Digital Commons Network^™

Orthotrichum Lyellii As An Active Moss Biomonitor: Examining The Interplay Between Ambient Pm10, Bulk Deposition And Heavy Metals In An Urban Environment, Scott Bradley Kiel

Dissertations and Theses

The importance of monitoring and preventing pollution in the environment is a globally recognized issue. Of the criteria pollutants outlined by the United States Environmental Protection Agency, particulate matter is among these least understood in relation to toxicity and most wide-spread. Many governments have employed continuous air quality monitoring networks to track ambient levels of particulate matter, but are often too widespread to capture the heterogeneity of the urban environment, especially for heavy metal deposition. In Portland, OR, the epiphytic moss Orthotrichum lyellii was successfully used as a low-cost passive biomonitor to increase the spatial resolution of pollution around the …

Exploring Linkages Between Landscape Patterns And Freshwater And Estuarine Bivalves In The Coast Range Of Oregon, Kaegan Michael Scully-Engelmeyer

Dissertations and Theses

Spatial configurations of landscape variables (biotic, abiotic, and socio-ecological) affect and are affected by ecological processes and species in watersheds. This dissertation explores relationships among landscape patterns, ecosystem processes and bivalve species dynamics in coastal watersheds in Oregon, USA. I approached this broad topic through two primary avenues of research: investigating cross-ecosystem threats from pesticide use in forestland management to downstream aquatic environments, and the landscape ecology of an at-risk freshwater mussel species.

Terrestrial land use activities present cross-ecosystem threats to riverine and marine species and processes. Specifically, pesticide runoff can disrupt hormonal, reproductive, and developmental processes in aquatic organisms, …

Modeling Biliary Polycyclic Aromatic Hydrocarbon Metabolites In Fish Using High Performance Liquid Chromatography With Fluorescence Detection, Principal Component Analysis, And Partial Least-Squares Analysis, Joshua C. Padilla

Honors Projects

Polycyclic aromatic hydrocarbons (PAHs) constitute a diverse class of highly toxic, ubiquitous environmental pollutants, and are thus of high interest in environmental monitoring and regulation. In this study, biliary samples of English soles Parophrys vetulus and smallmouth bass Micropterus dolomieu from Seattle waterways, and chum salmon Onchorynchus keta from the north Pacific Ocean were analyzed by high performance liquid chromatography with fluorescence detection (HPLC-FLD) to gauge PAH exposure. Samples were profiled in three broad molecular weight categories, to capture naphthalene-like (NAPH), phenanthrene-like (PHEN), and benzo[a]pyrene-like (BAP) metabolites. While quantification was not achieved for the chum salmon, the semi-quantitative measurements of …

Novel Sensing Concept For Organophosphate Monitoring, Cheyenne Bowman

Legacy Theses & Dissertations (2009 - 2024)

Organophosphates are a group of insecticides that are commonly used as chemical warfare agents (CWAs), since they can act as nerve agents by inhibiting acetylcholinesterase. Acetylcholinesterase is a vital enzyme of the central nervous system (CNS). This enzyme facilitates the breakdown of acetylthiocholine into thiocholine and acetate. The major goal of the research will be to provide a preliminary rapid, sensitive, and reliable method for sensing organophosphates. Current methods are enzyme inhibition-based – that is, a decrease in absorbance or signal yields a positive indicator for the presence of analyte. Herein, two different novel approaches to organophosphate sensing are described.The …

Legacy And Emerging Per- And Polyfluoroalkyl Substances : Analysis, Environmental Distribution, And Bioconcentration, Richard Anthony Brase

Legacy Theses & Dissertations (2009 - 2024)

Per- and polyfluoroalkyl substances (PFAS) constitute a broad class of anthropogenic chemicals that have been used in numerous industrial and consumer-product applications since the late 1940s. The environmental persistence of these compounds in combination with their widespread commercial use have led PFAS to be recognized as contaminants of concern on the global scale. Despite regulatory efforts calling for the decreased use of certain perfluorocarboxylic and -sulfonic acids referred to as “legacy” PFAS, these compounds continue to be detected in both environmental and biological matrices. Moreover, manufacturers have begun to replace the legacy PFAS with emerging alternatives for which the regulations …

Physical Characteristics And Microphysical Processing Of Atmospheric Aerosol In Rural And Urban New York State, Joseph Marto

Legacy Theses & Dissertations (2009 - 2024)

