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2010

Temperature

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Temperature And Frequency Dependent Conduction Mechanisms Within Bulk Carbon Nanotube Materials, John Simmons Bulmer Jan 2010

Temperature And Frequency Dependent Conduction Mechanisms Within Bulk Carbon Nanotube Materials, John Simmons Bulmer

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The resistance of three types of bulk carbon nanotube (CNT) materials (floating catalyst CNT yarn, forest grown CNT yarn, and super acid spun CNT fiber) was measured from room temperature to 900 C. Fitting the curves to established conduction equations for disordered materials, competing conduction mechanisms pertaining to the material could be determined. Floating catalyst CNT yarn displayed both semiconductive and metallic isotropic behavior with a resistance minimum, similar to the behavior of crystalline graphite. It was found that, at room temperature, the semiconducting contribution-most likely junctions between CNTs-accounted for 99.99% of the overall resistance. The resistance of forest grown …