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Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ₂₄ PFAS concentrations, respectively, on average. Primary sample variability is associated …

Origin Of The Mega-Streamlined Morphology In Ne Africa And Arabia: Remote Sensing And Field-Based Investigations, Mohamed Samy Mohamed Elhebery

Dissertations

Mega-streamlined landforms on Earth and Mars have been attributed to aeolian, glaciogenic, fluvial, and tectonic processes. Identifying the forces that shaped these landforms is paramount for understanding landscape evolution and constraining paleo-climate models and ice sheet reconstructions. Exhumed Late Ordovician glacial deposits and landscape of the North Gondwana are reported here for the first time from SE Egypt. Using field and remote sensing (Advanced Land Observing Satellite [ALOS], Phased Array L-band Synthetic Aperture Radar (PALSAR) radar, multispectral Landsat TM datasets, and digital elevation models (DEMs) I mapped the distribution of the Late Ordovician glacial features (i.e. deposits and landforms) in …

Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ24 PFAS concentrations, respectively, on average. Primary sample variability is associated with …

Concept Validation: Collecting Composite Samples To Understand The Presence Of Per- And Polyfluoroalkyl Substances (Pfas) In Michigan Forested Areas, Nicole Renee Sanabria

Masters Theses

This research discusses the results of a state-wide study conducted by The Michigan Department of Environment, Great Lakes, and Energy to assess the presence of PFAS in shallow soils of state-owned forested areas in Michigan utilizing a composite sampling method. One sample collected from each of Michigan’s 83 counties reveals the presence of PFAS in all but one sample, with total PFAS concentrations ranging from non-detect to 2.016 μg/kg (dry weight). PFOS is generally detected at the highest concentrations, ranging from non-detect to 0.88 μg/kg, followed by PFBA, with concentrations ranging from non-detect to 0.69 μg/kg, and PFOA, with concentrations …

Factors Affecting Groundwater Nitrate Concentration In Madinah Area, Saudi Arabia, Majed M. Almutairi

Masters Theses

High levels of nitrate in groundwater are a serious problem in Madinah Area, Saudi Arabia. Identifying factors affecting groundwater nitrate contamination is important for managing groundwater quality. This study examined factors that have significant impacts on the high level of groundwater nitrate in Madinah Area. Factors examined included well-depth and land cover. Relationships between variables were explored using three statistical approaches: the Kruskal-Wallis test and two types of regression (ordinary least squares [OLS] and geographically weighted regression [GWR]).

Nitrate concentration data show that 73% of obtained groundwater samples exceeded the United States Environmental Protection Agency (EPA) maximum contaminant level (MCL) …

Pfas Mass Balance, Donovan Vitale

Honors Theses

First-generation, PFOS-dominant Aqueous Film Forming Foam (AFFF) concentrate of approximately 200 gallons was released to the sewer system from the Kalamazoo/Battle Creek International Airport on March 30, 2021. The AFFF release migrated to the Kalamazoo Water Reclamation Plant (KWRP), raising plant effluent above the Department of Environment, Great Lakes, and Energy (EGLE) PFOS water quality standard for a total of 46 days post-spill, although the influent concentrations exhibited sharp declines after only 7 days. By sampling influent, effluent, and biosolids daily, the only known long duration, high-frequency PFAS data set of an accidental AFFF release was generated. This study has …

Exploring The Effects Of Tree Roots On Infiltration Process, Nazife Onaral

Masters Theses

Effects of the root structures on soil infiltration dynamics are not clearly defined. Imaging the complex tree root structures and movement of water through the root ball is a challenging task to achieve without damaging the trees and roots by conventional methods. Commonly used methods are invasive, labor-intensive, and not easily accessible. Ground Penetrating Radar (GPR) has commonly been used to characterize soil profiles and it can be a reliable tool to map complex root structures with a novel high-resolution circular data collection technique. Electrical resistivity tomography (ERT) is another reliable geophysical method to image infiltration processes by the change …

Remote Sensing Application For Landslide Detection: Monitoring Along Eastern Lake Michigan (Miami Park, Mi), Guzalay Sataer