Atmospheric aerosol has profound impacts on air quality, though particles of differing sizes can have profoundly different characteristics which are understated when measurements are reported as a single parameter (typically number concentration or total mass). To address some of these concerns and to better understand the nature of atmospheric aerosol, continuous particle size distributions have been measured at two sites in New York State. Measurement was performed for particle diameters between 7.6nm - 20µm at Pinnacle State Park (Addison, New York; March 2017-April 2018) and Queens College (May 2018-September 2019) at a 5-minute time resolution. At Pinnacle State Park, aerosol …

Fabrication, Characterization And Environmental Monitoring Of Polymer-Based Materials For Biomedical And Structural Applications, Mousumi Bose

Doctoral Dissertations

"Polymers are versatile materials utilized for variety of applications. In biomedical field, luminescence quenching based optical oxygen sensors encapsulated in polymeric substances are gaining attention for early detection of surface wounds associated with tissue oxygen. A simple and low-cost fabrication technique was developed to produce sensor arrays for continuous two-dimensional oxygen tension measurement. Sensor patch along with smart phone-based readout technique is being evaluated as a smart bandage.

The environmental concerns and limited petroleum supply demand for replacing petroleum-based polymers with renewable bio-based sources while maintaining comparable properties. A sustainable and green approach was adopted to synthesize soy polyol-derived rigid …

Field Evaluation Of Portable Air Quality Monitors And Evaluation Of Short-Lived Plume Events Of Atmospheric Pollutants, Joseph Peter Marto

Legacy Theses & Dissertations (2009 - 2024)

Availability of low cost optical sensors has allowed for the supplementation of existing air quality infrastructure with portable, adaptive monitors. While these sensors generally cannot offer the same accuracy and precision as established analysis methods, they can still reliably detect changes in pollutant concentration. This study evaluates the performance of two portable air quality enclosures deployed at collocated research sites to determine their accuracy and usefulness in field deployments. One system deployed collocated sensors for measurement of particulate matter mass concentration (Thermo pDR 1500 and TSI DustTrak DRX for PM2.5) and the second system deployed sensors for measurement of black …

A Study On The Current State Of Contaminants Of Concern Research, With A Focus On Biosolids And Regulations, Maren Mariah Fulton

Civil and Environmental Engineering Master's Project Reports

Wastewater treatment plants are a major source of contaminants of emerging concern, as these facilities are the main receptors of these products via household, commercial, and industrial drains, and transport via stormwater runoff. Biosolids are composed of numerous constituents, with a number of environmentally persistent and potentially toxic contaminants of emerging concern identified as present in large concentrations. Research is needed to understand the transport and fate mechanisms of these compounds in biosolids. Additionally, this research is needed to determine a new priority framework to regulate CECs, both on the national level and regional levels. Wastewater treatment plant influent and …

Analysis Of Landsat Satellite Data To Monitor Water Quality Parameters In Tenmile Lake, Oregon, Michael T. Waxter

Civil and Environmental Engineering Master's Project Reports

The health of North and South Tenmile Lakes in coastal Oregon has declined since the introduction of invasive species of fish and plant life in the 1920s. The lakes are now on the Federal Clean Water Act list of impaired water bodies due, in part, to a lack of dissolved oxygen and Hazardous Algae Blooms (HAB) blooms that occur during June through September. In this report we discuss the possibility of detecting and monitoring these blooms using satellite measurements of water surface color. In-situ measurements obtained from the Tenmile Lakes Basin Partnership were used to calibrate reflectance from the Thematic …

Methods For The Characterization Of Deep-Sea Benthic Megafauna In The Vicinity Of The Deepwater Horizon Macondo Well, Stephanie Marie Sharuga

LSU Doctoral Dissertations

Soft-sediment benthic environments are amongst the largest marine ecosystems in the world and play important roles in many ecosystem functions. In recent years, exploitation of resources and unintentional impacts on deep-sea benthic environments has increased. The Deepwater Horizon oil spill of 2010 in the northern Gulf of Mexico (GoM) represented a prime example of this. The oil spill not only highlighted deficiencies of data and information on baseline conditions, but also represented an opportunity to learn more and develop better methods for the future. Deep-sea imaging platforms such as autonomous underwater vehicles (AUVs) and remotely operated vehicles (ROVs) have been …

Analysis Of Ecological Change In Marine Ecosystems Via Novel Imaging And Spectroscopic Techniques On Microalgae Cells, Morgan Breonne Mcconico-Lewis

