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Nmr Characterization Of Novel Materials For Battery Electrolyte Applications, Sahana Bhattacharyya

Dissertations, Theses, and Capstone Projects

The extensive application of renewable and non-renewable energy storage devices in commercial products and services and the global warming have created significant motivations to accelerate research in battery technology. In addition, the risk factors generated by the high heat generation and flammability of the batteries are being addressed by inventing new renewable or non-renewable energy resources that do not release greenhouse gases into the atmosphere. This thesis discusses the applications of Nuclear Magnetic Resonance (NMR) Spectroscopy in characterizing and understanding novel battery materials as potential battery electrolytes. Works discussed include: the variable temperature characterization of water-based solid polymer electrolyte for …

Driven Dipolaritons In Van Der Waals Transition Metal Dichalcogenide Heterostructures: Properties And Applications, Patrick Serafin

Dissertations, Theses, and Capstone Projects

The need for advances in optical computation leads us toward the investigation of novel methods of re-routing light in optical circuits. The behavior and properties of electrically driven exciton-dipolaritons in van der Waals transition metal dichalcogenides are investigated as a platform for realizing working elements of a polaritronic transistor. In this work, we consider exciton-dipolaritons, which are three-way superposition of cavity photons, direct excitons, and indirect excitons in a bilayer semiconducting system embedded in an optical microcavity. We start by providing motivation for our study of polaritons and then survey the fundamental properties of exciton-dipolaritons. We also survey the basic …

Control Of Nonlinear Properties Of Van Der Waals Materials, Rezlind Bushati

Dissertations, Theses, and Capstone Projects

Van der Waals materials are a broad class of materials that exhibit unique optoelectronic properties. They provide a rich playground for which they can be integrated into current on-chip devices due to their nanometer-scale size, and be utilized for studying fundamental physics. Strong coupling of emitters to microcavities provides many opportunities for new exotic physics through the formation of hybrid quasi-particles exciton-polaritons. This thesis
focuses on exploring and enhancing nonlinearity of van der Waals materials through strongly coupling to microcavities. By taking advantage of the stacking order of TMDs, we show intense second-harmonic generation from bulk, centrosymmetric TMD systems. In …

Stability Of Two-Dimensional Magnetic Skyrmions, Amel Derras-Chouk

Dissertations, Theses, and Capstone Projects

Magnetic skyrmions are whirls formed by magnetic moments in a crystal. They have attracted attention largely due to their topological protection, which provides an avenue for technology like next-generation memory storage. The idea of topologically protected solutions of a quantum field theory was originally proposed by Tony Skyrme when he developed a model to explain the stability of hadrons in particle physics. His work has extended far beyond his original intent to several areas of condensed matter physics. Here we focus on skyrmions in magnetic materials.

Skyrme's original theory modeled excitations which exist in three spatial dimensions, a requirement for …

Using Protonation Microstates And Hydrogen Bond Networks To Track Proton Transfer Pathways In Complex I, Umesh Khaniya

Dissertations, Theses, and Capstone Projects

Complex I, NADH-ubiquinone oxidoreductase, is the first enzyme in the mitochondrial and bacterial aerobic respiratory chain. It pumps four protons through four transiently open pathways from the high pH, negative, N- side of the membrane to the positive, P-side driven by the exergonic transfer of electrons from NADH to a quinone. Three protons transfer through subunits descended from Mrp antiporters, while the fourth, E-channel is unique. Because of the complex possible paths thorough the many buried polar residues and lack of high-resolution crystal structure, the path for protons through the E-channel is elusive.

