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Eastern Kentucky University

2006

Methane oxidation

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Data Report: Dissolved Sulfide Concentration And Sulfur Isotopic Composition Of Sulfide And Sulfate In Pore Waters, Odp Leg 204, Hydrate Ridge And Vicinity, Cascadia Margin, Offshore Oregon, Walter S. Borowski Sep 2006

Data Report: Dissolved Sulfide Concentration And Sulfur Isotopic Composition Of Sulfide And Sulfate In Pore Waters, Odp Leg 204, Hydrate Ridge And Vicinity, Cascadia Margin, Offshore Oregon, Walter S. Borowski

EKU Faculty and Staff Scholarship

We report dissolved sulfide sulfur concentrations and the sulfur isotopic composition of dissolved sulfate and sulfide in pore waters from sediments collected during Ocean Drilling Program Leg 204. Porewater sulfate is depleted rapidly as the depth to the sulfate/methane interface (SMI) occurs between 4.5 and 11 meters below seafloor at flank and basin locations. Dissolved sulfide concentration reaches values as high as 11.3 mM in Hole 1251E. Otherwise, peak sulfide concentrations lie between 3.2 and 6.1 mM and occur immediately above the SMI. The sulfur isotopic composition of interstitial sulfate generally becomes enriched in 34 S with increasing sediment depth. …