Digital Commons Network^™

Controls On Phosphorus Export From An Agricultural Watershed: Amsden Brook, Fort Fairfield, Maine Usa., Gregory J. Mcdonald

Electronic Theses and Dissertations

This study explores the sources and mechanisms of phosphorus (P) mobilization during base flow within the Amsden Brook watershed, Fort Fairfield, Maine, USA. Amsden Brook is an agriculturally dominated watershed drained by a spring-fed and perennial first- to second-order stream. We characterized the P concentrations within the watershed to investigate connections between soils, stream sediment, surface water, and groundwater. Waters were monitored monthly during the 2017 snow-free period for temperature, pH, dissolved oxygen, conductivity, soluble reactive P (SRP), total P, strong acid anions, strong base cations, dissolved organic carbon (DOC), Al, Fe, and Mn. Phosphorus speciation within soils and sediment …

Modeling And Simulation Of The Thermoforming Process In Thermoplastic-Matrix Composite Materials, Philip M. Bean

Electronic Theses and Dissertations

Thermoplastic-matrix composite materials have unique advantages over traditional thermosets including faster processing, improved fracture toughness, and recyclability. These and other benefits have caused increasing interest in the use of these materials in both aerospace and automotive industries. Due to the differences in behavior, these materials require a different type of manufacturing process to thermoset matrix composites. This manufacturing process generally involves using pre manufactured tape-layers. These layers, containing both thermoplastic-matrix and fiber-reinforcement, are aligned to the desired orientation, and stacked up into a “tailored blank” using an automated tape layup machine. They are then heated to the thermoplastic melting temperature …

Coating Component Migration In Paper Coatings, Emilia Purington

Electronic Theses and Dissertations

In many applications such as in paints and coatings, pigments are mixed with polymeric binders to generate the final product. In the coating of paper, properties like strength, durability, and print quality are affected not only by the binder type, but the final location of the binder relative to the pigments and the fibers. During the application and drying of a paper coating, binder is known to migrate. A number of methods are available to measure the migration of latex or starch. However, all of these methods have some limitations, especially when starch, latex and kaolin are components of the …

Metal Thin Film Stiffness Extraction Technique For Surface Acoustic Wave Filters, Travis R. Weismeyer

Electronic Theses and Dissertations

Accurate knowledge of the surface acoustic wave (SAW) properties propagating at the surface of a piezoelectric substrate with thin films, electrodes or temperature compensated films, is critical in SAW filter design to meet the target frequency response, power durability and performance prior to device fabrication. While reliable material constants exist for substrates such as LiNbO3 used in SAW filters, the absolute elastic constants associated with operational thin films used for electrodes or temperature compensation do not exist. Although the bulk values of the constituent materials are known, the composite film/substrate properties are difficult to predict since they depend strongly on …

Application Of Silicon Nanohair Textured P-N Junctions In A Photovoltaic Device, Michael Small

Electronic Theses and Dissertations

The goal of this project is to design and develop a fabrication process for a silicon photovoltaic device which incorporates a nanohair textured p-n junction. The silicon nanowires are etched into a silicon wafer, comprising an epitaxial p-layer on n-substrate, via metal-assisted chemical etching (MACE). The resulting nanowires contain p-n junctions that lie along the length of the vertical nanowires. This construct has the potential to increase the optical bandwidth of a silicon photovoltaic device by allowing a greater amount of short wavelength light to reach the junction. In addition, the MACE method of nanofabrication has the potential for decreasing …

Process-Property-Microstructure Relationships In Laser-Powder Bed Fusion Of 420 Stainless Steel., Subrata Deb Nath

Electronic Theses and Dissertations

Laser-powder bed fusion (L-PBF) is an additive manufacturing technique for fabricating metal components with complex design and customized features. However, only a limited number of materials have been widely studied using L-PBF. AISI 420 stainless steel, an alloy with a useful combination of high strength, hardness, and corrosion resistance, is an example of one such material where few L-PBF investigations have emerged to date. In this dissertation, L-PBF experiments were conducted using 420 stainless steel powders to understand the effects of chemical composition, particle size distribution and processing parameters on ensuing physical, mechanical and corrosion properties and microstructure in comparison …