In this dissertation, the E-channel proton pumping …

Engineering Rare-Earth Based Color Centers In Wide Bandgap Semiconductors For Quantum And Nanoscale Applications, Gabriel I. López-Morales

Dissertations, Theses, and Capstone Projects

For many years, atomic point-defects have been readily used to tune the bulk properties of solid-state crystalline materials, for instance, through the inclusion of elemental impurities (doping) during growth, or post-processing treatments such as ion bombardment or high-energy irradiation. Such atomic point-defects introduce local ‘incompatible’ chemical interactions with the periodic atomic arrangement that makes up the crystal, resulting for example in localized electronic states due to dangling bonds or excess of electrons. When present in sufficient concentrations, the defects interact collectively to alter the overall bulk properties of the host material. In the low concentration limit, however, point-defects can serve …

Astrophysics, Cosmology And Particle Phenomenology At The Energy Frontier, Jorge Fernandez Soriano

Dissertations, Theses, and Capstone Projects

This dissertation consists of two parts, treating significantly separated fields. Each part consists on several chapters, each treating a somewhat isolated topic from the rest. In each chapter, I present some of the work developed during my passage through the graduate program, which has mostly been published elsewhere.

Part I – Cosmic Rays and Particle Physics

• Chapter 1: In this chapter we present an introduction to the topic of cosmic ray physics, with an special focus on the so-called ultra high energy cosmic rays: their potential origins, effects during their propagation between their sources and Earth, the different techniques used …

The Separation Of Charm And Bottom Decays Measured In P+Au Collisions At 200 Gev, Zhiyan Wang

Dissertations, Theses, and Capstone Projects

It has long been observed experimentally, from previous heavy-flavor electron measurements, that heavy quarks are subject to substantial modifications of their momentum spectrum. Using the PHENIX detector at the Relativistic Heavy Ion Collider (RHIC), measurements of the production of open heavy flavor hadrons with charm and bottom quarks in p+Au collisions at 200 GeV are studied and presented in this thesis. Distance of closest approach analysis of electron tracks is used to study the semileptonic decay electrons from charm and bottom hadrons. The results include invariant yield and fraction of bottom electrons. In addition to the p+p and Au+Au collisions’ …

Electron Transport In Quantum Systems With Interaction, Sara Abedi

Dissertations, Theses, and Capstone Projects

No abstract provided.

The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin

Dissertations, Theses, and Capstone Projects

An artificial urban shallow lake, Prospect Park Lake (PPL), is situated on a terminal moraine in Brooklyn New York, and supplied with municipal water treated with ortho-phosphates. The constant input of the phosphate nutrient is the primary source of eutrophication in the lake. The numerous pools along the water course houses various aquatic phototrophs, which influence the water quality and the state of the system, driving conditions into favoring the survival of their species. In the first half of the dissertation, the focus of the project is on analyzing how the different primary producers in different regions of PPL affect …

Magnetic Field Effects On The Physics Of Neutron Stars, Aric A. Hackebill

Dissertations, Theses, and Capstone Projects

In the context of neutron stars (NS), dense-magnetized quark and hadron models have been well studied under the assumption that the system's pressures are isotropic. However, the pressures determined from semi-classical statistical averaging of the energy momentum tensor in the presence of a uniform background magnetic field are anisotropic with different pressures arising along and perpendicular to the magnetic field direction. Since large magnetic fields are expected to be present in the interior of NS, it is important to understand the roll the pressure anisotropy plays. While considering the pressure anisotropy, we revisit some important calculations in NS physics.

We …

Removal Of Anisotropic Background From Neutral Pion And Tagged Direct Photon–Hadron Correlations Of Au+Au 200 Gev Collisions, Zachary Rowan

Dissertations, Theses, and Capstone Projects

A reaction plane dependent event mixing technique is developed to remove the collective background from two particle correlation measurements in heavy ion collisions. The method eliminates the need for any external flow measurements and is well suited for studying the path length dependence of particle production in quark-gluon plasma. Central to mid-central, as well as in vs out-of-plane, per neutral pion trigger integrated away-side hadron yield comparisons are made. Results suggest a significant path length dependent partonic energy loss in the medium. A tagging method is also introduced to measure the direct photon yield for various collision criteria. Direct photon …

Symmetries, Zero Modes And Light Transport In Non-Hermitian Photonics, Jose David Hernandez Rivero

Dissertations, Theses, and Capstone Projects

We approach some fundamental aspects of photonic dissipative systems treated by a non-Hermitian theory. Inspired by the possibilities provided by some major non-Hermitian symmetries, we study systematically the properties of the novel pseudochirality, pseudo-anti-Hermiticity, and supersymmetry. We analyze other aspect of photonics, the zero mode, which has a profound connection to non-Hermitian physics. We propose a scheme to realize a zero mode that exists even in the absence of symmetries. Finally, we approach light transport in non-Hermitian photonic systems, where the introduction of gain and loss can modify drastically the propagation speed of wavepackets.

