Digital Commons Network^™

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Sedimentary Provenance Of The Wedington Member, Fayetteville Shale, From Age Relations Of Detrital Zircons, William Tyson Cains

Graduate Theses and Dissertations

U-Pb geochronology of detrital zircons collected from the Chesterian Wedington Sandstone allows interpretation of sediment provenance and dispersal patterns in the southern midcontinent during the Late Mississippian. Detrital zircons analyzed from six samples of Wedington Sandstone yielded a final result of 565 concordant analyses used for interpretation. Results are plotted as Probability-Density Plots to interpret the spectrum of ages. Significant peaks occurred at 350-500 Ma, 950-1250 Ma, 1300-1500 Ma, 1600-1800 Ma, 1800-2300 Ma, and >2500 Ma. These peaks are interpreted as sourced by crystalline rocks within the Laurentian craton from Taconic-Acadian, Grenville, Midcontinent Granite-Rhyolite, Yavapai-Mazatzal, Paleoproterozoic, and Superior Provinces. The …

Bedrock Geological Map Of The Rockhouse Quadrangle, Carroll And Madison Counties, Arkansas, Douglas Eben Jones

Graduate Theses and Dissertations

A digital geologic map of the Rockhouse quadrangle, Carroll and Madison counties, Arkansas, was created on a 1:24,000 scale using ArcMap 10 and Photoshop CS4. The data obtained in the field are digitized onto the United States Geological Survey (USGS) digital raster graphic (DRG) of the Rockhouse quadrangle. The geology in the Rockhouse quadrangle consist entirely of sedimentary rocks that are Paleozoic ranging from Lower Ordovician to Mississippian in age. The Ordovician System is represented by the Cotter, Powell, Everton, and St. Peter Formations. The Cotter and Powell are the prominent bluff forming units throughout the quadrangle and along the …

Assessment Of The Predictive Reliability Of A Swat Flow Model And The Evaluation Of Runoff Generation And Bmp Effectiveness In A Shale-Gas Impacted Watershed Using A Modeling Approach, Kwasi Asante

Graduate Theses and Dissertations

In order to ensure a harmonious harness of shale-gas resources while ensuring minimal damage to the environment, it is imperative that studies to conduct to inform various aspects of managing the environment. This includes the development of reliable hydrologic models to inform in decisions concerning water and the environment.

The first objective of this study was to evaluate the predictive reliability of the Soil and Water Assessment Tool (SWAT) model based on respective methods of LULC data classification and data type spatial resolution. Results showed that the high-resolution data classified with object-oriented image method does not provide any significant advantage …

Bacterially-Mediated Formation Of Rock Coatings In Kärkevagge, Swedish Lapland: A Mineralogical And Micro-Environmental Analog For Mars, Cassandra L. Marnocha

Graduate Theses and Dissertations

The search for past or present life on Mars is, for now, limited to surface environments. An often neglected surface environment that could have served as an abode for life and could presently preserve evidence of that life is that of rock coatings. Rock coatings are mineral accretions on rock surfaces. On Earth, they are widespread and occur with considerable chemical diversity. There is growing evidence for a biotic role in their formation on Earth, particularly with respect to rock varnish. As a result, rock varnish has become a target of astrobiological interest on Mars, where varnish-like coatings have been …

Archaeological Geophysics, Excavation, And Ethnographic Approaches Toward A Deeper Understanding Of An Eighteenth Century Wichita Site, Michael Don Carlock

Graduate Theses and Dissertations

This research exemplifies a multidirectional approach to an archaeological interpretation of an eighteenth century Wichita village and fortification located on the Red River bordering Oklahoma and Texas. A battle that is believed to have occurred at the Longest site (34JF1) in 1759 between Spanish colonials and a confederation of Native Americans led to several Spanish primary documents describing the people that lived there, the fortification and surrounding village, and of course the battle itself. Investigation of the Longest site (34JF1) in Oklahoma presents a remarkable opportunity to combine extensive historical research, archaeological prospecting using geophysics, and traditional excavation techniques in …

Hydrogeology And Chemical Characterization Of Hydrocarbon In Domestic Water Wells, Rancho Villa Subdivision, Rogers, Arkansas, Janelle Renee Sherman

