Digital Commons Network^™

Evaluation Of Characterization Techniques For Beneficial Use Of Underutilized Slag Materials, Thomas Sandy Weymouth

Master's Theses and Capstones

Wisely using byproduct materials in beneficial use applications such as highway construction is becoming more important in the United States as virgin materials are depleted and landfill capacity declines. Slags are byproducts of the steel and iron industries found in the Midwestern United States. Historically, many of these materials have historically been used in construction applications, but methods for characterizing their environmental risk are limited. This research considers a series of steps used to identify whether a particular slag poses an environmental or human health risk. The first step involves identifying the appropriate use of the material. The second step …

Improving The Policy Making Process In Municipal Solid Waster Management: Learning From Minamata-City, Japan, Rika Ikemoto

Master's Theses and Capstones

Many countries, especially industrialized countries, are facing a crisis in municipal solid waste (MSW) problems due to its ever increasing amount and related problems such as limited dumping space, transboundary waste movement, financial pressures, and dioxin problems. In Japan, one of those industrialized countries, while national MSW policies have not appeared effective, some municipalities have established remarkable policies to reduce MSW Minamata-city, which has a unique experience of environmental pollution, known as Minamta-disease, has reduced waste with the two major MSW policies: a Recycling Program; and the Food-containers Abolition Project of the Women's Committee on Waste Reduction, based on the …

Optimization Of Pcb Dechlorination With Palladized Magnesium In Marine And Freshwater Sediments, Irina Calante

Master's Theses and Capstones

Polychlorinated biphenyls (PCBs) are one of the most persistent and toxic pollutants in our environment today. Many rivers and lakes were heavily polluted with PCBs during the 1970s when their use and production was at their highest demand. Today, more than 30 years after they have been banned from production they continue to be one of the top priority contaminants. Their characteristic stability has made them very recalcitrant to physical, chemical and biological degradation. Remediation in soils and sediments are particularly more difficult due to the variability in the soil and sediment characteristics that affect how strongly PCBs are sorbed. …

Treatment Of Dioxin/Furan And Pcn Contaminated Sediments With Palladized Magnesium, Linda M. Rauch

Master's Theses and Capstones

Sediments contaminated with dioxins/furans and polychlorinated naphthalenes (PCNs) have been the subject of little study although they are equal, if not more significant, contributors than PCBs to toxicity at selected sites. The reaction of a bimetal catalyst, palladized magnesium (Mg/Pd, 0.01% by weight Pd) with these contaminants was studied in solvents and sediments.

The reaction for single congeners in solvent resulted in 69-95% removal in 30 minutes. The detection of dibenzo-p-dioxin for the dioxin reaction and naphthalene/tetralin for the PCN reaction demonstrated dechlorination. A 24 hour sediment reaction with Mg/Pd resulted in 48% and 71% reduction for spiked sediments (500 …

Degradation Of Methyl Tert Butyl Ether, Priya Saripalli

Master's Theses and Capstones

Methyl tertiary butyl ether (MTBE) is the most common oxygenated fuel additive used in gasoline to improve combustion and reduce air emissions. MTBE is commonly found in natural water as contaminate from gasoline spills. Remediation of the contaminated water is difficult by traditional treatments. In this thesis, degradation of MTBE using Fenton's reaction was studied. The effect of pH, concentration of ferric ammonium sulfate and hydrogen peroxide on the removal efficiency of MTBE was studied and optimum conditions were determined experimentally. A maximum conversion of 90% was achieved when 0.14 M MTBE was reacted with 1.1 g/L ferric ammonium sulfate …

The Role Of The Schmutzdecke In Escherichia Coli Removal In Slow Sand And Riverbank Filtration, Michael C. Unger

Master's Theses and Capstones

A series of studies was conducted on laboratory scale sand columns under varying operational and design conditions with spiked concentrations of E. coli to investigate the role of the schmutzdecke, a biologically active layer that develops at the interface of the water and filter in slow sand filtration (SSF) and riverbank filtration (RBF). Results confirmed that E. coli removals in slow-rate biological filters occur primarily at the interface and are related to schmutzdecke ripening state, empty bed contact time, biological activity, temperature, and protistan abundance. Using a suite of analyses characterizing the biofilm growing on the schmutzdecke, no connection was …

Performance Assessment Of Porous Asphalt For Stormwater Treatment, Joshua F. Briggs

Master's Theses and Capstones

The objective of this study is to assess the stormwater management capability of porous asphalt (PA) as a parking lot in Durham, New Hampshire. The site was constructed in 2004 and consists of a 4-inch PA pavement course overlying a porous media reservoir, including a fine-grained filter course. Cost per PA parking space ($2,200) was comparable to that for dense mix asphalt ($2,000). Pavement durability has been adequate. The lot retained or infiltrated 25% of precipitation (18 months) and 0.03 lb/sf of chloride (1 year). There was high initial surface infiltration capacity (IC) at two locations (1,000--1,300 in/hr), and moderate …