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Molecular Dynamics Modeling Of Polymers For Aerospace Composites, Swapnil Sambhaji Bamane

Dissertations, Master's Theses and Master's Reports

Polymer matrix composite materials are widely used as structural materials in aerospace and aeronautical vehicles. Resin/reinforcement wetting and the effect of polymerization on the thermo-mechanical properties of the resin are key parameters in the manufacturing of aerospace composite materials. Determining the contact angle between combinations of liquid resin and reinforcement surfaces is a common method for quantifying wettability. It is challenging to determine contact angle values experimentally of high-performance resins on CNT materials such as CNT, graphene, bundles or yarns, and BNNT surfaces. It is also experimentally difficult to determine the effect of polymerization reaction on material properties of a …

A Critical Review On The Development Of Ionic Liquids-Based Nanofluids As Heat Transfer Fluids For Solar Thermal Energy, Titan C. Paul, Amitav Tikadar, Rajib Mahamud, Azzam S. Salman, A.K.M. Monjur Morshed, Jamil A. Khan

Faculty Publications

In recent years, solar thermal energy (STE) has attracted energy researchers because of its higher efficacy compared to the photovoltaic solar cell. STE is one of the forms of solar energy whereby heat is transferred via a secondary medium called heat transfer fluids (HTFs). Therefore, the overall performance of STE depends on the thermophysical properties and thermal performance of the HTFs. Traditional HTFs suffer from low decomposition temperature, high melting point, and higher vapor pressure. To overcome these limitations, researchers have recently begun working on new HTFs for STE. Ionic liquids (ILs) are considered as a potential candidate for the …

Deformation Manifold Learning Model For Multi Walled Carbon Nanotubes, Shashank S. Pathrudkar

Dissertations, Master's Theses and Master's Reports

Two-Dimensional (2D) materials are being studied widely by researchers due to their superior material properties over the bulk materials. Since the isolation of graphene in 2004, graphene has gained popularity amongst the 2D materials community. Graphene when rolled into sheets form Carbon Nanotubes (CNTs) which possess excellent mechanical and electrical properties. Concentric stacks of CNTs yield Multi-walled Carbon Nanotubes (MWCNTs) which are superior to CNTs in certain aspects. It has been well established that the deformation of CNTs and MWCNTs change their mechanical and electrical properties significantly. This has opened doors for CNTs into numerous applications and also piqued the …

Application Of Carbon Nanotube Thermophones As Duct Noise Cancelling Speakers: Using New Technology With Old Theories, Stephania M. Vaglica

Dissertations, Master's Theses and Master's Reports

Certain materials can produce sound through heat fluctuations. In recent times, the material capable of this was discovered to be Carbon Nanotubes (CNT). The idea is to create a flexible speaker that can be made into any shape or form to create sound. Once a speaker has been created, an active noise control system can be designed to cancel loud sounds in building and pipe ducts. This technology, similar to noise cancelling headphones, allows a user to create a modular system to mitigate noise in everyday life. Thus, the purpose of this research is to illustrate the abilities of a …

Active Noise Control Using Carbon Nanotube Thermophones: Case Study For An Automotive Hvac Application, Walker H. Nelson

Dissertations, Master's Theses and Master's Reports

The goal of this project was to reduce the overall noise levels emitted by the HVAC components in a vehicle’s cabin. More specifically, the feasibility of achieving this goal using two key technologies was investigated.

The first of these technologies, Active Noise Control (ANC), is a noise attenuation technique that relies on destructive interference that “cancels” unwanted noise. Typically used in situations where physical constraints prevent passive attenuation techniques from being used, ANC is known for its high size-to-effectiveness ratio. This benefit cannot be gained without a cost however; the complexity of ANC systems is significantly higher than their passive …

Peridynamic Approaches For Damage Prediction In Carbon Fiber And Carbon Nanotube Yarn Reinforced Polymer Composites, Forrest E. Baber

Theses and Dissertations

Aerospace structures are increasingly utilizing advanced composites because of their high specific modulus and specific strength. While the introduction of these material systems can dramatically decrease weight, they pose unique certification challenges, often requiring extensive experimental testing in each stage of the design cycle. The expensive and time-consuming nature of experimental testing necessitates the advancement of simulation methodologies to both aid in the certification process and assist in the exploration of the microstructure design space.

