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Enhanced Terahertz Emission From Quantum Dot By Graphene-Coated Nanoparticle, Edin Sijercic, P. T. Leung
Enhanced Terahertz Emission From Quantum Dot By Graphene-Coated Nanoparticle, Edin Sijercic, P. T. Leung
Physics Faculty Publications and Presentations
The terahertz (THz) emission from quantum dots in close proximity to graphene-coated nanoparticles is studied via phenomenological modeling with particular interest in the possibility of enhancement for such emission via the excitation of the graphene plasmons. It is shown that depending on various factors such as the damping factor and the Fermi level of the graphene, as well as the size and core material of the coated particle, such plasmonic-enhanced THz emission is indeed possible. This thus opens up a new pathway to provide intense THz sources for future applications.
Multi-Level Surface Enhanced Raman Scattering Using AgoX Thin Film, Ming Lun Tseng, Chia Min Chang, Bo Han Cheng, Pin Chieh Wu, K. S. Chung, M. K. Hsiao, H. W. Huang, D. W. Huang, Hai-Pang Chiang, P.T. Leung, D. P. Tsai
Multi-Level Surface Enhanced Raman Scattering Using AgoX Thin Film, Ming Lun Tseng, Chia Min Chang, Bo Han Cheng, Pin Chieh Wu, K. S. Chung, M. K. Hsiao, H. W. Huang, D. W. Huang, Hai-Pang Chiang, P.T. Leung, D. P. Tsai
Physics Faculty Publications and Presentations
Ag nanostructures with surface-enhanced Raman scattering (SERS) activities have been fabricated by applying laser-direct writing (LDW) technique on silver oxide (AgOx) thin films. By controlling the laser powers, multi-level Raman imaging of organic molecules adsorbed on the nanostructures has been observed. This phenomenon is further investigated by atomic-force microscopy and electromagnetic calculation. The SERS-active nanostructure is also fabricated on transparent and flexible substrate to demonstrate our promising strategy for the development of novel and low-cost sensing chip.
Efficient Pbs/Cds Co-Sensitized Solar Cells Based On Tio2 Nanorod Arrays, Yitan Li, Lin Wei, Xiya Chen, Ruizi Zhang, Xing Sui, Yanxue Chen, Jun Jiao, Liangmo Mei
Efficient Pbs/Cds Co-Sensitized Solar Cells Based On Tio2 Nanorod Arrays, Yitan Li, Lin Wei, Xiya Chen, Ruizi Zhang, Xing Sui, Yanxue Chen, Jun Jiao, Liangmo Mei
Physics Faculty Publications and Presentations
Narrow bandgap PbS nanoparticles, which may expand the light absorption range to the near-infrared region, were deposited on TiO₂ nanorod arrays by successive ionic layer adsorption and reaction method to make a photoanode for quantum dot-sensitized solar cells (QDSCs). The thicknesses of PbS nanoparticles were optimized to enhance the photovoltaic performance of PbS QDSCs. A uniform CdS layer was directly coated on previously grown PbS-TiO₂ photoanode to protect the PbS from the chemical attack of polysulfide electrolytes. A remarkable short-circuit photocurrent density (approximately 10.4 mA/cm²) for PbS/CdS co-sensitized solar cell was recorded while the photocurrent density of only PbS-sensitized solar …
Effects Of Sn Doping On The Morphology And Properties Of Fe-Doped In2o3 Epitaxial Films, Tie Zhou, Lin Wei, Yanru Xie, Qinghao Li, Guoxiang Hu, Yanxue Chen, Shishen Yan, Guolei Liu, Liangmo Mei, Jun Jiao
Effects Of Sn Doping On The Morphology And Properties Of Fe-Doped In2o3 Epitaxial Films, Tie Zhou, Lin Wei, Yanru Xie, Qinghao Li, Guoxiang Hu, Yanxue Chen, Shishen Yan, Guolei Liu, Liangmo Mei, Jun Jiao
Physics Faculty Publications and Presentations
(Sn, Fe)-codoped In₂O₃ epitaxial films were deposited on (111)-oriented Y-stabilized ZrO₂ substrates by pulsed laser deposition with constant Fe concentration and different Sn concentrations. The influence of Sn concentration on the crystal structure and properties of Fe-doped In₂O₃ ferromagnetic semiconductor films has been investigated systematically. Experimental results indicate that Sn doping can effectively reduce the surface roughness and suppresses breakup of the films into separated islands. At the same time, the optical band gap increases and the electrical properties improve correspondingly. However, although the carrier density increases dramatically with the Sn doping, no obvious change of the ferromagnetism is observed. …
