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University of Connecticut

Master's Theses

Theses/Dissertations

2019

Anion exchange membranes

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Liquid Crystalline Brush-Like Imidazolium Co-Polymer Membranes For Energy Conversion, Edirimuni Iyomali Abeysekera Aug 2019

Liquid Crystalline Brush-Like Imidazolium Co-Polymer Membranes For Energy Conversion, Edirimuni Iyomali Abeysekera

Master's Theses

Anion exchange membrane (AEM) research is primarily focused to develop suitable AEMs with high ion conductivity for high pH and high-temperature environments used in water electrolysis and fuel cells. To address these issue research has been done on improving the ion exchange head group to obtain high ion conductivity and designing a rational polymer architecture to improve chemical and mechanical stability.

Most widely used ionic head groups are based on quaternary ammonium ions due to its high ion conductivity. However quaternary ammonium ion containing membranes degrades with time resulting in low ion exchange capacity (IEC) and low alkaline stability due …