Peridynamic (PD) theory, originating from Sandia National Lab’s in the early 2000’s, is a nonlocal continuum-based method that reformulates the equation of motion into an …

Studying The Effect Of Vacancies On The Thermal Conductivity Of Metal-Coated Carbon Nanotubes Using Molecular Dynamics Atomistic Simulations, Ravindra Sunil Dhumal

Graduate Research Theses & Dissertations

Breakthroughs in nanotechnology have made it possible for the size of electronic gadgets to be scaled down to micro/nano level. What follows however, is the side effect of high power densities and overheating as the heat dissipation is restricted to very small surface area. Thus, the need of an effective thermal management system is central to these developments. One way to counter this problem is to use Thermal Interface Materials (TIMs) which promote heat transfer between heat source and sink.

Owing to their high thermal conductivity (up to 6000 W/mK), Carbon Nanotubes (CNTs) are thought of as strong candidates for …

Using Non-Destructive Testing To Predict Bending Modulus Of Carbon Infiltrated-Carbon Nanotubes, Fred Stile Fagergren

Theses and Dissertations

Fabrication of carbon infiltrated carbon nanotubes (CI-CNT) can result in large mechanical property variation, and methods to characterize properties usually involve destructive testing. Finding a non-destructive way to test for stiffness of this material reduces the number of parts that have to be made. It also simplifies testing of complex parts. The stiffness of CI-CNT beams is related to the type of carbon material infiltrated between the carbon nanotubes (CNTs), how it interacts with the CNTs, and how much of it there is. The amount of material can be estimated using the density of the beam, and both the type …

Commercialization Of The Carbon Nanotube Thermophone For Active Noise Control Applications, Steven A. Senczyszyn

Dissertations, Master's Theses and Master's Reports

The rate of commercialization for technology developed in junction with academic institutions has risen dramatically over the past 30 years. Since the introduction of the Bayh-Dole Act in 1980, the amount of intellectual property owned by academic institutions has increased exponentially, and with that, there has also been an increase in the number of university spinouts generated. However, the increase of spinouts does not match the rate of increase in intellectual property. The National Science Foundation has created the Innovation Corps (I-Corps) program to help bridge this gap and provide academic professionals and students the tools necessary to commercialize technology …

Forming A Metal Matrix Nanocomposite (Mmnc) With Fully Dispersed And Deagglomerated Multiwalled Carbon Nanotubes (Mwcnts), Mahesh Kumar Pallikonda

ETD Archive

Carbon Nanotubes (CNTs) with their exceptional properties will facilitate the Metal matrix composites (MMC) to exhibit good mechanical properties, thermal and electrical conductivities, corrosion resistance, etc. The critical factor that holds the development of the Metal matrix Nanocomposites (MMNC) by using CNTs is the tendency of CNTs to form clusters (agglomerations) due to their high Van der Waals attractions. Due to this factor, low density and other properties of the CNTs, there has been a delay in harnessing their ultimate potential.
Existing literature in contemporary times from the works of few researches in Nanocomposites shows the prevalence of using surfactants …

Carbon Nanotube Based Groundwater Remediation: The Case Of Trichloroethylene, Kshitij C. Jha, Zhuonan Liu, Hema Vijwani, Mallikarjuna Nadagouda, Sharmila M. Mukhopadhyay, Mesfin Tsige

