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Theses/Dissertations

Collision broadening

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Collision Broadening Using Alkali-Filled, Hollow Core Fibers, Luke P. Rodgers Oct 2007

Collision Broadening Using Alkali-Filled, Hollow Core Fibers, Luke P. Rodgers

Theses and Dissertations

The goal of this research was to demonstrate the possibility of collision broadening in a cesium-filled, hollow-core fiber as an alternative to the proven technique of pressure broadening. Theoretically, alkali electrons should relax from the 2P3/2 to the 2P1/2 level and the absorption spectrum should collisionally broaden due to the presence of fiber walls, as opposed to the more common pressure broadening method. An absorption dip located at 852.34nm was recorded in a pressure broadened comparison leg. This data was used as a baseline during analysis of the fiber leg's data. While the fiber was successfully …


Broadening And Shifting Of Atomic Strontium And Diatomic Bismuth Spectral Lines, Jeremy C. Holtgrave May 2003

Broadening And Shifting Of Atomic Strontium And Diatomic Bismuth Spectral Lines, Jeremy C. Holtgrave

Theses and Dissertations

The objective of this research is to study the effects of noble gases on atomic strontium and diatomic bismuth visible transitions, Specifically, this research seeks to determine if the line broadening and, in the case of atomic strontium, line shifting rates of these transitions in the presence of noble gases depend on the total angular momenta of the energy states involved. It has been known for more than a century that atomic and molecular spectral lines are broadened and shifted by perturbing species. While a considerable body of theoretical work has been accomplished on this topic over the years, only …