of preflood-N application and flood establishment timing on aboveground-N content, 50% heading, yield components, and grain yield. Trials were established on silt loam soils at the Pine Tree Research Station (PTRS) and Rice Research and Extension Center (RREC) during 2015 and 2016. Urea-N was applied at 0, 45, 90, 135, and 180 kg N ha-1 …


Detection Of Survival And Proliferation Of Sulfate Reducers Under Simulated Martian Atmospheric And Soil Conditions, Sergio Mosquera Mora Dec 2017

Detection Of Survival And Proliferation Of Sulfate Reducers Under Simulated Martian Atmospheric And Soil Conditions, Sergio Mosquera Mora

Graduate Theses and Dissertations

Numerous studies have tried to determine the survivability and proliferation of microorganisms under simulated Martian conditions. Furthermore, most of them have been focused on the ability of these microbes to cope with high brines’ salt (NaCl) concentrations inherent of the Martian surface. However, there are not studies related to the ability of bacteria to survive on subsurface environments that have increasing concentrations of sulfate compounds. For this research, a group of microorganisms known as sulfate-reducing bacteria or simply sulfate reducers were chosen due to their ability to use sulfate compounds as terminal electron acceptors to produce metabolic energy, their tolerance …


3d Seismic Interpretation Of A Plio-Pleistocene Mass Transport Deposit In The Deepwater Taranaki Basin Of New Zealand, Francisco Jose Rusconi Dec 2017

3d Seismic Interpretation Of A Plio-Pleistocene Mass Transport Deposit In The Deepwater Taranaki Basin Of New Zealand, Francisco Jose Rusconi

Graduate Theses and Dissertations

A series of Plio-Pleistocene mass transport deposits (MTD) have been identified in the deepwater Taranaki Basin, in New Zealand, using the Romney 3D seismic survey, which covers an area of approximately 2000 km2. One of these MTDs has been chosen for description and interpretation based on high confidence mapping of its boundary surfaces. The deposit exhibits an array of interesting features similar to those documented by researchers elsewhere plus a unique basal feature unlike those previously observed. The basal shear surface exhibits erosional features such as grooves, “monkey fingers”, and glide tracks. Internally, the MTD is typically characterized by low …


Bacterial And Archaeal Nitrifier Communities After Seven Years Surface Ground Cover And Nutrient Management In An Orchard Soil, Mashael Albalawi Dec 2017

Bacterial And Archaeal Nitrifier Communities After Seven Years Surface Ground Cover And Nutrient Management In An Orchard Soil, Mashael Albalawi

Graduate Theses and Dissertations

Nitrification is oxidation of ammonia to nitrite and subsequently to nitrate. The rate limiting step of nitrification, ammonia oxidation to nitrite, was thought for many years to be carried out primarily by ammonia oxidizing bacteria (AOB). However, using molecular techniques and investigating the amoA gene, ammonia-oxidizing archaea (AOA) were discovered. Understanding how long-term application of surface ground covers and organic fertilizers to perennial systems affect microbial communities is critical for sustainable soil management. An organically managed experimental apple orchard soil received seven years (2006 – 2013) of annual, surface applications of poultry litter or commercial fertilizer compared to no fertilizer …


Soil-Structure Interaction Effects On The Seismic Response Of Low-Rise Eccentrically Braced Frames, Luis Gerardo Buitrago Goyez Aug 2017

Soil-Structure Interaction Effects On The Seismic Response Of Low-Rise Eccentrically Braced Frames, Luis Gerardo Buitrago Goyez

Graduate Theses and Dissertations

The importance of soil-structure interaction (SSI) effects on the seismic response of

buildings has been long recognized and has been researched for over 40 years. However, SSI

analysis has only been applied in a few building projects because the fixed base condition is

considered to provide a conservative estimation for the response of buildings under seismic loads.

This assumption of a fixed base condition adopted by practitioners is not always conservative or

cost-effective, especially for rigid buildings over soft soils. Additionally, for the case of ductile

steel frames with eccentric configurations, the influence of SSI on their seismic performance has …


Laboratory Resistivity Measurements For Soil Characterization, Behdad Mofarraj Kouchaki Aug 2017

Laboratory Resistivity Measurements For Soil Characterization, Behdad Mofarraj Kouchaki

Graduate Theses and Dissertations

Field based electrical resistivity measurements, such as electrical resistivity tomography (ERT) and capacitively coupled resistivity (CCR), are geophysical methods that offer a non-destructive and rapid means to collect continuous data. As such, ERT and CCR are becoming increasingly popular tools for geotechnical engineers; however, it is challenging to derive geotechnical information such as soil type, density, and water content from the data. A laboratory geophysical investigation was carried out to gain a better understanding of the parameters that affect the electrical resistivity of soils and devise a relationship between resistivity and soil type or classification. In this study, a soil …