Graduate Theses and Dissertations

This project is centered on the Rancho Villa community in Rogers, Arkansas where several residents have had hydrocarbon contamination in their domestic water wells. The goal of this project was to understand the hydrogeology in the study area, characterize the contaminant chemically, and determine the source of the contaminant. The hydrogeology of the area was determined from previous theses. Seventeen samples were taken from the wells in the Rancho Villa community; each sample was analyzed for geochemical parameters and by Gas Chromatography/Mass Spectrometry (GC/MS) for organic compounds analysis. Four of the 17 samples had a visible non-aqueous layer of hydrocarbon …

Infrared Spectra Analysis Of Thermally Altered Iron Phyllosilicates And The Implications For Mars, William Thomas Bryan

Graduate Theses and Dissertations

This study looks at two iron-rich phyllosilicates, which may be present on Mars. The minerals, greenalite and hisingerite, are rich in iron-II and iron-III, respectively. Small samples (~0.40 grams) of each mineral were crushed and heated in a Lindberg Tube Oven for approximately twenty-four hours at temperatures selected to mimic lava flows and impact events. Following heating, each sample was placed in a Fourier Transform Infrared (FT-IR) spectrometer to collect the near- and mid-infrared spectra. The spectra allowed for these terrestrial analogs to be analyzed with regards to how their structure breaks down with increasing temperature. The samples' colors were …

Design And Evaluation Of A Fiber Optic Probe As A Means Of Subsurface Planetary Exploration, Robert Paul Pilgrim

Graduate Theses and Dissertations

The Optical Probe for Regolith Analysis (OPRA) is an instrumentation concept designed to provide spectroscopic analysis of the near subsurface of unconsolidated regolith on bodies such as moons, asteroids and planets. Below a chemically altered surface may lay the geological history in the form of stratigraphy that is shielded from degradation due to harsh external environments. Most of what we know about our solar system comes from remote platforms, such as satellites that are deployed into orbit around the target body. In the case of Mars, we have had several successful landers and rovers however, with the exception of the …

The Interactive Effects Of Multiple Stressors On Lithobates Catesbeianus And Anaxyrus Americanus, Matthew Kyle Holden

Graduate Theses and Dissertations

Amphibian populations worldwide have experienced dramatic declines, and many species have already become locally, regionally, or globally extirpated with thousands more being threatened with extinction. These declines have occurred more rapidly in amphibians than any other group of vertebrates, which is especially concerning to scientists because amphibians serve as indicator species of overall environmental health. Major causes for amphibian declines are discussed in Chapter 1 and include: habitat modification and destruction, commercial over-exploitation, introduced species, environmental contaminants, global climate change, and infectious diseases.

Chapter 2 discusses the major research aspects of the thesis by examining the interactive effects of multiple …

Dammed Arkansas: Early Developments In How Arkansas Came To Be A Dammed State, 1836-1945, Mary Suter

Graduate Theses and Dissertations

The need to manage the rivers of Arkansas has been a driving force in developments that have resulted in dramatic changes to the geographical "face" of Arkansas over the last 200 years. These changes are the creation of man-made lakes throughout the state, where before, there had been none. The many lakes that dot the Ozarks and the Ouachitas were created by dams. There are 1,251 dams over 25 feet in height, or that impound more that 50 acre-feet of water, in Arkansas, and uncounted smaller dams. No matter their size, dams were constructed to manage the rivers and streams …

A Geomechanical Study Of The Mississippian Boone Formation, Karen Nicole Mason Buckland

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas is a chert-limestone sequence analogous to the subsurface Mississippi Lime reservoir in parts of Oklahoma and Kansas. It has low permeability and produces via horizontal drilling and hydraulic fracturing. The response to stimulation by fracturing is dependent on the quantity of chert in the area. Chert nodules and laterally extensive chert layers in the sequence are variable. Locally, cm- to dm-scale chert bedding is continuous and comprises up to 50% of the outcrop. Elsewhere, the chert is nodular and intermittent.