Mechanical and Materials Engineering Faculty Publications

Adsorption of chlorinated organic contaminants (COCs) on carbon nanotubes (CNTs) has been gaining ground as a remedial platform for groundwater treatment. Applications depend on our mechanistic understanding of COC adsorption on CNTs. This paper lays out the nature of competing interactions at play in hybrid, membrane, and pure CNT based systems and presents results with the perspective of existing gaps in design strategies. First, current remediation approaches to trichloroethylene (TCE), the most ubiquitous of the COCs, is presented along with examination of forces contributing to adsorption of analogous contaminants at the molecular level. Second, we present results on TCE adsorption …

Carbon-Based Hierarchical Scaffolds For Myoblast Differentiation: Synergy Between Nano-Functionalization And Alignment, Akhil Patel, Shilpaa Mukundan, Wenhu Wang, Anil K. Karumuri, Vinayak Sant, Sharmila M. Mukhopadhyay, Shilpa Sant

Mechanical and Materials Engineering Faculty Publications

While several scaffolds have been proposed for skeletal muscle regeneration, multiscale hierarchical scaffolds with the complexity of extracellular matrix (ECM) haven’t been engineered successfully. By precise control over nano- and microscale features, comprehensive understanding of the effect of multiple factors on skeletal muscle regeneration can be derived. In this study, we engineered carbon-based scaffolds with hierarchical nano- and microscale architecture with controlled physico-chemical properties. More specifically, we built multiscale hierarchy by growing carbon nanotube (CNT) carpets on two types of scaffolds, namely, interconnected microporous carbon foams and aligned carbon fiber mats. Nanostructured CNT carpets offered fine control over nano-roughness and …

Multiwall Carbon Nanotube Arrays For Thermal Interface Enhancement, Darrell Keith Etheredge

Theses and Dissertations--Mechanical Engineering

High performance/small package electronics create difficult thermal issues for integrated circuits. Challenges exist at material interfaces due to interfacial contact resistances. Multiwall carbon nanotube (MWCNT) arrays are considered to be excellent candidates for use as thermal interface materials (TIMs) due to outstanding thermal/mechanical properties. In this work, MWCNT array TIMs are analyzed in aluminum and carbon fiber composites via flash diffusivity analysis. The effect of TIM thickness, areal/bulk density, surface cleanliness, and volumetric packing fraction; along with the effect of substrate finish and interfacial contact pressure on thermal performance are analyzed. Trends show the best TIMs possess low thickness, high …

Interfacial Thermal Conductivity Using Multiwall Carbon Nanotubes, Carissa Don Russell

University of Kentucky Master's Theses

Shrinking volume, coupled with higher performance, microprocessors and integrated circuits have led to serious heat dissipation issues. In an effort to mitigate the excessive amounts of waste heat and ensure electronic survivability, heat sinks and spreaders are incorporated into heat generating device structures. This inevitability creates a thermal pathway through an interface. Thermal interfaces can possess serious thermal resistances for heat conduction. The introduction of a thermal interface material (TIM) can drastically increase the thermal performance of the component. Exceptional thermal properties of multiwall carbon nanotubes (MWCNTs) have spurred interest in their use as TIMs. MWCNTs inherently grow in vertically-oriented, …

Manufacture, Characterization, And Application Of Multiwall Carbon Nanotube Composite Crylonitrile-Butadiene-Styrene, Daniel Ray Bortz

University of Kentucky Master's Theses

Carbon nanotubes have been studied for nearly two decades and their amazing properties continue to spur intense investigation in the area of polymer composites. In terms of potential commercialization, mutiwall carbon nanotubes (MWCNTs) are currently the most prevalent and economically viable form of nanotubes. Uncovering innovative means to take full advantage of their properties remains a fundamental issue. In this thesis, viability of their use to reinforce polymeric systems is reported. Acrylonitrilebutadiene- styrene (ABS) was used as the host matrix. MWCNTs were introduced to the ABS matrix via melt compounding. The resulting composite was thoroughly rheologically, thermally, and mechanically characterized. …