Accurate Description Of The Optical Response Of A Multilayered Spherical System In The Long Wavelength Approximation, H. Y. Chung, G. Y. Guo, Hai-Pang Chiang, D. P. Tsai, P.T. Leung
Accurate Description Of The Optical Response Of A Multilayered Spherical System In The Long Wavelength Approximation, H. Y. Chung, G. Y. Guo, Hai-Pang Chiang, D. P. Tsai, P.T. Leung
Physics Faculty Publications and Presentations
The optical response of a multilayered spherical system of unlimited number of layers (a “matryoshka”) in the long wavelength limit can be accounted for from the knowledge of the static multipole polarizability of the system to first-order accuracy. However, for systems of ultrasmall dimensions or systems with sizes not-too-small compared to the wavelength, this ordinary quasistatic long wavelength approximation (LWA) becomes inaccurate. Here we introduce two significant modifications of the LWA for such a nanomatryoshka in each of the two limits: the nonlocal optical response for ultrasmall systems (<10 >nm), and the “finite-wavelength corrections” for systems ∼100 nm. This is …
Remote Plasma Assisted Growth Of Graphene Films, Gopichand Nandamuri, Sergei Rouvimov, Raj Solanki
Remote Plasma Assisted Growth Of Graphene Films, Gopichand Nandamuri, Sergei Rouvimov, Raj Solanki
Physics Faculty Publications and Presentations
Single and multiple layers of graphene films were grown on 111 oriented single crystals of nickel and polycrystalline nickel films using remote plasma assisted chemical vapor deposition. Remote plasma was employed to eliminate the effect of the plasma electrical field on the orientation of the grown graphene films, as well as to reduce the growth temperature compared to conventional chemical vapor deposition. The electrical and optical properties, including high resolution transmission electron microscopy of these films, suggest that this approach is both versatile and scalable for potential large area optoelectronic applications.
Plasmonic Enhancement Of Forster Energy Transfer Between Two Molecules In The Vicinity Of A Metallic Nanoparticle: Nonlocal Optical Effects, P.T. Leung, H. Y. Xie, H. Y. Chung, D. P. Tsai
Plasmonic Enhancement Of Forster Energy Transfer Between Two Molecules In The Vicinity Of A Metallic Nanoparticle: Nonlocal Optical Effects, P.T. Leung, H. Y. Xie, H. Y. Chung, D. P. Tsai
Physics Faculty Publications and Presentations
The problem of Forster resonance energy transfer (FRET) between two molecules in the vicinity of a metallic nanoparticle such as a nanoshell is studied within a phenomenological model which takes into account the nonlocal optical response of the metal. This model allows for arbitrary locations and orientations of the two molecular dipoles with respect to the metal particle which can be of ultrasmall sizes (nm) and for which nonlocal effects are of high significance. In particular, for the nanoshell case, the molecules can be located both outside, both inside, or one inside and one outside the shell. Also, the case …
Nanostructured Semiconductor Heterojunctions From Quantum Dot Layers, Rolf Könenkamp, Robert Campbell Word, Athavan Nadarajah
Nanostructured Semiconductor Heterojunctions From Quantum Dot Layers, Rolf Könenkamp, Robert Campbell Word, Athavan Nadarajah
Physics Faculty Publications and Presentations
We report the deposition of conformal thin layers of 10?50 nm thickness from II-VI quantum dot suspensions on ZnO nanowire substrates. Smooth polycrystalline films of high electronic quality can be obtained from CdSe quantum dots after annealing at moderate temperatures. The electronic properties are adequate for detector and solar cell applications. The growth and annealing temperatures permit deposition on light-weight and flexible substrates. Some elemental diffusion of Se across the CdSe/ZnO interface occurs in the film formation. A comparison with CdS/ZnO junctions indicates that the low Se diffusion rates are essential for efficient charge transfer.
