Digital Commons Network^™

Dark Matter Halo Concentration And The Evolution Of Spiral Structure In N-Body, Barred Spiral Galaxies, Jazmin Esmeralda Berlanga Medina

Graduate Theses and Dissertations

Motivated by the evidence of relationships between pitch angle (the tightness of spiral arm structure in the disk), P, and various indicators of central mass concentration, as well as the theoretical relationship between halo mass concentration and the density of visible matter in the central part of the galaxy, we look at a possible relationship between P and cvir (the virial concentration of the dark matter halo) in N-body simulations of barred, spiral galaxies. We also look at the evolution of pitch angle over time in higher temporal resolution than any data currently available in the literature. We find that …

Influence Of Shelling Temperature And Time On The Optical And Structural Properties Of Cuins2/Zns Quantum Dots, Colette Robinson

Graduate Theses and Dissertations

CIS/ZnS core/shell QDs are an important class of nanomaterials for optoelectronic, photovoltaic and photoluminescence applications. They consist of lower toxicity materials than the prototypical II-VI Cd-based QDs and show long fluorescence lifetimes, which generates prospective in biological imaging applications. It is vital to develop reproducible synthetic methods for this new class of nanomaterials in order to maintain small sizes with high QYs. CIS core QDs have been shelled with ZnS at various temperatures from 90-210°C for reaction times ranging from 20-140 minutes to examine the role of thermodynamics and kinetics on the shell growth. Using HR-TEM and ICP-MS, it was …

Photochemistry Of A Series Of Weakly Coupled Dinuclear Ruthenium(Ii) Complexes, Latisha Michelle Puckett

Graduate Theses and Dissertations

An improved synthetic method was developed for symmetric ruthenium(II) polypyridine complexes with the form L2Ru(diphen)RuL2. The scope of the reaction was investigated in regards to the ligands, bridging ligands, and starting materials. Several ligands were successful in the synthesis, including 2,2’-bipyridine (bpy), 4,4’-dimethyl-2,2’-dipyridyl (dmb), 1,10-phenanthroline (phen), 4,7-diphenyl-1,10-phenanthroline (dpphen), and 3,4,7,8-tetramethyl-1,10-phenanthroline (tmphen). Ligands that did not react to form symmetric dimeric complexes were 2,2’-bipyrazine, bpz, and 2,2’-bipyrimidine, bpm.

Dpp, 2,3-bis(2-pyridyl)-pyrazine, effectively replaced diphen as the bridging ligand to produce (phen)2Ru(dpp)Ru(phen)24+. However, replacing the [Ru(CO)2Cl2]n with Ru(DMSO)4Cl2 did not prove successful. The newly developed synthesis was also applied to the synthesis of …

The Mass-Pitch Angle Relation For Three High Redshift Active Galaxies Selected From The Goods Field, John Adam Hughes

Graduate Theses and Dissertations

As we continue to investigate and ponder the heavens, we have come to realize the presence of highly energetic gravitational wells at the center of all galaxies. These supermassive black holes at a galaxies nucleus formed in the company of the other features making up the galaxy, particularly spiral arms. With nearby galaxies showing a relationship between the spiral arm pitch angle and that central mass, here we push that relationship out to distances of redshift one. With three galaxies at this distance we find that they also hold to the same relationship of tighter spiral arms corresponding to more …

Probabilistic Graphical Modeling On Big Data, Ming-Hua Chung

Graduate Theses and Dissertations

The rise of Big Data in recent years brings many challenges to modern statistical analysis and modeling. In toxicogenomics, the advancement of high-throughput screening technologies facilitates the generation of massive amount of biological data, a big data phenomena in biomedical science. Yet, researchers still heavily rely on key word search and/or literature review to navigate the databases and analyses are often done in rather small-scale. As a result, the rich information of a database has not been fully utilized, particularly for the information embedded in the interactive nature between data points that are largely ignored and buried. For the past …

Calorimetry And Body Composition Research In Broilers And Broiler Breeders, Justina Victoria Caldas Cueva

