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Reactions Of The Cn Radical With Benzene And Toluene: Product Detection And Low-Temperature Kinetics, Adam J. Trevitt, Fabien Goulay, Craig A. Taatjes, David L. Osborn, Stephen R. Leone Jan 2010

Reactions Of The Cn Radical With Benzene And Toluene: Product Detection And Low-Temperature Kinetics, Adam J. Trevitt, Fabien Goulay, Craig A. Taatjes, David L. Osborn, Stephen R. Leone

Faculty of Science - Papers (Archive)

Low-temperature rate coefficients are measured for the CN + benzene and CN + toluene reactions using the pulsed Laval nozzle expansion technique coupled with laser-induced fluorescence detection. The CN + benzene reaction rate coefficient at 105, 165, and 295 K is found to be relatively constant over this temperature range, (3.9−4.9) × 10−10 cm3 molecule−1 s−1. These rapid kinetics, along with the observed negligible temperature dependence, are consistent with a barrierless reaction entrance channel and reaction efficiencies approaching unity. The CN + toluene reaction is measured to have a rate coefficient of 1.3 × 10−10 cm3 molecule−1 s−1 at 105 …


Effects Of Soil Temperature Regimes After Fire On Seed Dormancy And Germination In Six Australian Fabaceae Species, Victor Santana, Ross A. Bradstock, Mark Ooi, Andrew J. Denham, Tony D. Auld, M Baeza Jan 2010

Effects Of Soil Temperature Regimes After Fire On Seed Dormancy And Germination In Six Australian Fabaceae Species, Victor Santana, Ross A. Bradstock, Mark Ooi, Andrew J. Denham, Tony D. Auld, M Baeza

Faculty of Science - Papers (Archive)

In addition to direct fire cues such as heat, smoke and charred wood, the passage of fire leads indirectly to changes in environmental conditions which may be able to break physical dormancy in hard-coated seeds. After a fire, the open canopy and the burnt material lying on the surface alter the thermal properties of the soil, resulting in elevated soil temperatures for long periods of time. We simulated daily temperature regimes experienced at different depths of soil profile after a summer fire. Our aim was to determine whether these temperature regimes and the duration of exposure (5, 15 and 30 …


Temperature Effect On Microstructure And Electromagnetic Performance Of Polycarbosilane And Sugar-Doped Mgb2 Wires, Andrey V. Shcherbakov, Josip Horvat, Olga V. Shcherbakova, Nikolina Novosel, Emil Babic, S. X. Dou Jan 2010

Temperature Effect On Microstructure And Electromagnetic Performance Of Polycarbosilane And Sugar-Doped Mgb2 Wires, Andrey V. Shcherbakov, Josip Horvat, Olga V. Shcherbakova, Nikolina Novosel, Emil Babic, S. X. Dou

Faculty of Engineering - Papers (Archive)

The effect of processing temperature on structural and superconducting properties of 10 wt.% sugar- and 10 wt.% PCS-doped MgB2 wires is systematically investigated. It is demonstrated that these dopants significantly enhance the electromagnetic performance of Fe-clad MgB2 superconductor and increase its potential for practical application. The enhancement of in-field critical current density (Jc(Ba)) and upper critical field (Bc2) is due to formation of a large amount of lattice defects caused by impurities and C substitution into the MgB2 crystal lattice. High temperature sintering of sugar-doped sample results …


Effect Of Bulk Temperature On The Tribological Performance Of Aqueous Symmetric Tri-Block Copolymers (Ppo-Peo-Ppo And Peo-Ppo-Peo) Based Lubricant, Oyong Novareza, P B. Kosasih, A K. Tieu, Hongtao Zhu Jan 2010

Effect Of Bulk Temperature On The Tribological Performance Of Aqueous Symmetric Tri-Block Copolymers (Ppo-Peo-Ppo And Peo-Ppo-Peo) Based Lubricant, Oyong Novareza, P B. Kosasih, A K. Tieu, Hongtao Zhu

Faculty of Engineering - Papers (Archive)

This work investigates the effect of bulk temperature and the tribological performance of a number of symmetric triblock copolymers on MSI020 commonly in metal forming. It is to determine the best bulk temperature for the lubricants in order to apply in metal fOlming application. The triblock polymers are temperature dependant'. The polymers can be compeletly dissolved in solution since of hydrogen bonding in certain temperature. As temperature increases, the bond is weakend and the polymer break from the water and form dispersion in the water


A Hybrid Highly Birefringent Fiber Optic Sensing System For Simultaneous Strain And Temperature Measurement, Piotr Lesiak, Ginu Rajan, Yuliya Semenova, Gerald Farrell, Anna Boczkowska, Andrzej Domanski, Tomasz Wolinski Jan 2010

A Hybrid Highly Birefringent Fiber Optic Sensing System For Simultaneous Strain And Temperature Measurement, Piotr Lesiak, Ginu Rajan, Yuliya Semenova, Gerald Farrell, Anna Boczkowska, Andrzej Domanski, Tomasz Wolinski

Faculty of Engineering and Information Sciences - Papers: Part A

A novel hybrid fiber optic sensor based on integration of polarimetric fiber sensors for simultaneous strain and temperature measurement is presented in this paper. Two types of polarimetric fibers are used: a side-hole fiber and a polarization maintaining photonic crystal fiber. The disadvantage of each sensor type can be overcome by using the sensors in a complementary manner to measure temperature independently from average strain. © 2010 Photonics Society of Poland.


