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Application Of The Weiss Molecular Field Theory To The Lattice Of The B-Site Spinel, Wayne Edmund Holland

Masters Theses

"The Weiss molecular field theory has been applied to the lattice of the B-site spinel. The forms of the ordering temperatures and the asymptotic Curie temperature have been determined for a sixteen-sublattice model with collinear spins. The theory has been applied to the problem of determining the exchange integrals for systems of the form Aa₁₋ₓAbₓCr₂X₄ and ACr₂Xa_4(1-y)Xb_4y. The theoretical results have been compared to the experimental data for the systems Hg₁₋ₓCdₓCr₂S₄, Zn₁₋ₓCdₓCr₂Se₄, and CdCr₂S_4(1-y)Se_4y in an attempt to determine the exchange integrals"--Abstract, page ii.