Characterization Of Microreactor And Analysis Of Carbonyl Compounds In Exhaled Breath., Qi Li

Electronic Theses and Dissertations

Analysis of trace volatile organic compounds at parts per billion (ppbv) to parts per trillion (pptv) level has become an important research frontier because of the applicability for environmental monitoring and noninvasive diagnosis of diseases. The methods of preconcentration for detection of trace aldehydes and ketones both in ambient air and human exhaled breath have increased considerably over the last decade. However, the majority of these methods are not efficient. In this dissertation, we have improved an innovative microreactor that is suitable for quantitative analysis of volatile carbonyl compounds (VOCs) in ambient air as well as in human exhaled breath. …

Modeling And Simulation Methodologies For Spinal Cord Stimulation., Saliya Kumara Kirigeeganage

Electronic Theses and Dissertations

The use of neural prostheses to improve health of paraplegics has been a prime interest of neuroscientists over the last few decades. Scientists have performed experiments with spinal cord stimulation (SCS) to enable voluntary motor function of paralyzed patients. However, the experimentation on the human spinal cord is not a trivial task. Therefore, modeling and simulation techniques play a significant role in understanding the underlying concepts and mechanics of the spinal cord stimulation. In this work, simulation and modeling techniques related to spinal cord stimulation were investigated. The initial work was intended to visualize the electric field distribution patterns in …

Exploration Of Radiation Damage Mechanism In Mems Devices., Pranoy Deb Shuvra

Electronic Theses and Dissertations

We explored UV, X-ray and proton radiation damage mechanisms in MEMS resonators. T-shaped MEMS resonators of different dimensions were used to investigate the effect of radiation. Radiation damage is observed in the form of resistance and resonance frequency shift of the device. The resistance change indicates a change in free carrier concentration and mobility, while the resonance frequency change indicates a change in mass and/or elastic constant. For 255nm UV radiation, we observed a persistent photoconductivity that lasts for about 60 hours after radiation is turned off. The resonance frequency also decreases 40-90 ppm during irradiation and slowly recovers at …

A Transfer Learning Approach For Sentiment Classification., Omar Abdelwahab

Electronic Theses and Dissertations

The idea of developing machine learning systems or Artificial Intelligence agents that would learn from different tasks and be able to accumulate that knowledge with time so that it functions successfully on a new task that it has not seen before is an idea and a research area that is still being explored. In this work, we will lay out an algorithm that allows a machine learning system or an AI agent to learn from k different domains then uses some or no data from the new task for the system to perform strongly on that new task. In order …

Low Temperature Desiccants In Atmospheric Water Generation., Sunil Gupta

Electronic Theses and Dissertations

Surging global water demand as well as changes to weather patterns and over exploitation of natural water sources, such as ground water, has made potable water a critical resource in many parts of the World already – one rapidly heading towards a crisis situation. Desalination has been adopted as a solution – this is however energy intensive and impractical for most of the developing countries - those most in need of water. A renewable source of energy is solar thermal and solar photovoltaic. A plentiful source of water is the humidity in the atmosphere. This research is to push the …

Landmine Detection Using Semi-Supervised Learning., Graham Reid

Electronic Theses and Dissertations

Landmine detection is imperative for the preservation of both military and civilian lives. While landmines are easy to place, they are relatively difficult to remove. The classic method of detecting landmines was by using metal-detectors. However, many present-day landmines are composed of little to no metal, necessitating the use of additional technologies. One of the most successful and widely employed technologies is Ground Penetrating Radar (GPR). In order to maximize efficiency of GPR-based landmine detection and minimize wasted effort caused by false alarms, intelligent detection methods such as machine learning are used. Many sophisticated algorithms are developed and employed to …

Three-Dimensional Bedrock Channel Evolution With Smoothed Particle Hydrodynamics, Nick Richmond

