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Effect Of The Nonlinear Material Viscosity On The Performance Of Dielectric Elastomer Transducers, Yuanping Li

Electronic Thesis and Dissertation Repository

As a typical type of soft electroactive materials, dielectric elastomers (DEs) are capable of producing large voltage-induced deformation, which makes them desirable materials for a variety of applications in transduction technology, including tunable oscillators, resonators, biomimetics and energy harvesters. The dynamic and energy harvesting performance of such DE-based devices is strongly affected not only by multiple failure modes such as electrical breakdown, electromechanical instability, loss-of-tension and fatigue, but also by their material viscoelasticity. Moreover, as suggested by experiments and theoretical studies, DEs possess nonlinear relaxation processes, which makes modeling of the performance of DE-based devices more challenging.

In this thesis, …

Polymeric Pvdf Fibers For Piezoelectric Applications In Energy Harvesting, Misael E. Martinez

Theses and Dissertations

This work focuses on developing and characterizing the piezoelectric response of Cerium doped Polyvinylidene Fluoride (PVDF) fine fibers and the effects of dopants and alignment on the formation of the β-phase and consequently on the piezoelectric performance. Six sets of fiber mats were prepared varying the concentration (2.5–7.5wt%) of Cerium (III) Nitrate-Hexahydrate and Ammonium-Cerium (IV) Sulfate-Dihydrate. Fiber mats were developed using the Forcespinning® technique and the angular velocity and dopant concentration were adjusted to obtain a synergy between fiber yield and fiber diameter. Fourier Transform Infrared Spectroscopy showed a significant enhancement in the PVDF β-phase and inhibition of the non-polar …