Phase Transitions, Critical Phenomena, And Correlation Functions In The 2d Ising Model And Its Applications To Quantum Dynamics: A Tensor Network Approach, Sankhya Basu

Dissertations, Theses, and Capstone Projects

This thesis explores several aspects of the 2D Ising Model at both real and complex temperatures utilizing tensor network algorithms. We briefly discuss the importance of tensor networks in the context of forming efficient representations of wavefunctions and partition functions for quantum and classical many-body systems respectively, followed by a brief review of the tensor network renormalization algorithms to compute the one point and two point correlation functions. We use the Tensor Renormalization Group (TRG) to study critical phenomena and examine feasibility of accurate estimations of universal critical data for three critical points for three critical points in two dimensions …

Optical Studies Of Wide Bandgap Photonic Materials, Nikesh Maharjan

Dissertations, Theses, and Capstone Projects

In this dissertation work, optical properties of wide bandgap materials such as hexagonal Boron Nitride (h-BN) and Zinc Oxide (ZnO) have been studied. Deep UV photoluminescence spectroscopy was employed to study the optical properties of bulk h-BN and powder crystals using a laser of wavelength 200 nm, which is the fourth harmonic of Ti:Sapphire laser as excitation source. The properties and chemical compositions of annealed and unannealed bulk h-BN were investigated. The PL spectra from h-BN samples annealed at 900 ºC in ambient air, had strong phonon assisted band edge emissions along with a sharp atomic-like emission line at 4.09 …

Collective Behavior Of Dissipatively-Coupled Photonic Oscillator Networks, Jiajie Ding

Dissertations, Theses, and Capstone Projects

This thesis discusses the collective behavior of networks formed by photonic oscillators. The key motivations for doing this research are the interest in developing high power laser arrays on photonic chips and performing optical computing.

Symmetry-Inspired Analysis Of Biological Networks, Ian Leifer

Dissertations, Theses, and Capstone Projects

The description of a complex system like gene regulation of a cell or a brain of an animal in terms of the dynamics of each individual element is an insurmountable task due to the complexity of interactions and the scores of associated parameters. Recent decades brought about the description of these systems that employs network models. In such models the entire system is represented by a graph encapsulating a set of independently functioning objects and their interactions. This creates a level of abstraction that makes the analysis of such large scale system possible. Common practice is to draw conclusions about …

Charge Transport And Spin Dynamics Of Color Centers In Diamond, Damon Daw

Dissertations, Theses, and Capstone Projects

Solid state defects in diamond are promising candidates for room temperature quantum information processors (1, 3, 5). Chief among these defects is the nitrogen vacancy center (‘NV center’ or ‘NV’). The NV has long coherence times (at 300K) and its state is easily initialized, manipulated and read out (5). However, the outstanding issue of entangling NV centers in a scalable fashion, at room temperature remains a challenge. This thesis presents experimental and theoretical work aimed at achieving this goal by developing the ‘flying qubit’ framework in (1). This method for remote entanglement utilizes a charge carrier (initialized into a definite …

Connections Between Atmospheric Blocking, General Circulation, And Weather Extremes In A Hierarchy Of Models And Various Climates, Veeshan Narinesingh

Dissertations, Theses, and Capstone Projects

The field of geophysical fluid dynamics (GFD) includes the study of both the motion and thermodynamic aspects of the atmosphere. These properties are of particular importance because they directly influence both local and large-scale weather and climate and are associated with various phenomena. One phenomena that is particularly influential is atmospheric blocking. Atmospheric blocks are persistent, quasi-stationary anticyclones (a.k.a. high-pressure systems) that occur in the atmosphere and disrupt the flow. Blocks are known to induce heat extremes and cold spells, as well as steer storms and cause numerous types of hazards. Yet despite the hazards associated with blocks, our current …