Graduate Theses and Dissertations

Indirect calorimetry to study heat production (HP) and dual energy X-ray absorptiometry (DEXA) for body composition (BC) are powerful techniques to study the dynamics of energy and protein utilization in poultry. The first two chapters present the BC (dry matter, lean, protein, and fat, bone mineral, calcium and phosphorus) of modern broilers from 1 – 60 d of age analyzed by chemical analysis and DEXA. DEXA has been validated for precision, standardized for position, and equations and validations developed for chickens under two different feeding levels. These equations are unique to the machine and software in use. Research in broilers …

First Astrophysical Observations With The Low Frequency All Sky Monitor, Emma Youmans Handzo

Theses and Dissertations

The Low Frequency All Sky Monitor (LoFASM) is a radio telescope that consists of dipole antennas. It is sensitive to the frequencies of 10-88MHz. The primary science goals of LoFASM are to detect and study low frequency radio transient events and to develop and test low frequency interference (RFI) mitigation techniques.

Once a telescope starts collecting data, it is necessary to calibrate the telescope to convert the data into standard units. This will allow for scientific deductions to be made from the data. Once the calibration of a telescope is complete it is necessary to determine what astrophysical sources are …

Facile Sol-Gel Molten Salt Synthesis Of Double Perovskite La 2nimno6 As An Electrocatalyst For Oxygen Evolution Reactions, Padmini Kukkapalli

Theses and Dissertations

Double perovskites have attracted a great attention recently for its high intrinsic activity in oxygen evolution reaction (OER) in electrochemical energy storage and conversion systems in alkaline media. In this study, we are the first to report the new approach of La2NiMnO6 double perovskite which was synthesized via Sol-gel molten-Salt synthesis method. However their stability and specific activity remain challenging that need to be addressed to meet the reqiurement for OER activities. Here in this study we synthesized three different samples with varying concentrations by taking molten salts NaNO 3 and KNO3 in (1:1) ratio such as 30:30, 60:60, 90:90. …

The Bourbaki-Jacobson Correspondence, Jose R. Vera

Theses and Dissertations

A general ring theoretic correspondence between subrings of the endomorphism ring of the additive group of a commutative field will be established. This correspondence (called Bourbaki-Jacobson Correspondence) provides the ordinary Galois correspondence when applied to specific group rings. Throughout this thesis, we will work with finite dimensional field extensions.

Molecular Modeling And Mutational Mapping Of The Gpr119 Binding Site, Shane M. Askar

Theses and Dissertations

GPR119 receptor’s biological role in regulating glucose homeostasis has been studied extensively. Results in the scientific literature indicate that, when activated, GPR119 releases insulin in a glucose dependent manner. Currently the 3D structure of GPR119 has not been resolved.

The goal of this research is to use a combination of homology modeling and ligand docking studies to predict the binding mode of GPR119 ligands. Amino acids implicated to have direct interactions with docked ligands will further be assessed experimentally for their roll in binding and activation of GPR119. Our results indicate that residues W2656.48 and R813.28 are likely to be …

On Various Solutions To A (2+1) Dimensional General Camassa-Holm Equation, Eric J. Tovar

Theses and Dissertations - UTB/UTPA

We study a (2+1)-dimensional generalized Camassa-Holm (2dgCH) equation with both quadratic and cubic nonlinearity. We derive a peaked soliton (peakon) solution and multi-peakon solutions. In particular, the two-peakon dynamical system is explicitly presented and their collisions are investigated in detail. We also find weak kink and kink-peakon interactional solutions. Furthermore, we study all possible smooth one-soliton solutions for the system.

Zeros Of Cubic Eisenstein Series, Sahak D. Sandragorsian

Theses and Dissertations - UTB/UTPA

This thesis provides a detailed exposition and extension of the work of F. K. C. Rankin and Swinnerton-Dyer on the location of the zeros of Eisenstein series for SL(2,Z). Exact values of the zeros in special cases will be given in terms of modular functions. Analogous new results on zeros of cubic Eisenstein series will be presented.