Geophysical Assessment Of Kinion Lake Dam, Tim Allen Moody Aug 2017

Geophysical Assessment Of Kinion Lake Dam, Tim Allen Moody

Graduate Theses and Dissertations

Geophysical methods including Capacitively-Coupled Resistivity (CCR), Electrical Resistivity Tomography/Imaging (ERT/ERI), Multichannel Analysis of Surface Waves (MASW) with Love and Rayleigh waves and a Full-Waveform Inversion (FWI) were performed on Kinion Lake Dam, an earth-filled embankment dam that has historically experienced significant seepage and internal erosion issues. Surveys were completed along the crest and downstream toe of the dam. Results from the surveys indicate that each method is capable of resolving the bedrock depth within 1-2 m of locations shown on previous drilling logs, though some discrepancies between the methods exist. A weathered bedrock layer is believed to have led to …


An Economic Analysis Of Residential Photovoltaic Systems With And Without Energy Storage, Rodney Moses Kizito Aug 2017

An Economic Analysis Of Residential Photovoltaic Systems With And Without Energy Storage, Rodney Moses Kizito

Graduate Theses and Dissertations

Residential photovoltaic (PV) systems serve as a source of electricity generation that is separate from the traditional utilities. Investor investment into residential PV systems provides several financial benefits such as federal tax credit incentives for installation, net metering credit from excess generated electricity added back to the grid, and savings in price per kilowatt-hour (kWh) from the PV system generation versus the increasing conventional utility price per kWh. As much benefit as stand-alone PV systems present, the incorporation of energy storage yields even greater benefits. Energy storage (ES) is capable of storing unused PV provided energy from daytime periods of …


Dental Microwear Textures Of Paranthropus Robustus From Kromdraai, Drimolen, And An Enlarged Sample From Swartkrans: Ecological And Intraspecific Variation, Alexandria Sachiko Peterson Aug 2017

Dental Microwear Textures Of Paranthropus Robustus From Kromdraai, Drimolen, And An Enlarged Sample From Swartkrans: Ecological And Intraspecific Variation, Alexandria Sachiko Peterson

Graduate Theses and Dissertations

The original microwear texture baseline for South African hominins was done by Scott et al. (2005) and concluded that Paranthropus robustus exhibited higher complexity values (Asfc) that are seen in occasional hard object feeders. Australopithecus africanus has higher anisotropy values (epLsar) consistent with consuming tough objects. This study expands upon this baseline by increasing the sample size from n = 9 for P. robustus and n = 10 for Au. africanus to n = 66 and n = 44, respectively. Additionally, this study incorporates multiple different sites and deposits. The P. robustus sample includes Drimolen, Kromdraai, and an expanded sample …


A Comparative Analysis Of Feed And Environmental Factors On Broiler Growth In The United States, Alexandra Gulli Aug 2017

A Comparative Analysis Of Feed And Environmental Factors On Broiler Growth In The United States, Alexandra Gulli

Graduate Theses and Dissertations

Broiler production in the United States has become an important industry within the last half century. As the demand for poultry continues to increase and the concern of climate change also increases, it will become an important part of the industry to become more sustainable. This study uses a feed optimization model, a broiler growth model, and a life cycle assessment (LCA) to determine how feed ingredients and the barn environment can affect the broiler’s growth and production emissions. A multi-criteria ration optimization model is used to produce feeds based on carbon footprint and cost. A growth model is used …


Effects Of Northern Bobwhite Management On Raccoon Abundance, Habitat Selection, And Home Range In Southwest Missouri, Jacob Cody Mcclain Aug 2017

Effects Of Northern Bobwhite Management On Raccoon Abundance, Habitat Selection, And Home Range In Southwest Missouri, Jacob Cody Mcclain

Graduate Theses and Dissertations

Habitat management has become vital for northern bobwhite (Colinus virginianus) conservation. In Missouri, efforts to conserve remaining populations on public lands have included the use of two management models. The Intensive Management Model (IMM) promotes hard edges, by creating a juxtaposition of different habitat types, while the Extensive Management Model (EMM) maintains a grassland-dominated landscape through the processes of fire and grazing. Preliminary results suggest that bobwhite success is significantly higher on EMM sites than IMM sites. Management efforts through IMM may be hindered by unintentionally managing for nest predators like raccoons (Procyon lotor). Nest predators may forage more often …


The Functionalization Of N-Cyclobutylanilines Under Photoredox Catalysis, Jiang Wang Aug 2017

The Functionalization Of N-Cyclobutylanilines Under Photoredox Catalysis, Jiang Wang

Graduate Theses and Dissertations

While transition metal catalyzed cross coupling reactions have become one of the most useful strategies in constructing carbon-carbon and carbon-heteroatom bond formations, major disadvantages such as high reaction temperature, expansive metal catalysts input and limited reaction substrates scope have significantly downshifted the applications of those two electron involved transformations. Comparably, the studies on the redox coupling reactions are less investigated. Derived from single electron transfer process, the redox coupling reactions can be used to construct otherwise challenging chemical bonds efficiently, such as Csp3-Csp3 bond. Recently, visible light mediated photoredox catalysis has merged as a highly prominent tool in the development …