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Fatigue Performance And Shear Demand Distributions Of Clustered Shear Connectors In Composite Bridge Girders, Brian David Hillhouse

Graduate Theses and Dissertations

The current American Association of State Highway and Transportation Officials (AASHTO) Bridge Specifications assumes uniform shear flow demands at the steel-concrete interface of composite bridge girders. As stud pitch increases to beyond 24 in or as studs become clustered to account for pre-cast concrete decks, this assumed shear demand distribution may be unrepresentative. Understanding shear transfer and resulting demands on headed studs in composite beams are important for ensuring adequate composite design. This study investigates stud demands in composite bridge girders using large-scale fatigue testing and direct pressure measurements for stud force calculations. In this study, two large-scale composite beam …

Optimizing The Plasmonic Enhancement Of Light In Metallic Nanogap Structures For Surface-Enhanced Raman Spectroscopy, Stephen Joseph Bauman

Graduate Theses and Dissertations

Technology based on the interaction between light and matter has entered something of a renaissance over the past few decades due to improved control over the creation of nanoscale patterns. Tunable nanofabrication has benefitted optical sensing, by which light is used to detect the presence or quantity of various substances. Through methods such as Raman spectroscopy, the optical spectra of solid, liquid, or gaseous samples act as fingerprints which help identify a single type of molecule amongst a background of potentially many other chemicals. This technique therefore offers great benefit to applications such as biomedical sensors, airport security, industrial waste …

Plasmonic Enhancement Of Photoluminescence And Photobrightening In Cdse Quantum Dots, David Alan French

Graduate Theses and Dissertations

Quantum dots are gaining recognition not just in the physics and chemistry community, but in the public eye as well. Quantum dot technologies are now being used in sensors, detectors, and even television displays. By exciting quantum dots with light or electricity, they can be made to emit light, and by altering the quantum dot characteristics the wavelength can be finely tuned. The light emitted can be also be made more intense by an increase in the excitation energy. The excitation light can be increased via plasmonic enhancement, leading to increased luminescence. Aside from the relatively steady-state response, quantum dots …

Exfoliation, Synthesis, And Characterization Of Nanoscale Te, Takayuki Hironaka

Graduate Theses and Dissertations

Since the experimental discovery of graphene, two dimensional materials have enjoyed more attention and emphasis in academic research than nanowires, but the latter are an important area of study for creating 1D materials, or single atom chains, the next generation materials for advancing electronic devices. Atomically thin layers can be generated from 2D materials with weak bonds in one direction, and by applying this concept to one dimensional weakly bonded materials, we hypothesize that single atom chains with atomic-scale diameters may be produced. Tellurium (Te) and selenium (Se) have lattices consisting of spiral chains oriented along the c-axis, and each …

Fabrication And Characterization Of Electrochemical Glucose Sensors, Mohammed Marie

Graduate Theses and Dissertations

Electrochemical sensors based on the nanostructure of the semiconductor materials are of tremendous interest to be utilized for glucose monitoring. The sensors, based on the nanostructure of the semiconductor materials, are the third generations of the glucose sensors that are fast, sensitive, and cost-effect for glucose monitoring.

Glucose sensors based on pure zinc oxide nanorods (NRs) grown on different substrates, such ITO, FTO, and Si/SiO2/Au, were investigated in this research. Silicon nanowire (NW)- based glucose sensors were also studied. First, an enzyme-based glucose sensor was fabricated out of glass/ITO/ZnO NRs/BSA/GOx/nafion membrane. The sensor was tested amperometrically at different glucose concentrations. …

Quasi-Particle Band Structure And Excitonic Effects In One-Dimensional Atomic Chains, Eesha Sanjay Andharia

Graduate Theses and Dissertations

The high exciton binding energy in one dimensional (1D) nano-structures makes them prominent for optoelectronic device applications, making it relevant to theoretically investigate their electronic and optical properties. Many-body effects that are not captured by the conventional density functional theory (DFT) have a huge impact in such selenium and tellurium single helical atomic chains. This work goes one step beyond DFT to include the electron self-energy effects within the GW approximation to obtain a corrected quasi-particle electronic structure. Further, the Bethe-Salpeter equation was solved to obtain the absorption spectrum and to capture excitonic effects. Results were obtained using the Hyberstein-Louie …

Scattering Of Few Photon Fields By Two Level Systems In A One Dimensional Geometry, William Konyk

Graduate Theses and Dissertations

Recent experimental progress has realized strong, efficient coupling of effective two level systems to waveguides. We study the scattering of multimode photons from such emitters coupled losslessly to the confined geometry of a one dimensional waveguide. We develop novel techniques for describing the scattered state of both single and multi-photon wavepackets and explore how such wavepackets interact with arrays of emitters coupled to a one dimensional waveguide. Finally, we apply these techniques and analyze the capability of two particular systems to act as a quantum conditional logic gate.