Structural Identification Of Cubic Iron-Oxide Nanocrystal Mixtures: X-Ray Powder Diffraction Versus Quasi-Kinematic Transmission Electron Microscopy, Peter Moeck
Physics Faculty Publications and Presentations
Two novel (and proprietary) strategies for the structural identification of a nanocrystal from either a single high-resolution (HR) transmission electron microscopy (TEM) image or a single precession electron diffraction pattern are proposed and their advantages discussed in comparison to structural fingerprinting from powder X-ray diffraction patterns. Simulations for cubic magnetite and maghemite nanocrystals are used as examples.
Transmission Electron Goniometry And Its Relation To Electron Tomography For Materials Science Apoplications, Peter Moeck, P. Fraundorf
Transmission Electron Goniometry And Its Relation To Electron Tomography For Materials Science Apoplications, Peter Moeck, P. Fraundorf
Physics Faculty Publications and Presentations
Aspects of transmission electron goniometry are discussed. Combined with high resolution phase contrast transmission electron microscopy (HRTEM) and atomic resolution scanning TEM (STEM) in the atomic number contrast (Z-STEM) or the phase contrast bright field mode, transmission electron goniometry offers the opportunity to develop dedicated methods for the crystallographic characterization of nanocrystals in three dimensions. The relationship between transmission electron goniometry and electron tomography for materials science applications is briefly discussed. Internet based java applets that facilitate the application of transmission electron goniometry for cubic crystals with calibrated tilt-rotation and double-tilt specimen holders/goniometers are mentioned. The so called cubic-minimalistic tilt …
Nonlocal Effects On Optical And Molecular Interactions With Metallic Nanoshells, P.T. Leung, Railing Chang
Nonlocal Effects On Optical And Molecular Interactions With Metallic Nanoshells, P.T. Leung, Railing Chang
Physics Faculty Publications and Presentations
Theoretical studies of the optical response of metallic nanoshells have been carried out, where quantum effects are partially accounted for through the application of a nonlocal response model for shells of mesoscopic dimensions. Both far field and near field interactions are considered, with the incident source being a plane wave and an emitting molecular dipole, respectively. It is found that these nonlocal effects can lead to significant deviations from macroscopic electrodynamic theory, for shells of ultrasmall dimensions (nm) or ultrathin thickness (~1 nm), and are particularly significant for processes involving higher multipolar responses of the nanoshells. It is further concluded …
Making Sense Of Nanocrystal Lattice Fringes, P. Fraundorf, Wentao Qin, Peter Moeck, Eric Mandell
Making Sense Of Nanocrystal Lattice Fringes, P. Fraundorf, Wentao Qin, Peter Moeck, Eric Mandell
Physics Faculty Publications and Presentations
The orientation dependence of thin-crystal lattice fringes can be gracefully quantified using fringe-visibility maps, a direct-space analog of Kikuchi maps [Nishikawa and Kikuchi, Nature (London) 121, 1019 (1928)]. As in navigation of reciprocal space with the aid of Kikuchi lines, fringe-visibility maps facilitate acquisition of crystallographic information from lattice images. In particular, these maps can help researchers to determine the three-dimensional lattice of individual nanocrystals, to 'fringe-fingerprint' collections of randomly oriented particles, and to measure local specimen thickness with only a modest tilt. Since the number of fringes in an image increases with maximum spatial-frequency squared, these strategies (with help …
Vertical Nanowire Transistors With Low Leakage Current, Jie Chen, M. C. Lux-Steiner, Rolf Kӧnenkamp, S. Klaumünzer
Vertical Nanowire Transistors With Low Leakage Current, Jie Chen, M. C. Lux-Steiner, Rolf Kӧnenkamp, S. Klaumünzer
Physics Faculty Publications and Presentations
A vertical field-effect transistor based on semiconductor nanowires is reported. The fabrication of the device uses a self-supporting flexible nanostructured polymer foil as a template and an electrochemical growth technique for the preparation of the semiconductor. The fabrication process is substantially simpler, and the mechanical robustness is strongly increased as compared to the original device. The channel region of the transistor has a diameter of ∼100 nm and a length of ∼50 nm. Operation in the hole depletion mode allows a change of the transfer conductance by ∼50% when the gate voltages is changed in the range ∓1 V. The …
High-Resolution Near-Field Raman Microscopy Of Single-Walled Carbon Nanotubes, Achim Hartschuh, X. Sunney Xie, Lukas Novotny, Erik J. Sánchez
High-Resolution Near-Field Raman Microscopy Of Single-Walled Carbon Nanotubes, Achim Hartschuh, X. Sunney Xie, Lukas Novotny, Erik J. Sánchez
Physics Faculty Publications and Presentations
We present near-field Raman spectroscopy and imaging of single isolated single-walled carbon nanotubes with a spatial resolution of approximately 25 nm. The near-field origin of the image contrast is confirmed by the measured dependence of the Raman scattering signal on tip-sample distance and the unique polarization properties. The method is used to study local variations in the Raman spectrum along a single single-walled carbon nanotube.
