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Biaxial Nematic Phase In Bent-Core Thermotropic Mesogens, Bharat R. Acharya, Andrew Primak, Satyendra Kumar
Biaxial Nematic Phase In Bent-Core Thermotropic Mesogens, Bharat R. Acharya, Andrew Primak, Satyendra Kumar
Satyendra Kumar
A biaxial nematic phase had been predicted with D2h symmetry, wherein the mesogen’s long and short transverse axes are simultaneously aligned along the two orthogonal, primary and secondary directors, n and m, respectively. The unique low-angle x-ray diffraction patterns in the nematic phases exhibited by three rigid bent-core mesogens clearly reveal their biaxiality. The results of x-ray diffraction can be readily reproduced by ab initio calculations that explicitly include the bent-core shape in the form factor and assume short-range positional correlations.
Novel Examples Of Achiral Bent-Core Azo Compounds Exhibiting B1 And Anticlinic-Antiferroelectric B2 Mesophases, Veena Prasad, Shin-Woong Kang, Satyendra Kumar
Novel Examples Of Achiral Bent-Core Azo Compounds Exhibiting B1 And Anticlinic-Antiferroelectric B2 Mesophases, Veena Prasad, Shin-Woong Kang, Satyendra Kumar
Satyendra Kumar
The first examples of achiral bent-core molecules consisting of an azo linkage and five aromatic rings exhibiting bent-core mesophases are reported. They exhibit B1 and B2 phases as identified by optical microscopy, differential scanning calorimetry, X-ray diffraction, and electro-optical techniques. The B2 phase of these materials is identified to be the anticlinic–antiferroelectric, SmCAPA phase. The mesophases of these compounds have relatively low transition temperatures and wide temperature ranges. The observation of bent-core phases in azo compounds assumes significance from the fact that the introduction of the –NN– linkage adds a new dimension, namely photochromism, to this field.