Samples collected from representative outcrops spanning the thickness and aerial extent of the formation …

Insights Into The Timing, Origin, And Deformation Of The Highland Mountains Gneiss Dome In Southwestern Montana, Usa, Lane Markes Boyer

Graduate Theses and Dissertations

The Highland Mountains of southwestern Montana offer a unique view of the Archean igneous and metamorphic rocks within the Great Falls tectonic zone (GFTZ). A Paleoproterozoic structural gneiss dome has been interpreted in the southern extent of the Highland Mountains. The ∼ 130km² of exhumed metamorphic rocks and gneiss dome exposed in the Highland Mountains are the primary focus of this research. The formation of the Highland Mountains gneiss dome is proposed to be directly related to a northwest-side down detachment (the Steels Pass shear zone) that formed during terrane collision along the GFTZ. The field investigation determined foliation …

Analysis Of Tripolitic Chert In The Boone Formation (Lower Mississippian, Osagean), Northwest Arkansas And Southwestern Missouri, Paul Marchand Minor

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas and southwestern Missouri exposes a nearly complete sequence of Lower Mississippian chert-bearing carbonates deposited by a single 3rd order transgression and regression. An abundant amount of chert that has replaced limestone highlights the Boone, but little is understood about the timing and development of chert in Lower Mississippian carbonates. Interpretation of the diagenetic history of the chert, in particular tripolite, has significant implications beyond the outcrop. Determining the origin, timing, and extent of tripolitic chert in the Lower Mississippian System improves reservoir characterization in subsurface petroleum reservoirs in the mid-continent that are laterally equivalent …

Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins

Graduate Theses and Dissertations

The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …

Using The Ceres-Maize Model To Create A Geographically Explicit Grid Based Estimate Of Corn Yield Under Climate Change Scenarios, Ryan Zachary Johnston

Graduate Theses and Dissertations

The CERES-Maize model was evaluated in its capacity to predict both regional maize yield and water use within the United States Department of Agriculture (USDA) Economic Research Service (ERS) Region 1 between the years 1997-2007. A grid based, geospatially explicit method was developed to express the various rainfed and irrigated maize cultivars grown across the region. Overall, the calibrated model compared well for both physiological and yield parameters, producing significant linear relationships (p

The calibrated and validated CERES-Maize model was used to predict potential evapotranspiration and yield under three IPCC weather scenarios for the year 2050 to evaluate crop production …

Battle Mound: Exploring Space, Place, And History Of A Red River Caddo Community In Southwest Arkansas, Duncan Mckinnon

Graduate Theses and Dissertations

This research is a synthesis of archaeogeophysical and archaeohistorical data collected from the Battle Mound site (3LA1). Using these data, this research seeks to understand how the site is organized in terms of architectural variability and how differential use areas, such as domestic or community space, can be compared to ethnographic and archaeological data concerning Caddo community structure and landscape use. The research is formulated around three research questions related to spatial organization and settlement patterning, intrasite behavioral practices, and Caddo culture history. Results show that an examination at multiple scales of resolution can inform about the spatial organization and …

Subsurface Stratigraphy And Characterization Of Mississippian (Osagean To Meramecian) Carbonate Reservoirs Of The Northern Anadarko Shelf, North-Central Oklahoma, Brett Robert Wittman

Graduate Theses and Dissertations

Mississippian carbonate strata of the midcontinent contain prolific oil and gas reservoirs. Production from these carbonates has been primarily from two reservoir types, the Mississippi "chat" and recently denser chert-rich mudstone intervals. The"chat" interval is a high porosity chert residuum associated with the both the Osagean and basal Pennsylvanian unconformity. The distribution of the "chat" reservoir is discontinuous and heterogeneous. Recent horizontal drilling successes have reinvigorated academic and industry interest in the Lower Mississippian. Much of the activity is now targeting lower porosity, cherty, mudstone intervals of the Reeds Spring and Cowley Formations, which were previously considered to be non-economic. …

Classification Of Satellite Time Series-Derived Land Surface Phenology Focused On The Northern Fertile Crescent, Brian Embree Bunker

Graduate Theses and Dissertations

Land surface phenology describes events in a seasonal vegetation cycle and can be used in a variety of applications from predicting onset of future drought conditions, to revealing potential limits of historical dry farming, to guiding more accurate dating of archeological sites. Traditional methods of monitoring vegetation phenology use data collected in situ. However, vegetation health indices derived from satellite remote sensor data, such as the normalized difference vegetation index (NDVI), have been used as proxy for vegetation phenology due to their repeated acquisition and broad area coverage. Land surface phenology is accessible in the NDVI satellite record when images …

Agricultural Production And Stability Of Settlement Systems In Upper Mesopotamia During The Early Bronze Age (Third Millennium Bce), Tuna Kalayci

Graduate Theses and Dissertations

This study investigates the relationship between rainfall variation and rain-fed agricultural production in Upper Mesopotamia with a specific focus on Early Bronze Age urban settlements. In return, the variation in production is used to explore stability of urban settlement systems. The organization of the flow of agricultural goods is the key to sustaining the total settlement system.

