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Speciation And Spectroscopy Of The Uranyl And Tetravalent Plutonium Nitrate Systems: Fundamental Studies And Applications To Used Fuel Reprocessing, Nicholas A. Smith
Speciation And Spectroscopy Of The Uranyl And Tetravalent Plutonium Nitrate Systems: Fundamental Studies And Applications To Used Fuel Reprocessing, Nicholas A. Smith
UNLV Theses, Dissertations, Professional Papers, and Capstones
This dissertation explores the use of UV-Visible spectroscopy and Time Resolved Laser Induced Fluorescence spectroscopy as near real time process monitors of uranium and plutonium concentrations in aqueous reprocessing trains. The molar absorptivities and linear ranges of these metals were investigated under total nitrate and acid concentrations similar to those found in current reprocessing systems. Concurrent to this, a new multiple wavelength monitor was derived that is capable of determining the total nitrate concentration spectroscopically. This method uses the uranium absorbance spectrum to calculate the nitrate concentration in solution. When used as part of an Advanced Safeguard suite, this technique …
Positron Annihilation Ratio Spectroscopy (Psars) Applied To Positronium Formation Studies, Robert C. Slaughter
Positron Annihilation Ratio Spectroscopy (Psars) Applied To Positronium Formation Studies, Robert C. Slaughter
Theses and Dissertations
A Positron Annihilation of Radiation Spectrometer (PsARS) was developed and characterized. PsARS spectroscopy as well as digital Positron Annihilation Lifetime Spectroscopy (PALS) was applied to measure positronium formation on gold nanoparticles deposited through an evaporative method onto a thin capillary tube. This gold coated capillary tube was designed to be used for positronium lifetime studies in local electric field experiments. High local electric fields can polarize a positron-electron pair, which may result in an extended lifetime of the positron. These fields may be created through the interaction of an external electric field with silver nanoparticles deposited onto the surface of …
Hard Collisions In Rubidium Using Sub-Doppler Spectroscopy, Douglas E. Thornton
Hard Collisions In Rubidium Using Sub-Doppler Spectroscopy, Douglas E. Thornton
Theses and Dissertations
To better understand the laser kinetics of an alkali gain medium, hard collisions, or velocity-changing collisions, has been studied and a velocity-changing collisional rate has been calculated. Previous works have studied these collisions, but no rate has been calculated. Using the precise tool of sub-Doppler spectroscopy, atomic hard collisions can be observed. The collected spectra are fitted with two different line shapes to demonstrate the accuracy of this method. From the fits, the number of hard collisions can be extracted. The time scale of the hard collisions in rubidium is interpolated by varying the chopping frequency of the pump beam, …