Electronic Theses and Dissertations

Bedrock channels are responsible for balancing and communicating tectonic and climatic signals across landscapes, but it is difficult and dangerous to observe and measure the flows responsible for removing weakly-attached blocks of bedrock from the channel boundary. Consequently, quantitative descriptions of the dynamics of bedrock removal are scarce. Detailed numerical simulation of violent flows in three dimensions has been historically challenging due to technological limitations, but advances in computational fluid dynamics aided by high-performance computing have made it practical to generate approximate solutions to the governing equations of fluid dynamics. From these numerical solutions we gain detailed knowledge of the …

Development Of Thermoplastic Composite Reinforced Ultra-High Performance Concrete Panels For Impact Resistance, Reagan M. Smith Gillis

Electronic Theses and Dissertations

Recent studies investigating the impact performance of ultra-high performance concrete (UHPC) reported a quasi-brittle flexural failure that transitioned to a brittle punching-shear failure as the size of the impact head was reduced. A potential technology to increase the flexural strength and impact resistance of concrete is applying fiber reinforced polymer (FRP) composites to the exterior faces of the beam or slab. In this work, E-glass fiber reinforced thermoplastics were utilized in two different systems to apply reinforcement to UHPC. Thermoplastic materials were chosen over traditional thermoset materials for their unique advantages, such as rapid fabrication, automated manufacturing and the ability …

Field Implementation Of Tire Derived Aggregate As Lightweight Backfill For Retaining Walls, Jeremy Labbe

Electronic Theses and Dissertations

The objective of this study was to determine the effectiveness of Tire Derived Aggregate (TDA) as embankment and retaining wall backfill material using data from two field projects supplemented by data from previously published studies. Data collected from the two projects included horizontal earth pressure, resultant forces and moments acting in the wall stem, tensile and compressive forces within the wall, moments at the base of the wall, settlement of the TDA, time dependent temperature fluctuations within TDA, pore pressure changes in underlying foundation soil, movement of the wall face, and movement of the embankment. Data Collection was completed by …

Feasibility Of Hybrid Thermoplastic Composite-Concrete Load Bearing System, Camerin M. Seigars

Electronic Theses and Dissertations

Thermoplastic composites have many advantages over thermoset composites such as being recyclable, rapidly manufacturable, and more impact resistant. The goal of this thesis is to assess the feasibility of using thermoplastic composites in structural applications through literature review, mechanical testing, design of a load-bearing hybrid composite-concrete structures, and the implementation of thermoplastic composites for tensile reinforcement of concrete. The study had four objectives covering the stated goal.

1. Conduct a literature review to direct thermoplastic material selection
2. Characterize thermoplastic material mechanical properties using standardized mechanical testing
3. Design a hybrid composite-reinforced concrete beam, and
4. Develop thermoplastic shear connectors to develop composite action …

Formate Assisted Pyrolysis Of Lignin, Mayank S. Patel

Electronic Theses and Dissertations

A significant fraction of global energy demand is met through nonrenewable petroleum feedstock, which increases the risk of energy security. The energy production from nonrenewable petroleum feedstocks is one of the large contributor to greenhouse gas emissions, which can cause climate change impacts. The energy security can be improved, and the greenhouse gas emissions can be reduced by deriving energy from domestically available renewable lignocellulosic feedstocks such as wood. Wood has three major components: cellulose, hemicellulose, and lignin. The cellulose is primarily used to produce pulp and paper. The hemicellulose is often utilized to produce a valueadded chemical like furfural. …

Modeling Coastal Flooding And Sand Transport In The Gulf Of Maine During Severe Storms In A Changing Climate, Dongmei Xie

Electronic Theses and Dissertations

Elevated water level and large waves cause extensive damage and economic loss to coastal communities. An integrated atmosphere-ocean-coast modeling system that links physical processes with scales ranging from the open ocean to the surf zone has been developed for the Gulf of Maine. The modeling system includes a hydrodynamic model, a wave overtopping model and a sediment transport model. It is then applied to investigate and gain a comprehensive understanding of the following coastal processes: (1) the interaction between tide-surge, waves and bathymetry, (2) coastal flooding due to wave overtopping, and (3) sand transport.

