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Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik

Theses and Dissertations

Advanced oxidation of organic pollutants with TiO2 photocatalysts is limited due to the wide bandgap of TiO2, 3.2 eV, which requires ultraviolet (UV) radiation. When nanosized TiO2 is modified by carbon doping, charge recombination is inhibited and the bandgap is narrowed, allowing for efficient photodegradation under visible light. Here, we propose a flame spray pyrolysis (FSP) technique to create TiO2. The facile process of FSP has been successful in preparing highly crystalline TiO2 nanoparticles. Using the same procedure to deposit TiO2 onto biochar, the photocatalyst was doped by the carbonaceous material. The morphology, crystalline and electronic structure of the FSP …

Remediation Strategies To Reduce Heavy Metal Uptake In Lettuce Grown In Contaminated Urban Soil, Ryley Thomas

UCARE Research Products

Urban soils are increasingly used to produce food for local consumption, which requires at the same time management strategies that prevent the plant uptake of potentially present contaminants. This study was conducted to test different soil amendments for their ability to retain lead (Pb) and arsenic (As) within the soil matrix. The analyzed soil was taken from a potential community garden lot near a railroad in Lincoln, NE where elevated concentrations in Pb and As had been detected. Ponderosa pine biochar and spent coffee grounds were used as soil additives because of their documented chemical reactivity towards soil cations or …

Synthesis Of Nanotemplated, Glucose-Derived Adsorbents For The Removal Of Organic And Inorganic Pollutants From Water, Luis Alfonso Barrera

Open Access Theses & Dissertations

With an ever-present rise in population, along with an increase in industrial and manufacturing plants, contamination of potable water has become a global concern. While water treatment facilities exist which can help with the purification of water from bacterial and organic contaminants, these facilities are expensive to set in place and maintain. Therefore, in impoverished areas, point of use (POU) purification systems are often preferred, such as filters made from activated carbon. These filters are inexpensive and relatively easy to install and use. However, while activated carbons generally display excellent adsorption capabilities towards organic contaminants, their adsorption towards inorganic pollutants …

Remediation Strategies To Reduce Heavy Metal Uptake In Lettuce Grown In Contaminated Urban Soil, Ryley Thomas

Department of Environmental Studies: Undergraduate Student Theses

Urban soils are increasingly used to produce food for local consumption, which requires at the same time management strategies that prevent the plant uptake of potentially present contaminants. This study was conducted to test different soil amendments for their ability to retain lead (Pb) and arsenic (As) within the soil matrix. The analyzed soil was taken from a potential community garden lot near a railroad in Lincoln, NE where elevated concentrations in Pb and As had been detected. Ponderosa pine biochar and spent coffee grounds were used as soil additives because of their documented chemical reactivity towards soil cations or …

Design Improvements To Sulfate-Reducing Bioreactors For Mine-Influenced Stream Remediation In Cold Climates, Katrina Moreira

Graduate Theses & Non-Theses

Mine-influenced water (MIW), a waste water product containing heavy metals and sulfates, is a significant pollution source to waters in Montana. Implementing a low cost, passive treatment system, such as a sulfate-reducing bioreactor (SRBR), is desired for remediation of streams influenced by heavy metals in remote locations. SRBR systems operate by using organic matter and sulfate-rich water to precipitate and immobilize dissolved heavy metals. Sulfate-reducing bacteria utilize the organic matter as an electron donor to convert sulfate to sulfide, and then sulfide in the bioreactor is utilized to precipitate heavy metals. Under ideal operating conditions, SRBR systems can remove >98% …

The Biogeochemistry Of Elemental Sulfur Contaminated Soils: Insights Into Effective Remediation, Michael Ryan Mctee

Graduate Student Theses, Dissertations, & Professional Papers

Soil contamination that results from elemental sulfur (S⁰) deposition is a new occurrence. Elemental sulfur is stockpiled as a byproduct from the oil and gas industry and is deposited by biodegradable trap and skeet targets at shooting ranges. Chemolithotrophs and mixotrophs can oxidize S⁰ to H₂SO₄. Consequently, in areas where excess S⁰ is deposited or stockpiled, soils can acidify to pH values observed with acid mine drainage.

I studied S⁰ contamination at a former sporting clay range. For seven years, the range used biodegradable trap and skeet targets that contained S …