Evaluation Of High Temperature Fatigue Behaviour Of P22 By Miniature Specimen Testing, M D. Callaghan, S. R Humphries, M Law, H Li, W.Y Yeung Jan 2010

Evaluation Of High Temperature Fatigue Behaviour Of P22 By Miniature Specimen Testing, M D. Callaghan, S. R Humphries, M Law, H Li, W.Y Yeung

Faculty of Engineering - Papers (Archive)

Miniature specimen testing to evaluate mechanical properties, presents a novel opportunity to undertake structural integrity assessments of in-service power generation components, by removing only a very small volume of material. In this study, high temperature fatigue testing of P22 steel was undertaken and a number of fatigue properties determined using a miniature specimen testing methodology. Good comparisons were observed between fatigue properties determined by miniature specimens and the more established standard-sized specimen testing reported in literature.


A Study Of The Continous Cooling Behaviour And Effect Of Preheat And Interpass Temperature On The Haz Of High Strength Quenched And Tempered Steel, Lenka Kuzmikova, Mark Callaghan, Nathan Larkin, Robert Scott, Robert De Jong, Huijun Li, John Norrish Jan 2010

A Study Of The Continous Cooling Behaviour And Effect Of Preheat And Interpass Temperature On The Haz Of High Strength Quenched And Tempered Steel, Lenka Kuzmikova, Mark Callaghan, Nathan Larkin, Robert Scott, Robert De Jong, Huijun Li, John Norrish

Faculty of Engineering - Papers (Archive)

In this study, the continuous cooling phase transformation behaviour of a quenched and tempered armour steel was investigated. A continuous cooling transformation diagram was constructed providing valuable information for predicting microstructural evolution and mechanical properties at different cooling rates during actual welding fabrication. Welding trials were carried out utilising flux-cored arc welding technique in combination with an austenitic stainless steel consumable. The effect of various preheat and interpass temperatures on cooling rate and consequently on the heat affected zone microstructure and mechanical properties of multipass welds were investigated.


Vertical Absorption Edge And Temperature Dependent Resistivity In Semihydrogenated Graphene, Lei Chen, Zhongshui Ma, Chao Zhang Jan 2010

Vertical Absorption Edge And Temperature Dependent Resistivity In Semihydrogenated Graphene, Lei Chen, Zhongshui Ma, Chao Zhang

Faculty of Engineering - Papers (Archive)

We show that for graphene with any finite asymmetry in the on-site energy between the two sublattices (Δ), the optical absorption edge is determined by the Δ. The universal conductance will be broken and the conductance near the band edge varies with frequency as 1/ω2. The onset conductance is σc = 2σ0 = πe2/2h, independent of the size of the band gap. The total integrated optical response is nearly conserved despite of the opening of the band gap. Moreover, near the band edge, there is a change over of …


Reaction Of The C2h Radical With 1-Butyne (C4h6): Low Temperature Kinetics And Isomer-Specific Product Detection, Satchin Soorkia, Adam J. Trevitt, Talitha M. Selby, David L. Osborn, Craig A. Taatjes, Kevin R. Wilson, Stephen R. Leone Jan 2010

Reaction Of The C2h Radical With 1-Butyne (C4h6): Low Temperature Kinetics And Isomer-Specific Product Detection, Satchin Soorkia, Adam J. Trevitt, Talitha M. Selby, David L. Osborn, Craig A. Taatjes, Kevin R. Wilson, Stephen R. Leone

Faculty of Science - Papers (Archive)

No abstract provided.


Magnetotransport Of La0.70ca0.3-Xsrxmno3(Ag): A Potential Room Temperature Bolometer And Magnetic Sensor, V P. Awana, Rahul Tripathi, Neeraj Kumar, H Kishan, G V. Bhalla, Rong Zeng, L.S Sharth Chandra, V Ganesan, H U. Habermeier Jan 2010

Magnetotransport Of La0.70ca0.3-Xsrxmno3(Ag): A Potential Room Temperature Bolometer And Magnetic Sensor, V P. Awana, Rahul Tripathi, Neeraj Kumar, H Kishan, G V. Bhalla, Rong Zeng, L.S Sharth Chandra, V Ganesan, H U. Habermeier

Australian Institute for Innovative Materials - Papers

Here we report the optimized magnetotransport properties of polycrystalline La0.70Ca0.3−xSrxMnO3 and their composites with Ag. The optimization was carried out by varying the Sr and Ag contents simultaneously to achieve large temperature coefficient of resistance (TCR) as well as low field magnetoresistance (MR) at room temperature. Sharpest paramagnetic (PM)-ferromagnetic (FM) and insulator-metal (IM) transition is observed in the vicinity of the room temperature (TC≈300 K ≈TIM) for the composition La0.70Ca0.20Sr0.10MnO3:Ag0.20. Partial substitution of larger Sr2+ ions at the …