Dissertations

I assessed the nature and spatial and temporal patterns of deformation over the Miami Park bluffs on the eastern margin of Lake Michigan and investigated the factors controlling its observed deformation. Our approach involved the following steps: (1) extracting bluff deformation rates (velocities along the line of sight of the satellite) using a stack of Sentinel-1A radar imagery in ascending acquisition geometry acquired between 2017 and 2021 and applying the Intermittent Small Baseline Subset (ISBAS) InSAR time series analysis method; (2) generating high-resolution (5 cm) elevation models and orthophotos from temporal unmanned aerial vehicle (UAV) surveys acquired in 2017, 2019, …

A Framework For Assessing The 4th Rank Dispersivity Tensor Under Anisotropic Axial Symmetries, Xiang Fan

Dissertations

Multi-dimensional expansion of the advection-dispersion equation necessitated the representation of dispersivity as a 4th rank tensor. This tensorial form of dispersivity has 81 terms in three-dimensions with a maximum of 36 independent terms that may be used to describe Fickian spreading of a dissolved contaminant plume according to intrinsic properties of a porous medium. The complexity of the 4th rank tensor has led to the common practice of simplifying the tensor to only 2 or 3 independent terms by assuming isotropic conditions, although isotropic porous media are uncommon in nature as many natural geologic systems exhibit pronounced anisotropy. A broad …

“This Isn't Working For Me. Can We Do It A Different Way?" The Lived Experiences Of Geoscience Students With Learning Disabilities, Nina Morris

Masters Theses

The purpose of this exploratory qualitative study is to better understand the lived experiences of geoscience students with learning disabilities in their geoscience classes. Students with learning disabilities bring a unique perspective while also facing unique challenges in post-secondary education. In the literature, there is limited information on what support and teaching strategies are beneficial to this population. Undergraduate and graduate geoscience students who identify as having a learning disability from colleges and universities in the United States were recruited. Six students consented to participate in the study, and each completed a semi-structured interview. Semi-structured interviews were designed to prompt …

Evidence For An Early Saginaw Lobe Ice Retreat And Drainage Adjustments Across Southern Michigan, Usa, Nathan Erber

Dissertations

The Saginaw lobe of the Laurentide Ice Sheet (LIS), flowed out of Saginaw Bay, across Lower Michigan and into northern Indiana. As it retreated, the Saginaw lobe deposited the Sturgis moraine, a recessional moraine of the lobe in southern Michigan. Positioned to the west and east of the Saginaw lobe were the Lake Michigan and Huron-Erie lobes, respectively. These lobes retreated across the region asynchronously, with the Saginaw lobe retreating first. The asynchronous behavior of the lobes allowed for the Lake Michigan and Huron-Erie lobes to overprint and alter landscapes once occupied by the Saginaw lobe ice.

The Kalamazoo moraine, …

Characterization Of Mumian And Host Rock In Al-Amerat Cave, Oman., Sara Alqamshouai

Honors Theses

Mumian is a sticky black-brown material found in the Mumian cave in Wadi Al Mayh, Al Amerat, Oman. Mumian has been used for centuries as traditional medicine by the local Omani people. Though commonly ingested orally to resolve a variety of common ailments, very little is known about the Mumian material in terms of its chemical composition. The principle aim of this study is to characterize the Mumian and the host rock in terms of the mineralogy and chemical characteristics using a variety of analytic instruments, including XRD, NMR, FT-IR, XRF, and UV- VIS. A secondary goal of this study …

Mid To Late Neogene (5.9-3.7 Ma) Epeirogenic Uplift And Associated Ultramafic Volcanism, Canterbury Basin, New Zealand, Katherine Anne Dvorak

Dissertations

Cored marine sediments from Canterbury Basin Integrated Ocean Drilling Program (IODP) Expedition 317 shelf sites U1351, U1353, and upper slope Site U1352 have been resampled with emphasis on benthic foraminifera from the Late Eocene to Late Pliocene. These new data coupled with paleo water-depth and age data from the nearby Clipper-1 petroleum exploration well, are used to develop a 1-dimensional basin subsidence model for the Canterbury Basin. Our model indicates there was widespread epeirogenic uplift of 890  350m, in the mid-Neogene (5.9-3.7 million years ago), which took place during concomitant ultramafic volcanism. Close association of uplift and volcanism could …

A Remote Sensing And Machine Learning-Based Approach To Forecast The Onset Of Harmful Algal Bloom (Red Tides), Moein Izadi

