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Articles 1 - 30 of 1018
Full-Text Articles in Entire DC Network
Localized Corrosion Behavior Of Sensitized 304 Stainless Steel By Scanning Reference Electrode Technique, Chen-Qing Ye, Rong-Gang Hu, Rui-Qing Hou, Xiao-Ping Wang, Rong-Gui Du, Chang-Jian Lin
Localized Corrosion Behavior Of Sensitized 304 Stainless Steel By Scanning Reference Electrode Technique, Chen-Qing Ye, Rong-Gang Hu, Rui-Qing Hou, Xiao-Ping Wang, Rong-Gui Du, Chang-Jian Lin
Journal of Electrochemistry
Based on a home-built setup of scanning reference electrode technique, and combined with conventional electrochemical measurements, the localized corrosion behavior of sensitized 304 stainless steel (304ss) had been investigated in this work. The results showed that, the non-sensitized 304ss or 304ss sensitized at 550 oC was susceptible to pitting; while 304ss sensitized at 650 oC or 750 oC suffered severe intergranular corrosion in 10% FeCl3 solution.
Study On Hydrogen Bubble Template Fabrication Of Porous Biomaterials Coatings By Electrochemically Induced Deposition, Hui Wang, Chang-Jian Lin, Ren Hu, Ke-Qin Zhang, Hong-Ping Duan, Xiang Dong
Study On Hydrogen Bubble Template Fabrication Of Porous Biomaterials Coatings By Electrochemically Induced Deposition, Hui Wang, Chang-Jian Lin, Ren Hu, Ke-Qin Zhang, Hong-Ping Duan, Xiang Dong
Journal of Electrochemistry
So far, the pore architecture in biomaterials plays a critical role on the cell response and integration between the biomaterials and implanted environment. In this study, porous calcium phosphate (CaP) coatings and CaP/protein composite coatings have been successfully constructed on titanium substrate by using an electrochemically induced deposition technique. The shape, size and pliability of CaP crystals are controlled by electrolyte concentration, temperature, current density, time and protein additive in preparing process. In addition, the formation mechanism of the porous structure is discussed based on the “hydrogen bubble template” model. It demonstrates that the growth velocity of CaP crystals should …
Effect Of Vanadium Substitution On Structure Of Li2Fesio4/C Composites, Yang Hong, Zhang Ying, Cheng Xuan
Effect Of Vanadium Substitution On Structure Of Li2Fesio4/C Composites, Yang Hong, Zhang Ying, Cheng Xuan
Journal of Electrochemistry
The carbon coated lithium iron silicate (Li2FeSiO4/C) composites were prepared using less expansive iron starting material of soluble ferric nitrate through sol-gel process and solid state reaction. The theoretically calculated amounts of 5, 10, 15, 20, 25, 30, and 50% of vanadium (V) were introduced using NH4VO3 to obtain V-substituted Li2FeSiO4/C composites. It was found that the pure Li2FeSiO4/C composite exhibited a good crystallinity with P21/n and nearly no impurities being detected, while the V-substituted Li2FeSiO4/C composites showed major impurities of Li2SiO3 …
Cmk-3/Sulfur Composite (CXSY) And Room-Temperature Na/S Battery, Qing Zhao, Yu-Xiang Hu, Kai Zhang, Li-Jiang Wang, Zhan-Liang Tao, Jun Chen
Cmk-3/Sulfur Composite (CXSY) And Room-Temperature Na/S Battery, Qing Zhao, Yu-Xiang Hu, Kai Zhang, Li-Jiang Wang, Zhan-Liang Tao, Jun Chen
Journal of Electrochemistry
A series of ordered mesoporous carbon (CMK-3)/sulfur composite (CxSy) with different sulfur contents were synthesized via a melt-diffusion method. XRD, Raman, BET, SEM, and TEM techniques were used to characterize the structure and morphology of the as-prepared composite. The electrochemical performance of CMK-3/sulfur composite as the electrode of Na/S battery was tested at room temperature. Cyclic voltammograms show that one obvious reduction peak was located at about 1.61V, which is corresponding to the formation of Na2Sx (x=2~5), while two oxidation peaks were displayed at about 1.82V and 1.95V, which are belonging to the …
Surface Composition Structure And Electrochemical Performance Of Aluminum Doped Lifepo4, Huai-Fang Shang, Wei-Feng Huang, Wang-Sheng Hu, Ding-Guo Xia, Zi-Yu Wu
Surface Composition Structure And Electrochemical Performance Of Aluminum Doped Lifepo4, Huai-Fang Shang, Wei-Feng Huang, Wang-Sheng Hu, Ding-Guo Xia, Zi-Yu Wu
Journal of Electrochemistry
Despite there are many successful reports about the preparation of electrode materials with surface coating for lithium ion batteries, the study in surface self-coating of cathode materials using segregation of doping elements and their electrochemical properties is still very rare. The LiFePO4 particles with rich-Al on the surface were synthesized by one step solvothermal route. TEM results demonstrated that the surface of the obtained LiFePO4 particles was well-covered by the amorphous coating. The soft X-ray absorption spectroscopy (XAS) and Auger electron spectroscopy (AES) component analyses revealed that the amorphous coating was composed of LiFe1-xAlxPO …
Controllable Synthesis Of Dispersed Spherical Fe3O4 Nanoparticles As Lithium-Inserted Materials, Hong-Li Zou, Wei-Shan Li
Controllable Synthesis Of Dispersed Spherical Fe3O4 Nanoparticles As Lithium-Inserted Materials, Hong-Li Zou, Wei-Shan Li
Journal of Electrochemistry
Dispersed spherical Fe3O4 nanoparticles were synthesized by a hydrothermal method. The influences of odecyl trimethyl ammonium bromide (DTAB) concentration on the morphology and particle size of the as-prepared Fe3O4 were studied. Electrochemical performance of the as-prepared sample as anode materials of lithium ion battery was investigated. It is found that the as-prepared sample exhibits superior rate performance and cycle performance. The nano-sized materials provide structural stability and favor the transfer of lithium ions.
Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-Qing Fang, Rui-Xue Zhang, Wei-Wei Liu, Bing-Bo Xia, Hong-Dan Sun, Hai-Bo Wang, Jing-Jing Wu, Shinko Kaneko, De-Cheng Li
Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-Qing Fang, Rui-Xue Zhang, Wei-Wei Liu, Bing-Bo Xia, Hong-Dan Sun, Hai-Bo Wang, Jing-Jing Wu, Shinko Kaneko, De-Cheng Li
Journal of Electrochemistry
The amorphous ZnSnO3@C composite was synthesized via a simple glucose hydrothermal and subsequent carbonization approach. The structure, morphology and electrochemical property of the composite were characterized by XRD, TEM and electrochemical measurements. Compared to bare ZnSnO3, the ZnSnO3/C composite exhibited markedly enhanced lithium storage property and cycle performance, delivering a reversible capacity of 659 mAh·g-1 after 100 cycles at a current density of 100 mA·g-1.
An Investigation On The Solid Electrolyte Interphase Of Silicon Anode For Li-Ion Batteries Through Force Curve Method, Jie-Yun Zheng, Hao Zheng, Rui Wang, Hong Li, Li-Quan Chen
An Investigation On The Solid Electrolyte Interphase Of Silicon Anode For Li-Ion Batteries Through Force Curve Method, Jie-Yun Zheng, Hao Zheng, Rui Wang, Hong Li, Li-Quan Chen
Journal of Electrochemistry
Non-aqueous electrolyte has been widely used in commercial Li-ion batteries. Optimized choices are proceeding among the various types of salts and solvents in an effort to achieve higher performance of electrolyte. However, the electrolyte will be reduced in low potential and the reductive product will be deposited on the surface of anode to form a passivating layer, solid electrolyte interphase (SEI). Herein an atomic force microscopy (AFM) based method was introduced to study the structure and mechanical property of SEI on silicon thin film anode during the first cycle. Silicon has been known as the most potential candidate anode for …
Synthesis And Electrochemical Property Of Li2Fesio4/C Cathode Material By Solid State Method, Jiao-Li Sun, Zhi-Jiao Chen, Yi-Xiao Li, Hu Cheng
Synthesis And Electrochemical Property Of Li2Fesio4/C Cathode Material By Solid State Method, Jiao-Li Sun, Zhi-Jiao Chen, Yi-Xiao Li, Hu Cheng
Journal of Electrochemistry
Li2FeSiO4/C cathode material was synthesized using Li2SiO3 and FeC2O4 as raw materials by solid state method. The structure and morphology of the material were characterized by XRD and SEM. The electrochemical properties of the material were studied by constant-current cyclic testing. The results show that Li2FeSiO4/C has a good electrochemical performance. The first discharge capacity of Li2FeSiO4/C cathode material at 30oC reached 167 mAhg-1 when cycled at 10 mAg-1 between 1.5 and 4.8 V.