Both coastal flooding and sand transport …

Performance Test And Numerical Simulation Of An Adjustable Implant For Treating Vocal Fold Paralysis, Hai Zi

Electronic Theses and Dissertations

Unilateral vocal fold paralysis (UVFP) is one of the most common laryngeal diseases that affect human voice and speech production. It often causes incomplete glottal closure, resulting in voice symptoms including hoarseness, voice fatigue and increased voice effort. One common treatment of UVFP is Thyroplasty Type I, which uses a thyroplasty implant to medialize the paralyzed vocal fold and restore the normal vibration of the vocal fold. However, the surgical outcome is extremely sensitive to the size and shape of the implant. Currently, modifications in the implant size and shape rely upon surgical intuition and experience. The level of voice …

Mechanistic Studies Of Reducible Metal Oxides As Hydrodeoxygenation Catalysts, Akbar Mahdavi Shakib

Electronic Theses and Dissertations

Hydrodeoxygenation of phenol to benzene using ruthenium supported titania catalysts strongly varies depending on the support crystal structure and preparation conditions. Here, we performed spectroscopic characterization of titania supports to identify the surface impurities common to commercial and synthesized titania samples using a variety of spectroscopic methods. Sulfate impurities were detected for the commercial anatase samples and a procedure for their elimination was proposed so that inactive catalysts gained reactivity. Surface hydroxyls of different TiO2 samples (anatase, rutile, and pyrogenic) were identified using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments performed on vigorously cleaned surfaces and a facet-specific assignment …

The Hilbert-Huang Transform: A Theoretical Framework And Applications To Leak Identification In Pressurized Space Modules, Kenneth R. Bundy

Electronic Theses and Dissertations

Any manned space mission must provide breathable air to its crew. For this reason, air leaks in spacecraft pose a danger to the mission and any astronauts on board. The purpose of this work is twofold: the first is to address the issue of air pressure loss from leaks in spacecraft. Air leaks present a danger to spacecraft crew, and so a method of finding air leaks when they occur is needed. Most leak detection systems localize the leak in some way. Instead, we address the identification of air leaks in a pressurized space module, we aim to determine the …

Comparison Of A Modified And Traditional Rapid Infiltration Basin For Treatment And Control Of Nutrients In Wastewater Effluent, Jessica Cormier

Electronic Theses and Dissertations

Rapid infiltration basins (RIB) have been historically used in Florida for groundwater recharge, effluent disposal, or a combination of both. However, this technique has proven ineffective in providing nitrogen control unless the RIB is modified in some manner. In this study, a traditional RIB was compared to a modified RIB constructed with manufactured biosorption activated media (BAM) to evaluate nitrate removal from reclaimed water. The RIBs are used for reclaimed and excess storm water disposal. Few, if any, studies have been published where BAM-modified RIBs have been used for this purpose. In this work, a mixture of clay, tire crumb, …

Electrochemical Microsensors For In Situ Monitoring Of Chemical Compounds In Engineered And Natural Aquatic Systems, Jared Church

Electronic Theses and Dissertations

The adaption of needle-type electrochemical microsensor (or microelectrode) techniques to environmental science and engineering systems has transformed how we understand mass transport in biotic and abiotic processes. Their small tip diameter (5-20μm) makes them a unique experimental tool for direct measurements of analytes with high spatial and temporal resolutions, providing a quantitative analysis of flux, diffusion, and reaction rate at a microscale that cannot be obtained using conventional analytical tools. However, their applications have been primarily limited to understanding mass transport dynamics and kinetics in biofilms. With the advancement of sensor fabrication and utilization techniques, their potential applications can surpass …

Nanofiltration Of Perfluorinated Compounds As A Function Of Water Matrix Properties, Hadi Toure

Electronic Theses and Dissertations

Perfluorinated compounds (PFCs) have been manufactured and used in various industries including food packaging, paintings, and coating industries. Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) are the most commonly investigated PFCs that have bioaccumulative properties and a strong persistence in environment. Despite the growing interest in using membrane technology to remove PFOA and PFOS from water, little information is available on the impact of natural water matrices on the removal of PFOA and PFOS when using nanofiltration (NF). The presence of natural organic matter (NOM) and cations (Ca2+ and Mg2+) in water matrices and their interactions with the PFCs …