Doctoral Dissertations

With the increase in anthropogenic pollutants such as: atmospheric CO₂ [carbon dioxide], fossil fuel combustion and fertilizer run off, the fate of the environment is of great importance. Through industrialization, the greenhouse gas, CO₂, is a major contributor to global warming; while nitrogen based fertilizer, causes the production of toxins due to harmful algal blooms. Both chemical impacts dissolve into marine ecosystems effecting the chemical composition of organisms such as microalgae. Microalgae remediate these changes by sequestering carbon and nitrogen; thus there is a need to understand how these impacts affect the ecosystem by detecting the change …

Assessment Of Human Exposure To Perchlorate And Perfluoroalkyl Substances In The United States : Biomonitoring And Environmental Monitoring Approaches, Qian Wu

Legacy Theses & Dissertations (2009 - 2024)

Perchlorate is an oxidant in solid fuels and explosives and is produced in large quantities worldwide. Perchlorate is a ubiquitous environmental contaminant and is present in water, food, indoor environment and humans. Human exposure to perchlorate is a concern due to its ability to disrupt the thyroid gland functions.

Documenting The Anthropogenic Impact On Ballston Lake New York From A Short Core Using Stable Isotopes Of Carbon And Nitrogen And Trace Metals, Taylor S. Labrecque

Honors Theses

Ballston Lake occupies a portion of an avulsed channel of the Mohawk River between Schenectady and Saratoga Springs, New York. The lake is about 5 km long, generally less than 200m wide, ~8-15m deep, dimictic, with a catchment basin area of ~22km2. Long cores (>8 m) indicate that the lake formed ~13,000 cal yr BP. This study was undertaken to document recent environmental change recorded in the upper portion of sediment in Ballston Lake. Three sediment cores ~40 cm long were acquired from ~8 m water depth at the north end of Ballston Lake (42°57.101’N, 73°51.066’W), and were analyzed …

A Novel Approach To Assess Environmental Changes In Marine Ecosystems Via Spectroscopic Analyses Of Microalgae, Rebecca Burke Horton

Doctoral Dissertations

Chemical analyses for environmental monitoring encounter many challenges which are imposed by a multitude of chemically complex and interrelated processes. For such investigations, innovative analytical methodologies must be developed which characterize chemical shifts of key environmental parameters in order to deduce insights into their ecological relevance. This dissertation is driven by an analytical chemistry perspective to develop chemical sensing techniques with the ultimate goal of gaining a deeper understanding of environmental changes and their chemical origins.

In order to overcome limitations inherent to any chemical sensor designed for a specific task, new paths are pursued which are based on the …

Integrating Human Variables In Cross-Boundary Monitoring Of Aberdare Preserves In Kenya, Peter K. Njuguna

Graduate Theses and Dissertations

This research critically examines extant data systems and their linkage of scientific research to policy and public education in east African highland forest conservation preserves. The research indicates that the current state of data and monitoring systems in the region imposes substantial limitations on the ability to manage these preserves. Major outcomes of those constraints manifest in unprecedented cross-boundary pressure such as encroachment and conversion of forest to agriculture, increased human-wildlife conflicts, and constrained relations among primary stakeholders. Current monitoring is biodiversity focused within preserves and fails to capture human dimensions in adjoining areas across preserve boundaries. This study proposes …

Old Father Hudson: The Three Stages Of Environmental Activism In The Hudson River Valley, Gregory P. Cannillo

Honors Theses

Consequences of development have threatened the health of the Hudson River for decades. These have included the prospect of destroying scenic value of the Hudson River Valley with the a hydroelectric power plant on Storm King Mountain, as well as the pollution of the river itself by a variety of industrial sources. Since the 1960s, a long lineage of environmental activism in the Hudson River Valley has emerged to address those issues. The example of the Hudson River supplies an excellent case study of how environmental issues began to be addressed in the later half of the 20th century. I …

Development Of A Long Range Wireless Sensor Platform, Daryoush Bayat

Theses: Doctorates and Masters

Wireless Sensor Networks have emerged as an exciting field in recent years. There have been numerous studies on how to improve and standardise different aspects of wireless sensor networks. This paper aims to develop a wireless sensor network suitable for environmental monitoring applications. More specifically this paper aims to address the limited communication range of the existing wireless sensor technology. In order to achieve the desired objectives, we have initially developed a hardware platform and then integrated the hardware with a long range RF radio module to achieve the goals. The system is further enhanced with mesh networking capabilities to …

Retrieval Of Atmospheric Elemental Carbon Records Using Lake Sediments : Implications In Radiative Forcing, Tanveer Ahmed

Legacy Theses & Dissertations (2009 - 2024)

Elemental or black carbon (EC or BC) aerosols produced during incomplete combustion strongly absorb solar radiation and contribute to global warming, and cause cardiopulmonary disease. Long-term atmospheric EC measurements, [EC]_atm, are needed to validate global climate models to estimate the impact of EC on earth's temperature. Such data is sparse.

