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Dynamics Of Chemical Degradation In Water Using Photocatalytic Reactions In An Ultraviolet Light Emitting Diode Reactor, John E. Stubbs
Dynamics Of Chemical Degradation In Water Using Photocatalytic Reactions In An Ultraviolet Light Emitting Diode Reactor, John E. Stubbs
Theses and Dissertations
This work examined ultraviolet (UV) light emitting diodes (LED) and hydrogen peroxide in an advanced oxidation process in support of a USAF installation net zero water initiative. A UV LED reactor was used for degradation of soluble organic chemicals. There were linear relationships between input drive current, optical output power, and first order degradation rate constants. When drive current was varied, first order degradation rates depended on chemical identities and the drive current. When molar peroxide ratios were varied, kinetic profiles revealed peroxide-limited or radical-scavenged phenomena. Molar absorptivity helped explain the complexity of chemical removal profiles. Degradation kinetics were used …
Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner
Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner
Theses and Dissertations
Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of …