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South Dakota State University

Theses/Dissertations

2017

Pyrolysis

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Lignin Transformation And Characterization Of Pyrolytic Products, Eric Amo Boakye Jan 2017

Lignin Transformation And Characterization Of Pyrolytic Products, Eric Amo Boakye

Electronic Theses and Dissertations

Lignocellulosic materials derived from plants have the ability to serve as feedstocks in place of depleting petroleum and coal for production of fuels and chemicals. Lignin forms about 30% of lignocellulosic material, and is the second most abundant non-fossil organic carbon source in the biosphere. However, it is often treated as waste or, in some instances, burned to supply energy. Developing an efficient and environmentally benign method to convert lignin to high value-added aromatic monomers (e.g., guaiacol, vanillin, acetovanillone, and eugenol) for synthesis of polymers is of interest. Mineral bases, such as NaOH and CsOH, or supported-metal catalysts (Pt, Ru, …


Understanding The Impacts Of Ammonia Fiber Expansion (Afex™) Pretreatment And Densification On Densified Products Quality And The Bioproducts Yield Through Enzymatic Hydrolysis And Fast Pyrolysis, Vijay Sundaram Jan 2017

Understanding The Impacts Of Ammonia Fiber Expansion (Afex™) Pretreatment And Densification On Densified Products Quality And The Bioproducts Yield Through Enzymatic Hydrolysis And Fast Pyrolysis, Vijay Sundaram

Electronic Theses and Dissertations

Lignocellulosic biomass poses significant challenges during handling, transportation, and storage due to its low bulk density. Densification involves conversion of the low bulk density biomass into a highly compacted product which helps in improving the handling, transporting, and storage obstacles associated with biomass logistics. Besides the logistical challenges, the recalcitrant nature of the lignocellulosic biomass makes it even more challenging during the enzymatic hydrolysis. The carbohydrate components, cellulose and hemicellulose are not readily accessible by the enzymes during the hydrolysis process due to the presence of lignin. Pretreatment is the process to convert the native recalcitrant biomass in the form, …