Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Entire DC Network
Catalytic Hydrogenolysis Of Lignin Β-O-4 Aryl Ether Compound And Lignin To Aromatics Over Rh/Nb2o5 Under Low H2 Pressure, Weixiang Guan, Xiao Chen, Haoquan Hu, Chi Wing Tsang, Jie Zhang, Carol Sze Ki Lin, Changhai Liang
Catalytic Hydrogenolysis Of Lignin Β-O-4 Aryl Ether Compound And Lignin To Aromatics Over Rh/Nb2o5 Under Low H2 Pressure, Weixiang Guan, Xiao Chen, Haoquan Hu, Chi Wing Tsang, Jie Zhang, Carol Sze Ki Lin, Changhai Liang
Faculty of Science & Technology (THEi)
The increasing risk of fossil fuels depletion due to surging energy demand has accelerated the search of alternative renewable sources. Lignin, one of the major components of lignocellulosic biomass, is the only abundant renewable natural resource for aromatic compounds. In this work, the effects of metals and process parameters were discussed via the catalytic hydrogenolysis of β-O-4 lignin model compound, 2-phenethyl phenyl ether. The best results were obtained over Rh/Nb2O5 with an overall conversion of 99.3% and exceptional selectivity of 98.9% to aromatic products when the hydrogenolysis was carried out at 260 °C and 0.1 MPa H2 for 4 h. …
A Review On High Catalytic Efficiency Of Solid Acid Catalysts For Lignin Valorization, Weixiang Guan, Chi-Wing Tsang, Carol Sze Ki Lin, Christophe Len, Haoquan Hu, Changhai Liang
A Review On High Catalytic Efficiency Of Solid Acid Catalysts For Lignin Valorization, Weixiang Guan, Chi-Wing Tsang, Carol Sze Ki Lin, Christophe Len, Haoquan Hu, Changhai Liang
Faculty of Science & Technology (THEi)
It is imminent to develop renewable resources to replace fossil-derived energies as fossil resources are on the brink of exhaustion. Lignin is one of the major components of lignocellulosic biomass, which is a natural amorphous three-dimensional polymer with abundant C-O bonds and aromatic structure. Hence, valorization of lignin into high value-added liquid fuels and chemicals is regarded as a promising strategy to mitigate fossil resource shortages. Solid acid catalysts are extensively studied due to environmentally friendly in terms of the ease of separation, recovery and reduced amount of wastes. Hence, this review focuses on summarizing the recent progress of catalytic …
Nb(Ta)-Based Solid Acid Modified Pt/Cnts Catalysts For Hydrodeoxygenation Of Lignin-Derived Compounds, Weixiang Guan, Xiao Chen, Chuang Li, Jie Zhang, Chi-Wing Tsang, Haoquan Hu, Shaojie Li, Changhai Liang
Nb(Ta)-Based Solid Acid Modified Pt/Cnts Catalysts For Hydrodeoxygenation Of Lignin-Derived Compounds, Weixiang Guan, Xiao Chen, Chuang Li, Jie Zhang, Chi-Wing Tsang, Haoquan Hu, Shaojie Li, Changhai Liang
Faculty of Science & Technology (THEi)
Efficient upgrading of lignin bio-oils into oxygen-free liquid alkane fuels is a challenging task owing to the incompatibility of the phenolic feedstock with conventional fuels and the availability of effective hydrotreating catalysts based on the current refinery infrastructure. In this work, a series of solid acid nanosheets (HNbWO6, HNbMoO6, HTaWO6) modified Pt/CNTs bifunctional catalysts were evaluated in hydrodeoxygenation (HDO) of lignin-derived compounds. The effects of types of nanosheets and the synergistic effect between metal sites and acid sites were discussed via HDO of diphenyl ether. Pt/HNbWO6/CNTs catalyst exhibited the most efficient performance for the HDO of diphenyl ether to cyclohexane …