Biomonitoring For Exposure To Trace Elements In Utero : Analysis Of The Human Placenta, Pamela Catherine Kruger

Legacy Theses & Dissertations (2009 - 2024)

The placenta forms in eutherian mammals, and is responsible for the nutrition of the developing fetus. However, maternal exposure to environmental pollutants both before and during pregnancy may result in the passage of toxins through the placental barrier and into fetal tissues. The placenta is the only organ derived from both maternal and fetal tissues, and establishes a link between the fetus and the environmental exposures of the mother. The analysis of placentae for the presence of environmental pollutants offers the possibility of exposure measurements in both the mother and the developing fetus. Specifically, trace element determination in human placentae …

Remote Sensing Systems Optimization For Geobase Enhancement, Steve J. Paylor

Theses and Dissertations

The U.S. Air Force is in the process of implementing GeoBase, a geographic information system (GIS), throughout its worldwide installations, Air Force GIS needs can be augmented by imagery from aerial and satellite platforms. Imagery has greatly improved over the past several years and provides high resolution coverage of features on earth. Various imagery types will significantly increase GeoBase usefulness in a range of mission requirements, Potential Air Force uses of imagery include identifying heat loss, environmental monitoring, command decision-making, and emergency response, The research develops a decision tool to determine the appropriate imagery for a given Air Force Application, …

Survey Of Military Applications For Fourier Transform Infrared (Ftir) Spectroscopy, Robert G. Hauser

Theses and Dissertations

This paper surveyed four potential military uses for a Fourier Transform Infrared (FTIR) Spectrometer. A physical method to retrieve vertical atmospheric temperature profiles using a least-squares solution on atmospheric radiance observed at the surface in the 4.3-micrometer carbon dioxide absorption band was analyzed. The method was not successful. Weighting functions, calculated from the surface looking up, were a maximum at the surface, so no unique solution for temperature retrieval by height was determined. Observed atmospheric radiance measurements were compared with radiance calculated using the Moderate Resolution Transmittance Code (MODTRAN). Qualitative comparison showed spectral features of observed and calculated radiance plots …

Neural Network Classification Of Environmental Samples, Jeffrey L. Blackmon

Theses and Dissertations

This research develops a general methodology for designing neural network classifiers for real-world environmental problems. This methodology is demonstrated through the design of a multi-layer perceptron to classify stainless steel and actinide samples. Neural networks, sometimes called artificial neural networks, have been shown capable of classifying complex patterns. Artificial neural networks are physiologically motivated computer algorithms which attempt to mimic the function of the large interconnected network of neurons in the human brain, which has extraordinary pattern recognition capabilities. These artificial neural networks learn to map a set of input features, elemental composition, onto a set of outputs such as …

Hydrogeology And Water Budget Analysis Of Two Interdunal Ponds Nags Head Woods Ecological Preserve, Dare County, North Carolina, Richard A. Hisert

OES Theses and Dissertations

Ground-water-fed interdunal ponds in Nags Head Woods Ecological Preserve lose as much as 7600 m³ yr^-1 of water through evaporation. This withdrawal of groundwater is sufficient to significantly alter flow patterns through the surficial aquifer on Bodie Island, N.C. Statistical analyses of evaporation estimates derived by various methods indicate a weak correlation, (r²=0.4-0.5) between pan evaporation data from Aurora, N.C. and pond evaporation at Nags Head Woods calculated by water budget analyses.

Results of stratigraphic and pedologic analyses in and around the ponds indicate that the ponds formed after development of multiple generations of dunes. This …

Remote Sensing Of Earth Resources System Capabilities V.S. Design Constraints, William Howard Grisham

Retrospective Theses and Dissertations

There is new evidence that global earth resources satellite net will be practical. This paper weighs recent advances in remote sensing to pinpoint the dominant constraints. The data and sensor systems interfacing requirements are critically reviewed. It is shown that conventional optics constraints can be relaxed, with the newer systems, based on multi-spectral imagery and statistical processing methods. The most powerful computational methods use algorithms based on a Gaussian assumption for the species vector in feature space, but biases in the imagery limit their efficiency. A rationale is proposed: improving the observational network calibrating efficiency will also improve the photogrammetric …