Open Access. Powered by Scholars. Published by Universities.®
- Keyword
-
- Adhesion (1)
- Antimicrobial/thermochromic (1)
- Arborescent (1)
- Bioactive Glass (1)
- Bioceramics (1)
-
- Biodegradable polymers (1)
- Butyl rubber (1)
- Catechol (1)
- Chitosan (1)
- Class II Organic/Inorganic Hybrid Biomaterials (1)
- Composites (1)
- Denture adhesive (1)
- Diethyl Fumarate (1)
- Drug Delivery (1)
- Drug release (1)
- Dual-functional (1)
- Free Radical Polymerization (1)
- Free radical polymerization (1)
- Graft copolymer (1)
- Mechanical Properties (1)
- Mussel-inspired polymer (1)
- Nanoparticles (1)
- Paclitaxel (1)
- Poly(caprolactone) (1)
- Poly(lactide) (1)
- Polyisobutylene (1)
- Protein Carrier (1)
- Reactivity ratio (1)
- Reactivity ratios (1)
- Rheological study (1)
Articles 1 - 6 of 6
Full-Text Articles in Entire DC Network
Sol-Gel Derived Bioceramic Poly(Diethyl Fumarate – Co – Triethoxyvinylsilane) Composite, Aref Sleiman
Sol-Gel Derived Bioceramic Poly(Diethyl Fumarate – Co – Triethoxyvinylsilane) Composite, Aref Sleiman
Electronic Thesis and Dissertation Repository
Synthetic bone graft materials have become an increasingly popular choice for bone augmentation. Ceramic-based and polymer-based bone graft materials constitute the two main classes of synthetic bone graft materials. This study investigated the synthesis of novel bioactive composites for their potential use as bone graft biomaterials. Poly(diethyl fumarate-co-triethoxyvinylsilane)/bioceramic class II organic/inorganic hybrid biomaterials were synthesized via a sol gel process. These biomaterials were then reacted with an ammonium phosphate solution to prepare their respective composites. For the first time, we successfully synthesized sol-gel derived bioceramic poly(diethyl fumarate-co-triethoxyvinylsilane) composites. In vitro bioactivity evaluation of poly(diethyl fumarate-co-triethoxyvinylsilane)/bioceramic composites in simulated body fluid …
Catechol-Containing Copolymers As An Active Ingredient For Denture Adhesives, Vincent Ying Wun Kong
Catechol-Containing Copolymers As An Active Ingredient For Denture Adhesives, Vincent Ying Wun Kong
Electronic Thesis and Dissertation Repository
Moisture inside the mouth adds challenge to making denture adhesives formulations. Some formulations have zinc to enhance adhesion on wet skin despite knowing the health hazards. Inspired by mussel foot proteins’ catechol unit’s strong underwater adhesion, nine catechol-containing copolymers (P1A-P3C) were synthesized by free radical polymerization of 3,4-dimethoxystyrene (3,4- DMS) with different styrene derivatives followed by deprotection. P1A-P3C were used to make Fn(P)-C-PBS denture adhesive formulations which had suitable shear stresses around ≥ 5 kPa satisfying ISO 10873. In-situ NMR studies of free radical polymerization of 3,4 - DMS and styrene derivatives allowed computation of their reactivity ratios showing all …
Synthesis Of Vo2/Poly(Mma-Co-Dmemuabr) Antimicrobial/Thermochromic Dual-Functional Coating And Reactivity Ratios Study, Yixian Liu
Electronic Thesis and Dissertation Repository
Antimicrobial/thermochromic dual-functional coatings were successfully synthesized via UV-curing. The quaternary ammonium compound (QAC) N,N-dimethyl-N-{2-[(2-methylprop-2-enoyl)oxy]ethyl}undecane-1-aminium bromide (dMEMUABr) was synthesized and copolymerized with methyl methacrylate (MMA) for antimicrobial properties. Vanadium oxide (VO2) nanoparticles were evenly dispersed within the coating, providing thermochromic properties. The dual-functional coating showed high luminous transmittance (Tlum(25°C) =36.1 %) and solar energy modulation ( Tsol=5.8 %). 90.3 % of bacteria reduction was observed against Escherichia coli within 24 h contact. To further understand the sequence distribution of the copolymer poly(MMA-co-dMEMUABr), the reactivity ratios of MMA and dMEMUABr monomer were studied and compared under thermal …
A Ph-Sensitive Delivery System For The Prevention Of Dental Caries Using Salivary Proteins, Yi Zhu
A Ph-Sensitive Delivery System For The Prevention Of Dental Caries Using Salivary Proteins, Yi Zhu
Electronic Thesis and Dissertation Repository
Dental caries remains one of the most common chronic diseases worldwide. Salivary proteins such as histatins have demonstrated biological functions directly related to tooth homeostasis and prevention of dental caries. However, histatins are susceptible to the high proteolytic activities in the oral environment. Therefore, pH-sensitive chitosan nanoparticles (CNs) have been proposed as potential carriers to target major oral diseases that occur under acidic conditions (e.g. dental caries and dental erosion). Four different types of chitosan polymers were investigated and the optimized CNs successfully loaded histatin 3 and released it selectively under acidic conditions. Through loading the survival time of histatin …
Synthesis, Properties, And Applications Of Carboxylic Acid Functionalized Polyisobutylene, Inderpreet Sran
Synthesis, Properties, And Applications Of Carboxylic Acid Functionalized Polyisobutylene, Inderpreet Sran
Electronic Thesis and Dissertation Repository
Polyisobutylene (PIB) and its copolymers are used in a wide range of commercial products owing to their high chemical stability, impermeability, elasticity, and biocompatibility. In this thesis, linear and arborescent PIB containing small percentages of isoprene (IP) were functionalized to provide different derivatives and their physical and biological properties were studied.
Butyl Rubber-Aliphatic Polyester Graft Copolymers For Biomedical Applications: Synthesis And Analysis Of Chemical, Physical And Biological Properties, Bethany A. Turowec
Butyl Rubber-Aliphatic Polyester Graft Copolymers For Biomedical Applications: Synthesis And Analysis Of Chemical, Physical And Biological Properties, Bethany A. Turowec
Electronic Thesis and Dissertation Repository
Biomaterials can be used in a wide variety of medical applications owing to their breadth of characteristics that can be imparted by varying their chemical structures. Butyl rubber (IIR), which is a copolymer of isobutylene (IB) and small percentages of isoprene (IP), is particularly attractive as a biomaterial because of its elastomeric mechanical properties, biocompatibility, impermeability and high damping characteristics. IIR is typically vulcanized through chemical-based crosslinking mechanisms. However, these methods are not acceptable for biological applications. This thesis focuses on the synthesis of IIR-polyester graft copolymers by grafting biodegradable and biocompatible polyesters including poly(caprolactone) (PCL) and poly(d,l-lactide) (PDLLA) to …