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Local Structure And Dynamic Studies Of Mixed Ch4-Co2 Gas Hydrates Via Computational Simulation And Neutron Scattering, Bernadette Rita Cladek

Doctoral Dissertations

Permeated throughout the ocean floor and arctic permafrost, natural gas hydrates contain an estimated 3000 trillion cubic meters, over three times that of traditional shale deposits, of CH₄ that is accessible for extraction. Gas hydrates are a crystal structure in which water molecules form a cage network, the host, through hydrogen bonds while trapping a guest molecule such as CH₄ in the cavities. These compounds form naturally where the appropriate low temperature and high pressure conditions occur. A promising and tested method of methane recovery is through exchange with CO₂, which energetically takes place of the …

Acoustic Confinement And Characterization Of A Microwave Plasma, Seth Lee Pree '09

Doctoral Dissertations

High amplitude acoustic fields are used to confine, characterize, and manipulate collisional plasmas with temperatures of a few thousand Kelvin. This dissertation describes the theory, experimental techniques, and apparatus necessary both to generate high amplitude sound in a few thousand Kelvin plasma and to use that sound field to manipulate the plasma within a resonant acoustic cavity. The acoustic field in a spherically symmetric oscillating plasma has been measured to have a Mach number of .03, which is sufficient to cause acoustic radiation pressure effects to confine the plasma to the center of its container. This field also generates convection …

Characterization Of Neutron Irradiated Accident Tolerant Nuclear Fuel Cladding Silicon Carbide & Radiation Detector Deadtime, Bader Almutairi

Doctoral Dissertations

“In part I, the pulse shape characteristics generated by a Geiger Muller (GM) detector and recorded by an oscilloscope manually, were investigated. The objective of part I was (1) to find a correlation between pulse shape and the operating voltage; and (2) to assess if pulse shape properties followed distinct patterns comparable to detector deadtime findings reported by a previous study. It was observed that (1) there is a strong correlation between pulse shape and operating voltage, and (2) pulse shape falls in three distinct regions similar to detector deadtime. Furthermore, parts II and III are companions and share the …

Magnetic Control Of Transport Of Particles And Droplets In Low Reynolds Number Shear Flows, Jie Zhang

Doctoral Dissertations

“Magnetic particles and droplets have been used in a wide range applications including biomedicine, biological analysis and chemical reaction. The manipulation of magnetic microparticles or microdroplets in microscale fluid environments is one of the most critical processes in the systems and platforms based on microfluidic technology. The conventional methods are based on magnetic forces to manipulate magnetic particles or droplets in a viscous fluid.

In contrast to conventional magnetic separation method, several recent experimental and theoretical studies have demonstrated a different way to manipulate magnetic non-spherical particles by using a uniform magnetic field in the microchannel. However, the fundamental mechanism …

A Molecular Dynamics Study Of Temperature Dependent Wetting In Alkane-Water Systems, Pauf Neupane

Doctoral Dissertations

“The wetting behavior of aqueous organic systems is of great importance in several environmental and industrial processes such as the formation and growth of atmospheric aerosols, crude oil recovery from an oil field, onsite cleaning of natural gas, and clean-up of oil spills. In this work, we employed molecular dynamics (MD) simulations to explore the temperature dependent wetting behavior of octane and nonane on water in planar interfaces as well as in nanodroplets using PYS alkane and SPC/E and TIP4P/2005 water models.

For planar interfaces, we found unusual wetting behavior of octane and nonane on SPC/E water, but generally not …

Modification Of The Optical Response Of Alpha Quartz Via The Deposition Of Gold Nanoparticles In Etched Ion Tracks, Maria C. Garcia Toro

Doctoral Dissertations

”This study addresses the experimental methods used to develop and characterize plasmonic devices capable of modifying the optical response of alpha quartz via the deposition of gold nanoparticles in etched ion tracks. In the first part of the research, the microstructural characterization of latent and etched ion tracks produced in alpha quartz (α-SiO₂) is presented. Single crystals of α-SiO₂ were irradiated with two highly energetic ions to different nominal fluences. As expected, the morphology of the resulting ion tracks depends on the energy of the incident ion and their stopping powers within the target material. Subsequent chemical …