Combining Microdialysis And Electrophysiology In Cerebral Cortex To Delineate Functional Implications Of Acetylcholine Gradients, Tazima Nur

Graduate Theses and Dissertations

The neuronal network in cerebral cortex is a dynamic system that can undergo changes in collective neural activity as the organism changes its behavior. For example, during sleep and quiet restful awake state, many neurons tend to fire together in synchrony. In contrast, during alert awake states, firing patterns of neurons tend to be more asynchronous, firing more independently. These changes in population-level synchrony are defined as changes in cortical state. Response to sensory input is state-dependent, i.e., change in cortical state can impact the sensory information processing in cortex and introduce trial-to-trial variability in response to the same repeated …

Mesoscale Computational Studies Of Thin-Film Bijels, Joseph M. Carmack

Graduate Theses and Dissertations

Bijels are a relatively new class of soft materials that have many potential applications in the technology areas of energy, medicine, and environmental sustainability. They are formed by the arrest of binary liquid spinodal decomposition by a dispersion of solid colloidal nanoparticles. This dissertation presents an in-depth simulation study of Bijels constrained to thin-film geometries and in the presence of electric fields. We validate the computational model by comparing simulation results with previous computational modeling and experimental research. In the absence of suspended particles, we demonstrate that the model accurately captures the rich kinetics associated with diffusion-based surface-directed spinodal decomposition. …

The Incorporation Of Graphene To Lithium Cobalt Oxide As A Cathode To Improve The Performance Of Lithium Ion Batteries, Kenan Wang

Graduate Theses and Dissertations

One of the objectives of this thesis work was to investigate the cathode performance of lithium cobalt oxide (LiCoO2) incorporated with graphene powder in lithium ion batteries (LIBs). Graphene powder was incorporated into cathode materials to enhance the performance of LIBs. The other objective was to impede the construction of a solid electrolyte interphase (SEI) sheet using graphene sheet coating on its cathode.

The results of this work show that adding graphene powder improved the performance of LiCoO¬2 as a cathode material. With the incorporation of different weight percentages of graphene powder, the LiBs showed distinct changes in their charging …

Near Bandgap Two-Photon Excited Luminescence Of Inas Quantum Dots, Xian Hu

Graduate Theses and Dissertations

Semiconductor quantum dots (QDs) confine carriers in three dimensions, resulting in atomic-like energy levels as well as size-dependent electrical and optical properties. Self-assembled III-V QD is one of the most studied semiconductor QDs thanks to their well-established fabrication techniques and versatile optical properties. This dissertation presents the photoluminescence (PL) study of the InAs/GaAs QDs with both above bandgap continuous-wave excitation (one-photon excitation) and below-bandgap pulse excitation (two-photon excitation). Samples of ensemble QDs, single QD (SQD), and QDs in a micro-cavity, all grown by molecular beam epitaxy, are used in this study. Morphology of these samples was examined using atomic force …

Diffraction Of Laguerre Gaussian Vortex Beams, Anindya Ambuj

Graduate Theses and Dissertations

The natural phenomenon of waves bending around obstacles is diffraction. Spatial characteristics of the diffraction pattern depends on the incident wave field, the shape, and size of the aperture. The diffraction of a plane wave of light by a slit and a circular aperture produce the sinc-squared and the Airy intensity patterns, respectively. On the contrary, the diffraction of Laguerre-Gauss vortex (LGV) beams by simple apertures such as a slit, circular apertures, and polygons show many unexpected features.

LGV beams have ρ ` e i`φ transverse spatial dependence, where ρ is the distance from the beam axis, φ the azimuthal …

Properties Of Epitaxial Sr0.5ba0.5mno3 Films From First-Principles, Temuujin Bayaraa

Graduate Theses and Dissertations

Magnetoelectric multiferroics, that possess coupled magnetic and electric degrees of freedom, have been receiving ever renewed attention for more than 15 years since they hold promise for the design of novel devices exploiting their cross-coupling.

In this thesis, we present the results of first-principles studies on physical properties of multiferroic Sr0.5Ba0.5MnO3 films under epitaxial compressive and tensile strains, and chemical ordering. We start by reviewing multiferroic materials, a magnetoelectric coupling mechanism and then we give a brief introduction to the first-principles computational methods that are involved in this study.

Here, we report that Sr0.5Ba0.5MnO3 (SBM) films under compressive strain become …