Financial Market And Pricing Of Emerging Financial Derivatives: A Mathematical Approach, Haicheng Gu

Theses and Dissertations - UTB/UTPA

Pricing has been one of the key problems of financial market theory. With the development of the modern financial market, various new financial derivatives have been created and need to be priced properly. In the thesis, we are going to use several mathematical tools to investigate the essential structure of the financial market and models for financial derivatives.

Higgs Boson Equation In De Sitter Spacetime: Numerical Investigation Of Bubbles Using Gpus, Jacob N. Banda

Theses and Dissertations - UTB/UTPA

The Higgs field, along with its corresponding boson, represent a milestone for modern day particle physics. In this work we consider the Higgs boson equation in de Sitter spacetime. Previous work by K. Yagdjian [23] has formulated sufficient conditions for the existence of the zeros of global solutions in the interior of their supports. In searching for such solutions, we turn to heterogeneous parallel computing, which allows for faster computation through graphical processing units (GPUs). Armed with general-purpose computation on graphics hardware (GPGPU) techniques and explicit numerical schemes, we approximate solutions of the equation for the Higgs boson along with …

Good Stein Neighborhood Bases For Nonsmooth Pseudoconvex Domains, Chizuko Iwaki

Graduate Theses and Dissertations

In 1979, Dufresnoy showed that the existence of a good Stein neighborhood base for Ω ⊂ℂⁿ implies that one can solve the inhomogeneous Cauchy-Riemann equations in C^∞(Ω̄), even if the boundary of Ω is only Lipschitz. In my thesis, I will show sufficient conditions for the existence of a good Stein neighborhood base on a Lipschitz domain satisfying Property (P).

Static And Dynamical Properties Of Ferroelectrics And Related Material In Bulk And Nanostructure Forms, Zhigang Gui

Graduate Theses and Dissertations

Ferroelectrics (FE) and multiferroics (MFE) have attracted a lot of attentions due to their rich and novel properties. Studies towards FE and MFE are of both fundamental and technological importance. We use a first-principles-based effective Hamiltonian method, conventional ab-initio packages and linear-scale three-dimension fragment method to investigate several important issues about FE and MFE. Tuning the properties of FE and MFE films are essential for miniaturized device applications, which can be realized through epitaxial strain and growth direction. In this dissertation, we use the effective Hamiltonian method to study (i) BaTiO 3 films grown along the (110) pseudocubic direction on …

The Effects Of Strain And Vacancies On The Electric And Vibrational Properties Of Ferroelectric Batio3 From First-Principles, Aldo Serge Michael Raeliarijaona

Graduate Theses and Dissertations

The studies of ferroelectricity (FE) are of technological significance because of the multitude of applicable properties that ferroelectric materials exhibit. The mastery, and control of these properties necessitate the knowledge of the fundamental physics governing these insulating materials.

In this dissertation I present the results of first-principles investigations of the behavior of the fundamental ferroelectric properties under strain, and in the presence of vacancies. In the first part I introduce the important FE properties, their common behavior, and their numerous valuable applications. Following this background on FEs, a review of theoretical methods is presented with topics such as: Density Functional …

Isometries Of Besov Type Spaces Among Composition Operators, Melissa Ann Shabazz

Graduate Theses and Dissertations

Let Bp,alpha for p >1 and alpha >1 be the Besov type space of holomorphic functions on the unit disk D. Given Phi, a holomorphic self map of D, we show the composition operator CPhi is an isometry on Bp,alpha if and only if the weighted composition operator WPhiPhi, is an isometry on the weighted Bergman space Ap,alpha. We then characterize isometries among composition operators in Bp,alpha in terms of their Nevanlinna type counting function. Finally, we find that the only isometries among composition operators on Bp,alpha, except on B 2,0, are induced by rotations. This extends known results by …

Solubility And Detectability Of Hydrocarbons On The Surface Of Titan, Sandeep Singh