The Surface Plasmon Enhancement Effect On Adsorbed Molecules At Elevated Temperatures, P.T. Leung, Hai-Pang Chiang, W. S. Tse
The Surface Plasmon Enhancement Effect On Adsorbed Molecules At Elevated Temperatures, P.T. Leung, Hai-Pang Chiang, W. S. Tse
Physics Faculty Publications and Presentations
The surface plasmon enhancement effect on adsorbed molecules at elevated substrate temperatures is studied theoretically using surface enhanced Raman scattering (SERS) as an example. The surface structure is idealized to be a monodisperse spherical particle with its nonlocal dielectric response accounted for. The temperature effects are modeled using a temperature-dependent collision frequency in the Drude model. Numerical results show that only a small decrease in the SERS enhancement ratio occurs for temperatures up to the melting point of the substrate, even for scattering close to the surface plasmon resonance frequency of the metal. More definitive results are subjected to more …
Photodeflection Probing Of The Explosion Of A Liquid Film In Contact With A Solid Heated By Pulsed Excimer Laser Irradiation, P.T. Leung, Nhan Do, Leander Klees, Andrew C. Tam, Wing P. Leung
Photodeflection Probing Of The Explosion Of A Liquid Film In Contact With A Solid Heated By Pulsed Excimer Laser Irradiation, P.T. Leung, Nhan Do, Leander Klees, Andrew C. Tam, Wing P. Leung
Physics Faculty Publications and Presentations
The explosion or rapid vaporization of a liquid film on an opaque surface by a pulsed laser is studied experimentally. Using a probe-beam deflection sensing (PDS) scheme, together with a previously developed transmission monitor, the distortion of the PDS signal due to the generation of shock waves by the exploding liquid is investigated. Various liquids, including alcohols and pure water in contact with substrates such as polyimide, amorphous carbon, and silicon, are studied for a wide range of excimer laser fluences. It is concluded that the present PDS technique is highly sensitive to the explosion threshold.
Transmission Studies Of Explosive Vaporization Of A Transparent Liquid Film On An Opaque Solid Surface Induced By Excimer-Laser-Pulsed Irradiation, P.T. Leung, Nhan Do, Leander Klees, Wing P. Leung, Frank Tong
Transmission Studies Of Explosive Vaporization Of A Transparent Liquid Film On An Opaque Solid Surface Induced By Excimer-Laser-Pulsed Irradiation, P.T. Leung, Nhan Do, Leander Klees, Wing P. Leung, Frank Tong
Physics Faculty Publications and Presentations
Examines the dynamics of the explosion of a liquid film by an ultraviolet excimer pulsed laser studied experimentally on top of an amorphous silicon film deposited on fused quartz. Background on thermal physics of superheated pure or mixed liquids; Techniques for surface temperature measurement; Experimental of probe laser and pulsed excimer laser.
Energy-Transfer Theory For The Classical Decay Rates Of Molecules At Rough Metallic Surfaces, P.T. Leung, Thomas F. George
Energy-Transfer Theory For The Classical Decay Rates Of Molecules At Rough Metallic Surfaces, P.T. Leung, Thomas F. George
Physics Faculty Publications and Presentations
The problem of the decay rates for molecules at rough metallic surfaces is considered, where the classical electromagnetic energy-transfer theory of Chance, Prock, and Silbey for a flat surface is generalized to the case of a rough boundary. A dynamical theory is constructed through the combination of the Sommerfeld antenna theory and the integral equation formalism of Maxwell's equations at rough boundaries established mainly by Maradudin, Mills, and Agarwal. Perturbative solutions are obtained and numerical results are given with reference to a shallow sinusoidal grating surface. The results, when compared with those obtained previously from the application of the image …