Dissertations

In the last few decades, harmful algal blooms (HABs, also known as “red tides”) have become one of the most detrimental natural phenomena all around the world especially in Florida’s coastal areas due to local environmental factors and global warming in a larger scale. Karenia brevis produces toxins that have harmful effects on humans, fisheries, and ecosystems. In this study, I developed and compared the efficiency of state-of-the-art machine learning models (e.g., XGBoost, Random Forest, and Support Vector Machine) in predicting the occurrence of HABs. In the proposed models, the K. brevis abundance is used as the target, and 10 …

Instructor Selection And Use Of Virtual Field Experiences In College Geoscience Course, Kristen Foley

Masters Theses

Virtual Field Experiences (VFEs) are a growing supplement and gateway to traditional fieldwork in the geosciences. With VFEs becoming more accepted for use in college geoscience courses, how instructors find and choose VFEs for their students is critical to creating greater accessibility and future resources. VFEs that are not easily accessed by instructors may go unused, and the effort put into making them would have been wasted. This phenomenological descriptive study utilized five focus groups of college geoscience instructors in the United States. Each 1-to-1.5-hour focus group session of 3-7 participants took place on video conferencing software, which was recorded …

Experimental Insights Into The Origin Of Microcrystalline Calcites, Mohammed Hashim

Dissertations

A significant proportion of modern marine calcium carbonate sediments is dominated by metastable aragonite and high Mg calcite that either dissolves or stabilizes to low-Mg-calcite (calcite) or dolomite during diagenesis. Sediment dissolution and stabilization have implications for the CaCO3 budget in the ocean and carbon burial rates. Yet, the diagenetic conditions that promote each process and their relative importance are poorly understood. Further, stabilization most commonly produces calcite microcrystals that exhibit various textures and host micropores. Despite their ubiquity in the rock record, the controls on microcrystal textures remain unclear. Here, laboratory experiments were used to investigate aragonite-to-calcite stabilization as …

Mercury Emissions From Iron Mining And Copper Mining In The Upper Peninsula, Michigan, Ahmed Al Rahbi

Honors Theses

The wealth in the Upper Peninsula of Michigan has been intimately linked with mining, particularly the extraction of iron and copper. Iron was deposited in the Upper Peninsula 1.9 billion years ago (Gogebic and Ranges, 2020), and copper deposits are believed to be 1.1 billion years old (Blakemore et al., 2016). In the Upper Peninsula, mercury occurs naturally in taconite (iron ore) as elemental mercury (Hg⁰), and within the copper ores as “Mercury copper amalgam” (CuHg). When elemental mercury is released from the ores, it oxidizes in the atmosphere to form inorganic mercury (Hg²⁺) (Risher, 2003; …

Quantifying Surface Water Capture By Municipal Pumping Wells In An Urban Watershed Impacted By Road Salt, Austen York

Masters Theses

The Spring Valley sub-watershed is located within the Kalamazoo Township contains Spring Valley Lake, a man-made impoundment that ultimately discharges into the Kalamazoo River. Elevated chloride levels in pumped water from the Kalamazoo Station 14 municipal wellfield, located along the shoreline of Spring Valley Lake, has resulted in less than ideal corrosivity values for the water distribution system. Specific project objectives include: (1) identifying the cause of elevated chloride, (2) assessing surface water capture by the Station 14 wellfield, and (3) characterizing of water quality in Spring Valley Lake. Monitoring along a series of sampling transects spanning the sub-watershed, focused …

Using Sedimentary Mercury Geochemistry To Evaluate The Niagara-Salina Transition, Silurian Michigan Basin, Usa, Sara Hayes

Masters Theses

The Niagara-Salina boundary in the Michigan Basin is marked by an abrupt transition from carbonates to evaporites. Though the cause is uncertain, previous work suggests the onset of Salina evaporites was driven by basin restriction, but the presence of several global carbon isotope excursions (CIE) suggest a global driver. This study builds on this discussion using two relatively new geochemical proxies - elemental mercury concentrations [Hg] and Hg isotopes.