A Framework For Assessing Sustainability Impacts Of Truck Routing Strategies, Haluk Laman

Electronic Theses and Dissertations

The impact of freight on our transportation system is further accentuated by the fact that trucks consume greater roadway capacity and therefore cause more significant problems including traffic congestion, delay, crashes, air pollution, fuel consumption, and pavement damage. Assessing the actual effects of truck traffic is a growing need to support the ability to safely and efficiently move goods and people in areas where roadway expansion is not the best option. On one hand, trucks need to efficiently serve commerce and industry, while at the same time their activities need not contribute to a decline in the quality or public …

Large Scale Cryogenic Storage With Active Refrigeration, Adam Swanger

Electronic Theses and Dissertations

Storage and transfer of cryogenic liquefied gases on volume scales from under 10 liters for lab use, up to hundreds of millions of liters for industrial applications is of paramount importance across a vast range of industries. Traditionally, these commodities have been stored at or near the normal boiling point due to relative ease of operation and safety-related considerations; however, this also means that some percentage will always be lost due to environmental heat leaking into the vessel and causing boiloff. These losses become more concerning as scales increase, and are of particular importance for high-cost commodities such helium and …

Autonomous Discovery And Maintenance Of Mobile Frees-Space-Optical Links, Mahmudur Khan

Electronic Theses and Dissertations

Free-Space-Optical (FSO) communication has the potential to play a significant role in future generation wireless networks. It is advantageous in terms of improved spectrum utilization, higher data transfer rate, and lower probability of interception from unwanted sources. FSO communication can provide optical-level wireless communication speeds and can also help solve the wireless capacity problem experienced by the traditional RF-based technologies. Despite these advantages, communications using FSO transceivers require establishment and maintenance of line-of-sight (LOS). We consider autonomous mobile nodes (Unmanned Ground Vehicles or Unmanned Aerial Vehicles), each with one FSO transceiver mounted on a movable head capable of scanning in …

Selecting The Most Effective Energy Modeling Tool Based On A Project Requirement, Sodiq Akande

Electronic Theses and Dissertations

Building energy usage can be derived and controlled by performing building energy modeling. BEM can be performed using numerous software tools such as DesignBuilder, OpenStudio, EnergyPlus etc. These modeling tools can be sorted into three different modeling categories: Black-box, Gray-box and White-box. It is important for a modeler to be able to quickly select the proper tool from the proper category to meet the need of the project. To validate the method of categorizing tools, the three models generated using tools from each category and the modeling outputs required were compared. Each model was designed to estimate the amount of …

Room Temperature Operation Of Quantum Cascade Lasers Monolithically Integrated Onto A Lattice-Mismatched Substrate, Rowel Go

Electronic Theses and Dissertations

Quantum Cascade Lasers (QCLs) are semiconductor devices that, currently, have been observed to emit radiation from ~ 2.6 μm to 250 μm (1 to 100 terahertz range of frequencies.) They have established themselves as the laser of choice for spectroscopic gas sensing in the mid-wavelength infrared (3-8 μm) and long-wavelength infrared (8-15 μm) region. In the 4-12 μm wavelength region, the highest performing QCL devices, in terms of wall-plug efficiency and continuous wave operation, are indium phosphide (InP) based. The ultimate goal is to incorporate this InP-based QCL technology to silicon (Si) substrate since most opto-electronics are Si-based. The main …

Methods For Online Feature Selection For Classification Problems, Alaleh Razmjoo

Electronic Theses and Dissertations

Online learning is a growing branch of machine learning which allows all traditional data mining techniques to be applied on an online stream of data in real-time. In this dissertation, we present three efficient algorithms for feature ranking in online classification problems. Each of the methods are tailored to work well with different types of classification tasks and have different advantages. The reason for this variety of algorithms is that like other machine learning solutions, there is usually no algorithm which works well for all types of tasks. The first method, is an online sensitivity based feature ranking (SFR) which …