The vulnerability of a settlement system increases due to the increased demand for more output from agricultural lands. This demand is the key for the success of urbanization project. However, without estimating how many foodstuffs were available at the end of a production …

On Chlorine Salts: Their Detection, Stability And Implications For Water On Mars And Europa, Jennifer Hanley

Graduate Theses and Dissertations

Chlorine salts (e.g. chlorides, chlorates and perchlorates) are an important factor in the stability of water on the surfaces of planetary bodies. Here we have shown that perchlorate and chlorate salts will lower the freezing point of water, allowing it to be liquid down to ~204 K. These salts will also slow down the evaporation rate, extending the lifetime of the liquid water solution. Chlorine salts have been detected on Mars, which has significant implications for the stability of water and hence its habitability. To study their effects on the stability of water on planetary surfaces, we need to first …

Litter Conditioning Is Differentially Affected By Leaf Species, Phosphorus Enrichment, And Light Availability, Erin E. Scott

Graduate Theses and Dissertations

Anthropogenic enrichment of nitrogen and phosphorus is one of the most pervasive and detrimental threats to aquatic ecosystems worldwide. In streams that rely on allochthonous basal food resources, such as leaves, nutrient pollution can result in altered food quality and decreased carbon (C) standing stocks. However, the magnitude and mechanisms of this change in quality are poorly understood. Laboratory microcosm studies were conducted to 1) quantify the response of litter C:P to a gradient of phosphorus (P) enrichment (0, 0.05, and 0.5 mg SRP/L) across leaf species with variable levels of degradability (sugar maple and oak), and 2) quantify the …

Geophysical Surveys And Archaeological Insights At Fort Pierre Chouteau A Frontier Trading Post On The Middle Missouri, Margaret Maurine Patton

Graduate Theses and Dissertations

Fort Pierre Chouteau in present day South Dakota was the most important fur trading post of the American Fur Company in the 1830s, serving as a regional hub for the fur trade. The Fort was sold to the U.S. Military in 1855 for use as a base in the Sioux Wars but was abandoned in 1856. Geophysical surveys and previous excavations indicate evidence of both occupations. Geophysics is an important tool for determining the extent of archaeological sites, yet the relationships between geophysical anomalies and excavation features may not be readily evident. Initial geophysical surveys (Kvamme 2007) were completed to …

Magnesium Isotopic Compositions Of The Moon And Achondrites: Implications For Their Origin And Evolution, Fatemeh Sedaghatpour

Graduate Theses and Dissertations

The main objectives of this thesis are to estimate Mg isotopic compositions of the Moon and achondrites, to understand the behavior of Mg isotopes during magmatic differentiation processes in different planetary bodies, and to evaluate the extent of Mg isotopic heterogeneity in the solar system. In order to achieve these goals, Mg isotopes have been measured for 47 well-characterized lunar samples and 22 differentiated meteorites by MC-ICPMS. The limited Mg isotopic variations among mare and highland regolith, mare breccias, and highland impact-melt rocks reflect negligible Mg isotope fractionation during lunar surface processes (e.g. solar wind, cosmic rays, micrometeorite bombardments, meteorite …

Landscape Epidemiology And Machine Learning: A Geospatial Approach To Modeling West Nile Virus Risk In The United States, Sean Gregory Young

Graduate Theses and Dissertations

The complex interactions between human health and the physical landscape and environment have been recognized, if not fully understood, since the ancient Greeks. Landscape epidemiology, sometimes called spatial epidemiology, is a sub-discipline of medical geography that uses environmental conditions as explanatory variables in the study of disease or other health phenomena. This theory suggests that pathogenic organisms (whether germs or larger vector and host species) are subject to environmental conditions that can be observed on the landscape, and by identifying where such organisms are likely to exist, areas at greatest risk of the disease can be derived. Machine learning is …