Mercury concentrations [Hg] were measured in 88 samples from the State Kalkaska #2-15 core from 6604.03 ft to 6797.42 ft. [Hg] ranges from 0.11 to 0.62 mg/kg and [Hg]/TOC from 0.038 …

Impact Of Calcium Carbonate Reactant Size And Mineralogy On Dolomite Stoichiometry, Katharine G. Rose

Masters Theses

Dolomite is a common, diagenetic, Mg-Ca carbonate mineral. Dolomitization occurs by a dissolution-precipitation reaction between a CaCO₃ precursor (calcite or aragonite) and Mg bearing fluids. The amount of Mg in dolomite, referred to as dolomite stoichiometry (mol% MgCO₃), varies in natural dolomites (38-50 mol% MgCO₃). Laboratory experiments have shown that dolomite stoichiometry is dependent on physiochemical factors of the diagenetic fluids (i.e., temperature, salinity, and Mg/Ca). The impact of the CaCO₃ precursor on stoichiometry, however, has not been studied directly. This study tests how the CaCO₃ precursor size (sieve size) and mineralogy (calcite …

Understanding Potential Climate Change Impacts On Water Resources Within A Fractured Rock Watershed In Northern Togo, Mahawa-Essa Mabossani Akara

Dissertations

More than 72% of sub-Saharan Africa land surface is comprised of hard rock with fractured rock aquifers supplying water to an estimated 25% of the rural population. Given low porosity and storativity, fractured rock aquifers are particularly vulnerable to stresses such as projected population growth and climate variability. General circulation models of sub-Saharan Africa predict increases in temperature and in occurrences of extreme precipitation trends, such as flooding and drought. Adaptation strategies that promote optimal uses of water resources have emerged, although, most focus exclusively on surface water resources. This project investigates the potential impact of climate change on surface …

Using Low-Flow Sampling Data To Estimate Hydraulic Conductivity In Aquifers, Joy Kiefer

Masters Theses

Hydrogeologists sample wells to test aquifer water quality and use slug tests to estimate aquifer permeability. Robbins et al. (2009) proposed a more efficient way to obtain the goals of the two tests—the use of low-flow sampling and the use of the resulting flow rate and drawdown data to estimate aquifer hydraulic conductivity (K). The Robbins et al. method calculates K by using the slope of the best fit line from the graph of flow rate vs. drawdown for all low-flow pumping data collected at a well. When the method was applied to low-flow data from four Kalamazoo, MI, it …

Dolomite Stoichiometry As A Proxy For Fluid Chemistry, Cameron J. Manche

Dissertations

The origin of massive dolomites is a contentious issue in geology. Because modern dolomite is rare, interpretation of ancient dolomites requires the use of proxy resources, most of which provide ambiguous information. High-temperature dolomite synthesis experiments have shown that dolomite stoichiometry, the degree of cation ordering, and reaction rate are controlled by Mg:Ca, temperature, molarity, and salinity of the formative solution. Thus, it is posited here that dolomite stoichiometry may be a useful proxy for fluid chemistry, as are stable isotope and trace element composition of ancient dolomites. High-frequency sample intervals (cm-scale) from the Cretaceous Upper Glen Rose Formation (Comanche …

An Integrated Approach For The Assessment And Monitoring Of Land Deformation In The Riyadh City And Its Surroundings For Identifying The Controlling Factors, Abdulaziz Ibrahim Aljammaz

Dissertations

An integrated approach (remote sensing, field, geodesy, geology, and hydrogeology) was conducted to assess and monitor land deformation at Riyadh city and its surroundings. Two settings were investigated. The first, Jinadriyah area (1.5 km²), an urban area located east of Riyadh city, was selected to assess deformation associated with urbanization over desert lands. The second location was Al Kharj area (19,790 km²) to the south of Riyadh city, a reclaimed desert land that was selected to assess the deformation associated with agricultural groundwater extraction from fossil aquifers. My investigations revealed high subsidence rates (up to -30 …

Response Of Deep Aquifers To Climate Variability, Karem Fathy Abdelgaber Abdelmohsen

Dissertations

Our recent analysis of Temporal Gravity Recovery and Climate Experiment (GRACE) solutions over the largest aquifer system in Africa (the Nubian Sandstone Aquifer System: NSAS) revealed that while the response of deep aquifers to climatic variations remains a relatively slow process that takes thousands to tens of thousands of years, there is a much faster response in aquifers that are characterized by dense networks of faults, fractures and karst as is the case with the NSAS. This rapid groundwater flow, when it occurs, is detected as an increase in GRACE_TWS over areas downgradient and distant (hundreds of km) from …

Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed

Masters Theses

In regions where groundwater is used for irrigation, significant water losses take place due to evaporation. Previous studies demonstrated the utility of stable oxygen and hydrogen isotopes in estimating evaporative water loss experienced during return flow back to an aquifer. Unlike arid regions where the other studies took place, this study examined the region around Kalamazoo, Michigan, the United States, which experiences a more temperate climate. Irrigation in the Kalamazoo area primarily uses center-pivot systems supplied by wells, unlike flood irrigation in previous study areas. Water samples were taken periodically from wells close to center-pivot irrigation systems. Water losses due …

Monitoring Salt Diapir Related Land Deformation And Distribution: A Geophysical And Remote Sensing Approach Jazan Province, Saudi Arabia, Hannah G. Pankratz

Dissertations

Salt diapirs are rarely preserved on the surface and seldom considered as environmental hazards. The Jazan city diapir (JZD) is located in southwest Saudi Arabia along the Red Sea coastal plain and outcrops in the middle of a rapidly growing port city. The intrusion of the diapir (~ 2 km²) into the overburden sediments continues to cause uneven surfaces, compromises building foundations and infrastructure, caused dissolution sinkholes, and limits the expansion of the city along the coastline. This research aims to better understand the distribution and deformation associated with salt diapirs in arid environments.

Using integrated Interferometric Synthetic …

Statistical Downscaling Techniques To Enhance The Spatial Resolution Of The Grace Satellite Data And To Fill Temporal Gaps, Hossein Sahour

Dissertations

The Gravity Recovery and Climate Experiment (GRACE) has been successfully used to monitor variations in terrestrial water storage (GRACE_TWS ) and groundwater storage (GRACE_GWS) across the globe, yet such applications are hindered on local scales by the limited spatial resolution of GRACE data. Using the Lower Peninsula of Michigan as a test site, I developed optimum procedures to downscale GRACE Release-06 monthly mascon solutions. A four-fold exercise is conducted. Cluster analysis is performed to identify the optimum number and distribution of clusters (areas) of contiguous pixels of similar geophysical signals (GRACE_TWS time series); three clusters are …

Integrating Detailed Petrography, Geochemistry, And Mineralogy To Elucidate Extensive Early Diagenesis In The Eocene Carbonates Of Qatar, Brooks H. Ryan

Dissertations

Eocene carbonates comprising the Umm er Radhuma (UER), Rus, and Dammam Formations, cover 80% of the surface and extend >300 m into the subsurface of Qatar. These rocks record marine sedimentation in shallow sub-tidal to restricted settings. Despite undergoing only shallow burial (<1000 m), extensive diagenetic alteration has occurred. Given that little work on this topic has been published previously, the objectives of this work are to document diagenesis in the Eocene, and to integrate petrography, mineralogy, and geochemistry to delineate the timing and environments of diagenesis of these Eocene carbonates. Detailed petrographic data show that dolomitization occurred early in the UER, before the formation of diagenetic chert, palygorskite, pyrite, calcite, and gypsum cements. Bulk dolomite δ¹⁸O values, coupled with clumped isotope-derived (Δ47) temperatures and dolomitizing fluid δ¹⁸O values, suggest dolomitization took place in near-normal marine fluids, perhaps during shallow burial. These data challenge the current paradigm of large-scale, top-down hypersaline reflux dolomitization in the UER. Associated depth trends of increasing crystal size and with increasing stoichiometry and cation ordering …

An Integrated Approach (Remote Sensing, Hydrogeology, Gis, And Statistical Modeling) To Identify The Distribution Of Shallow Groundwater Occurrences Over Southwest Saudi Arabia, Fahad Khudier Alshehri

Dissertations

Identifying shallow (near-surface) groundwater in arid and hyper-arid areas has significant societal benefits, yet it is a costly operation when traditional methods (geophysics and drilling) are applied over large domains. In this study, we developed and successfully applied methodologies that rely heavily on readily available temporal, visible and near-infrared, radar, and thermal remote sensing data sets and field data, as well as statistical approaches to map the distribution of shallow (1–5 m deep) groundwater occurrences in Al Qunfudah Province, Saudi Arabia and to identify the factors controlling their development. A four-fold approach was adopted: (1) constructing a digital database to …