Graduate Theses and Dissertations

Titan’s thick atmosphere is enriched with organic compounds and its surface holds reservoirs of hydrocarbons. This makes Titan the only other candidate in our solar system (apart from Earth) to have stable liquid at the surface. The stability and characteristics of liquid and ices on the surface of Titan are of high importance in understanding its surface-atmosphere interactions. Titan’s hydrological cycle is similar to what we see on Earth, with the exception of methane (CH4) and ethane (C2H6) taking the place of water. The smoggy atmosphere veils the surface of Titan from the view of Cassini spacecraft, except at seven …

Fret Study Of Ligand Binding And Exchange Kinetics On The Surface Of Cdse/Zns Quantum Dots, Randee Jean Mcbride

Graduate Theses and Dissertations

Quantum dots are a valuable tool in many research applications and commercial development. Their applications are far reaching and as such have become a topic of great interest. One of their greatest assets is the ability to utilize them as water soluble fluorescent labels. Rendering the nanocrystals water soluble can be accomplished in several ways, but one very popular method is by capping them with water-soluble multi-functional organic ligands. However, these ligands, when attached to the quantum dot surface, are labile and can be exchanged which can be problematic when using the quantum dots in research applications. This projects investigates …

In Vitro Microdialysis Sampling Collection Of Volatile Organic Compounds (Voc's), Dodecafluoropentane (Ddfp) And Isoflurane, Valerie Shannon Mckinney

Graduate Theses and Dissertations

Death by stroke occurs every four minutes to human beings. Strokes cause necrosis within the tissue of the brain due to deprivation of oxygen. Perfluorocarbons have the ability to transport oxygen to tissue and in return decrease cell death. Dodecafluoropentane (DDFP) is a volatile fluorocarbon and collection in vivo can be a challenge since this compound evaporates at room temperature. There is currently not an efficient collection method in vivo for compounds that are volatile. Without a method to collect DDFP it is impossible to be approved for clinical use since exact concentrations of the drug within the body will …

Engineering The Ground State Of Complex Oxides, Derek Joseph Meyers

Graduate Theses and Dissertations

Transition metal oxides featuring strong electron-electron interactions have been at the forefront of condensed matter physics research in the past few decades due to the myriad of novel and exciting phases derived from their competing interactions. Beyond their numerous intriguing properties displayed in the bulk they have also shown to be quite susceptible to externally applied perturbation in various forms. The dominant theme of this work is the exploration of three emerging methods for engineering the ground states of these materials to access both their applicability and their deficiencies.

The first of the three methods involves a relatively new set …

Fundamental Studies Of Magnetoconvective Forces And Density Gradients In A Microfluidic Environment, Adam James Kreidermacher

Graduate Theses and Dissertations

Magnetoconvection is a promising phenomenon for developing new electrochemical-based microfluidic flow devices with unique capabilities, such as easily switching flow direction and adjusting flow speeds and flow patterns as well as avoiding bubble formation. In order to develop these devices it is necessary to study the underlying forces. Four contributions toward fluid flow were considered. The first and foremost is the magnetohydrodynamic force, which is the magnetic component of the Lorentz force and governed by the right hand rule. It generates the majority of the convention, and is the most well-known. The second is the gravitational force, which causes convection …

Surface Modification Of Noble Metal Nanostructures Toward Biomedical Applications, Samir V. Jenkins

Graduate Theses and Dissertations

Noble metal nanostructures have seen a steady increase in biomedical application over the last several decades; new diagnostic and therapeutic modalities are under intense investigation. Many of these applications are possible because of post-synthetic modifications to the particle surface. These modifications take a variety of forms and can significantly affect the pharmacokinetics of these particles. In this work, various surface modifications were investigated. Particle agglomeration, which occurs when particle surfaces remain in contact, can significantly affect the toxicity and efficacy of a nanomedicine. Darkfield microscopy and single-particle ICP-MS were developed as complementary methods to detect agglomeration in blood, with the …

