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Deuterium Mas Nmr Studies Of Mg-Ti Deuteride Formed During High Pressure Ball Milling, Samuel Emery

Arts & Sciences Electronic Theses and Dissertations

Magnesium hydride has long been considered a candidate onboard hydrogen storage material for hydrogen fuel cell powered vehicles due to its low cost, abundance (of magnesium metal), and high hydrogen content (7.6 wt%). However, its use has been limited by the poor kinetics and thermodynamics of the reversible hydriding/dehydriding reaction. Improvements to hydrogen uptake and release have been previously demonstrated when Mg is alloyed with Sc. The resulting MgSc-hydride adopts a cubic, fluorite crystal structure (as opposed to the rutile, tetragonal structure for bulk MgH2) that exhibits a significantly lower activation energy for thermally driven hydrogen motion. However, Sc is …