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Direct Spectroscopic Observation Of Cross-Plane Heat Transfer In A Two-Dimensional Van Der Waals Heterostructure, Du Chen, Matthieu Fortin-Deschênes, Yuchen Lou, Huiju Lee, Kenji Watanabe, Takaaki Taniguchi, Fengnian Xia, Peijun Guo, Multiple Additional Authors

Mechanical and Materials Engineering Faculty Publications and Presentations

Two-dimensional (2D) transition metal chalcogenides (TMDs) have drawn significant attention in recent years due to their extraordinary optical and electronic properties. As heat transfer plays an important role in device performance, various methods such as optothermal Raman spectroscopy and time-domain thermoreflectance have been developed to measure the thermal conductivity and interfacial thermal conductance in 2D van der Waals (vdW) heterostructures. Here, we employ the vibrational-pump-visible-probe (VPVP) spectroscopy to directly visualize the heat transfer process in a heterostructure of multilayer h-BN and monolayer WS2. Following an impulsive vibrational excitation of h-BN in the mid-infrared, we probe the heat transfer …

Preparation And Characterization Of Copper-Doped And Silver-Doped Titanium Dioxide Nano-Catalysts For Photo Catalytic Applications, Haya Abdel Ra’Ouf Ahmed Ra’Ouf Ahmed

Theses

The goal of this work was to improve the performance of TiO2 nanomaterials by increasing their optical activities by shifting the onset of the response from the UV to the visible-light region. Among the several ways to achieve this goal, doping TiO2 nanomaterials with other elements (e.g. metals) was selected to narrow the band gap and enhance the optical properties of TiO2 nanomaterials. In this work, we have prepared Cu-doped TiO2 and Ag-doped TiO2 nano-catalysts, characterized them and studied their properties, and the optical ones in particular. The Ag-doped TiO2 catalyst was prepared by the sol-gel method while the Cu-doped …

Spotlight On Available Optical Properties And Models Of Nanofluids: A Review

Faculty of Engineering University of Malaya

Optical characteristics besides unique thermo-physical properties of nanoparticles have encouraged researchers to use nanofluids in solar energy collectors or reservoirs as electromagnetic wave absorbing media. Recently, different analyses and approaches have been proposed by researchers. However, the appropriate electro-magnetic phenomenon of nanofluids is not established till date because of the complex dependence between nanoparticles and base fluids. In this work, optical properties of nanofluids are discussed on the basis of published data; mostly used models are presented along with their limitations and applications. (C) 2014 Elsevier Ltd. All rights reserved. Link to Full-Text Articles : http://www.sciencedirect.com/science/article/pii/S1364032114009411

Nanometric Structure-Property Relationship In Hafnium Oxide Thin Films Made By Sputter-Deposition, Mirella Vargas

Open Access Theses & Dissertations

Hafnium oxide (HfO2) is technologically an important material, which exhibits a unique set of properties such as a high dielectric constant (k~25) and wide band gap (~5.7 eV) which make this material attractive in the fields of microelectronics and optoelectronics. HfO2 has become the leading candidate to replace SiO2 dielectrics in gate oxides due to a higher permittivity and reportedly lower electron tunneling effects. HfO2 exhibits various polymorphs; the thermodynamic stability and phase existence depends on the temperature and pressure conditions. In addition, the controlled growth and manipulation of specific HfO2 crystal structures at the nanoscale dimensions is the driving …

Polarization Sensitive Near-Complete Reflection From Photonic Crystal Slab In Centered Rectangular Lattice, Simon Padron, Kris Ohlinger, Karen Lozano, Yuankun Lin

Mechanical Engineering Faculty Publications and Presentations

In this study, reflective properties have been systematically calculated for two-dimensional photonic crystal slabs in centered rectangular lattices with elliptical patterns for transverse electric polarization along perpendicular x- and y-directions. The slab structures can be geometrically optimized for a near-complete reflection over a broad wavelength range. The reflection from the photonic crystal slabs is polarization selective, allowing a complete reflection for one polarization and complete transmission for the other polarization, which could be useful for a laser cavity mirror without using Brewster windows. The dependence of the reflection on the slab thickness and the structural parameters demonstrates the effect of …

Influence Of Ni Nanoparticle On The Morphology And Growth Of Interfacial Intermetallic Compounds Between

A.S. Md Abdul Haseeb

TiO2 thin films were deposited on unheated and heated glass substrates at an elevated sputtering pressure of 3 Pa by radio frequency (RF) reactive magnetron sputtering. TiO2 films deposited at room temperature were annealed in air for 1 h at various temperatures ranging from 300 to 600 °C. The structural and optical properties of the thin films were investigated using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and ultraviolet-visible-near infrared (UV-VIS-NIR) spectrophotometry. XRD results show that as-grown and post-annealed TiO2 films have anatase crystal structure. Higher substrate and annealing temperatures result in a slight increase of crystallinity. TiO2 …

Investigations On Tio2 And Ag Based Single And Multilayer Films For Window Glazings

A.S. Md Abdul Haseeb

In this investigation, TiO2 and Ag based single and multilayer-films were deposited on microscope glass slides with varying individual layer thicknesses by radio-frequency reactive magnetron sputtering. Prior to multilayer development, single layers of Ag and TiO2 were deposited and characterized. All the films were prepared at an elevated pressure of 3 Pa at room temperature. It was found that single layer of TiO2 showed anatase polycrystalline structure. It also exhibited high visible transmittance of above 80% and higher refractive index of 2.31 at a wavelength of 550 nm. The indirect optical band gap of the TiO2 films was estimated as …

Influence Of Substrate Temperatures On Structural, Morphological And Optical Properties Of Rf-Sputtered Anatase Tio 2 Films

A.S. Md Abdul Haseeb

In this investigation, TiO 2 thin films were deposited on glass substrates at varying substrate temperatures from room temperature to 300 °C by radio-frequency (RF) magnetron sputtering at an elevated sputtering pressure of 3 Pa. As-deposited TiO 2 films were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), field emission Auger electron microscopy (FEAES), and UV-visible-NIR spectrophotometry. The XRD results reveal that all the as-deposited films possessing the anatase structure and crystallinity of TiO 2 films appears to deteriorate slightly at higher substrate temperatures. The crystallite size of the as-deposited films at different substrate temperatures …

Optical Properties Of Semiconducting Boron Carbide For Neutron Detection Applications, Ravi B. Billa

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Solid state neutron detection devices based on semiconducting boron carbide have the potential for nearly ideal neutron detection effciency for thermal neutrons. The present work is focused on characterizing optical properties of this semiconducting boron carbide material as a step in further development of the material for neutron detection and other applications.

Semiconducting boron carbide films were grown on silicon substrates using plasma enhanced chemical vapor deposition and their optical properties were characterized using variable angle spectroscopic ellipsometry over a wide spectral range, from mid-infrared to vacuum-ultraviolet wavelengths. The effects of deposition substrate temperature and of post-deposition heat treatments on …

Effects Of Annealing Treatment On Optical Properties Of Anatase Tio 2 Thin Films

A.S. Md Abdul Haseeb

In this investigation, anatase TiO 2 thin films were grown by radio frequency magnetron sputtering on glass substrates at a high sputtering pressure and room temperature. The anatase films were then annealed at 300-600 °C in air for a period of 1 hour. To examine the structure and morphology of the films, X-ray diffraction (XRD) and atomic force microscopy (AFM) methods were used respectively. From X-ray diffraction patterns of the TiO 2 films, it was found that the as-deposited film showed some differences compared with the annealed films and the intensities of the peaks of the crystalline phase increased with …