Designing Fret Assays To Study Electrostatic Interactions Pertaining To The Binding Of Intrinsically Disordered Proteins, Ashley Ann Howard

Graduate Theses and Dissertations

Fibroblast growth factor receptor plays a major role in several biological processes. Without FGFR, a human cannot live. FGFR is involved in cell differentiation and wound healing. Of course, if FGFR signaling becomes unregulated, it causes severe distress in the body. Several cancers are contributed to high signaling levels, as well as developmental conditions like rickets and Kallmann’s syndrome. FGFR is thought to undergo an auto-inhibition (or self-regulatory) process in order to try to facilitate regulation. The exact method of this inhibition is currently unknown, but is proposed to involve the unstructured acid box region of FGFR. We developed a …

Asymmetric Synthesis And Transition Metal-Catalyzed Cross-Coupling Arylations Of Selected Organolithiums, Barry Kyle Sharp

Graduate Theses and Dissertations

My former boss, Dr. Gawley, always loved to say, “The world is chiral” (à la Pasteur). From DNA and proteins to hands and feet, it is obviously true. Also, a wide variety of chemical products exist as single enantiomers. Advances in chemical technology have greatly accelerated asymmetric synthesis in the past quarter century, and namely, organolithiums, have been shown to provide a versatile route to chiral natural products and biologically active molecules. Versatility arises from the array of methods that produce a chiral organolithium. Dynamic thermodynamic resolution (DTR) is considered one of the most practical methods, but among the others …

A Study On Hispanic College Students' Mathematics Anxiety, Study Habits, And Academic Performances On Mathematics, Luis M. Fernandez

Theses and Dissertations - UTB/UTPA

Mathematics anxiety has been described as a feeling of apprehension, fear, tension, and discomfort when confronted with mathematics. Mathematics anxiety has also been shown to interfere with mathematics performance; therefore, for our research we investigated what portions of individuals seem to suffer higher levels of mathematics anxiety and to what extent they are affected by it. We also investigated the study habits of the students and how these affect their mathematics anxiety levels and overall mathematics performance. Our data was obtained from Hispanic undergraduate students (n=405) who took Elementary Algebra (Math 1300), Intermediate Algebra (Math 1334), College Algebra (Math 1340) …

Approximate Analysis Solution Of Burgers-Kdv Equation, Hani Aldirawi

Theses and Dissertations - UTB/UTPA

In this thesis, we study the Two-Dimensional Burgers-Kortewege-de Vries(2D-BKdV) equation by analyzing the equivalent Abel equation, which indicates that under some particular conditions, the 2D-BKdV equation has a unique bounded traveling wave solution. By using the theorem of contractive mapping, a traveling wave solution to the 2D-BKdV equation is expressed explicitly.

Population Dynamics In Active Galactic Nuclei, Jon Bessler

Graduate Theses and Dissertations

The goal of this thesis is to present an approach to understanding the dynamics that govern the evolution of active galactic nuclei (AGN) in general, and those associated with spiral galaxies in particular. This approach starts with the continuity equation governing the mass function for a population of supermassive black holes (SMBHs). This approach is then extended to the luminosity function for AGN. Where the dynamical parameters that govern accretion are fairly well known, those values are adopted. The values that are not as well known are constrained by comparing evolved luminosity functions with observed luminosity functions. Boundary conditions for …

Epitaxial Growth Of Silicon On Poly-Crystalline Si Seed Layer At Low Temperature By Using Hot Wire Chemical Vapor Deposition, Manal Abdullah Aldawsari

Graduate Theses and Dissertations

There has been a growing interest in using low cost material as a substrate for the large grained polycrystalline silicon photovoltaic devices. The main property of those devices is the potential of obtaining high efficiency similar to crystalline Si devices efficiency yet at much lower cost because of the thin film techniques. Epitaxial growth of Si at low temperatures on low cost large grained seed layers, prepared by aluminum induced crystallization method (AIC), using hot wire chemical vapor deposition (HWCVD) system is investigated in this thesis. In this work, different parameters have been studied in order to optimize the growth …