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Modeling The Behavior Of The Graphene To Liquid Interfaces In An Electrolytic Liquid, Caitlin Duffner
Modeling The Behavior Of The Graphene To Liquid Interfaces In An Electrolytic Liquid, Caitlin Duffner
Senior Theses
Understanding the mechanism for charge transfer between a graphene biosensor and its electrodes within an electrolyte solution is vital to better understand the sources of electrical noise in the system. By measuring the effective resistance and capacitance of the system at different frequencies, it is possible to develop a circuit model of the system's electrical behavior. This model provides a deeper understanding of the fundamental interactions that occur in a top-gated graphene device and provides opportunities to improve a signal. To reduce noise created at the liquid to graphene interface, a buffer layer of Yttrium Oxide was applied. While the …
Effect Of Electrolyte Concentration On The Capacitance And Mobility Of Graphene, Flint A. Martino
Effect Of Electrolyte Concentration On The Capacitance And Mobility Of Graphene, Flint A. Martino
Senior Theses
The use of graphene field-effect transistors as a biosensor is increasingly being used to study biological phenomena, due to the sensitivity and low reactivity of graphene. To further improve sensitivity in biological environments, we examined how different salt concentrations affect the mobility of capacitance of the graphene. Samples were also measured after an annealing process. We report on the positive correlation between sensitivity and electrolyte concentration and speculate on methods to improve future detectors. Mobility of the device was found to change from 1.07*103cm2/ (V*s) in de-ionized water to 2.78*103cm2/ (V*s) in …
Measuring Charge Carrier Mobility In Graphene, Christina A. Harmon
Measuring Charge Carrier Mobility In Graphene, Christina A. Harmon
Senior Theses
This research reports measurements of electron mobility in Graphene Field Effect Transistors (GFET), gated with liquid. Mobility is a quantity describing how easily charge carriers move through a material. GFET biosensors have the greatest sensitivity when the mobility is high; therefore, increasing mobility should improve sensitivity of these and similar devices. An optimal method was established for preparing samples and taking measurements of a liquid-gate device. Sheet conductivity was measured using van der Pauw geometry and carrier density was determined from measurements of the liquid-gate capacitance. It is shown that mobility improves after the graphene surface is cleaned by an …