Preparation And Electrochemical Properties Of Flake-Like Liv3O8 By Soft Template Assisted Sol-Gel Method As Anode Material For Aqueous Li-Ion Battery, Shuai Tan, Dan Sun, Hai-Yan Wang, Tian-Li Hou, Zhong-Xing Xiao, You-Gen Tang
Preparation And Electrochemical Properties Of Flake-Like Liv3O8 By Soft Template Assisted Sol-Gel Method As Anode Material For Aqueous Li-Ion Battery, Shuai Tan, Dan Sun, Hai-Yan Wang, Tian-Li Hou, Zhong-Xing Xiao, You-Gen Tang
Journal of Electrochemistry
Anode material has become the key issue for restricting the development of aqueous lithium ion battery (ALIB). Flake-like LiV3O8 materials were synthesized by sol-gel method using sodium dodecyl benzene sulfonate (SDBS) as a template. The XRD and SEM results showed that as-prepared flake-like LiV3O8 was of high purity with monoclinic system and P21/m space group. LiMn2O4//Li2SO4//LiV3O8 ALIB was assembled and tested. As observed, the flake-like LiV3O8 here exhibited good high-rate performance and cycling stability. A high discharge capacity of 154 mAh.g-1 (based on the mass …
Synthesis And Electrochemical Performance Of Nano Licopo4 By Polyol Method, Fei Wang, Yang Jun
Synthesis And Electrochemical Performance Of Nano Licopo4 By Polyol Method, Fei Wang, Yang Jun
Journal of Electrochemistry
High potential LiCoPO4 cathode material was synthesized by polyol method. Carbon layer of ca. 3 nm thick was coated on the LiCoPO4 surfaces by chemical vapor deposition from methylbenzene. Crystalline structure, morphology and electrochemical performance of the sample were studied by XRD, SEM, TEM, CV and galvanostatic charge/discharge curve. The synthesized material via polyol method showed a pure phase of LiCoPO4. The LiCoPO4/C electrode delivered a high discharge capacity of 132 mAh·g-1 and maintained 78% of the initial capacity after 50 cycles at 0.1C rate. The two-step extraction/insertion behavior of Li+ in LiCoPO4/C …
Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia
Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia
Journal of Electrochemistry
We adopted an effective route to prepare the particle size controllable core-shell structure carbon-coated LiFePO4 from different sized FePO4 precursors, varying from 80 nm, 200 nm and 1 μm by an in situ polymerization method integrated with a surface modification technology. The discharge capacities of the three sized LiFePO4/C are, respectively, 162 mAh·g-1, 142 mAh·g-1 and 92 mAh·g-1 at 0.1C rate. The nano-sized LiFePO4-a/C (80 nm) delivers a discharge capacity as large as 100 mAh·g-1 even at 30C, while the macroscopic LiFePO4-c/C (1 μm) exhibits a much poorer discharge …
Aqueous Solution-Evaporation Route Synthesis And Phase Structural Research Of The Li-Rich Cathode Li1.23Ni0.09Co0.12Mn0.56O2 By In-Situ Xrd, Chong-Heng Shen, Shou-Yu Shen, Zhou Lin, Xiao-Mei Zheng, Hang Su, Ling Huang, Jun-Tao Li, Shi-Gang Sun
Aqueous Solution-Evaporation Route Synthesis And Phase Structural Research Of The Li-Rich Cathode Li1.23Ni0.09Co0.12Mn0.56O2 By In-Situ Xrd, Chong-Heng Shen, Shou-Yu Shen, Zhou Lin, Xiao-Mei Zheng, Hang Su, Ling Huang, Jun-Tao Li, Shi-Gang Sun
Journal of Electrochemistry
The Li-rich Li1.23Ni0.09Co0.12Mn0.56O2 material was synthesized via aqueous solution-evaporation route. The structure and morphology of the material were characterized by means of XRD and SEM. The results indicated that the single particle of the product was polygonal with the size of 330 nm and the structure was layered solid solution with a certain amount of Li2MnO3. Electrochemical tests showed that the first discharge capacity of the Li-rich layered material was 250.8 mAh·g-1 at 0.1C,the capacity retention was 86.5% after 40 cycles. Through in-situ XRD study a …
Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries, Jiang-Feng Qian, Xue-Ping Gao, Han-Xi Yang
Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries, Jiang-Feng Qian, Xue-Ping Gao, Han-Xi Yang
Journal of Electrochemistry
Oncoming large scale electric energy storage (EES) requires battery systems not only to have sufficient storage capacity but also to be cost-effective and environmentally friendly. Li-ion batteries for widespread EES applications may be limited due to the constraint of global lithium resource. From the considerations of available resources and environmental impact, Na-ion batteries have potential advantages as next generation secondary batteries and an alternative to Li-ion batteries. However, in the present state of the art, the Na-storage cathodes reported so far are still deficient both in energy density and power capability, while the carbon and alloy anodes for Na-ion batteries …
Application Of Synchrotron Radiation Based Electrochemical In-Situ Techniques To Study Of Electrode Materials For Lithium-Ion Batteries, Zheng-Liang Gong, Wei Zhang, Dong-Ping Lv, Xiao-Gang Hao, Wen Wen, Zheng Jiang, Yong Yang
Application Of Synchrotron Radiation Based Electrochemical In-Situ Techniques To Study Of Electrode Materials For Lithium-Ion Batteries, Zheng-Liang Gong, Wei Zhang, Dong-Ping Lv, Xiao-Gang Hao, Wen Wen, Zheng Jiang, Yong Yang
Journal of Electrochemistry
Due to its merits of high brightness and high intensity, high level of polarization and wide tunability in energy, etc., synchrotron radiation technique provides an unique platform for analysis of the relationship among composition–structure–performance of materials for lithium ion batteries, especially for in-situ, real time dynamic investigation of the electrochemical reaction mechanism, aging process and failure mechanism during charge-discharge cycling. In this paper, we review the latest developments in application of synchrotron based electrochemical in-situ experimental methods to studies of lithium ion batteries. The paper mainly focuses on the application of electrochemical in-siu XRD and XAFS techniques to the investigations …
Table Of Contents, Michele Harmon
Table Of Contents, Michele Harmon
Journal of the South Carolina Academy of Science
No abstract provided.
Dose Dependent Effects Of Caffeine On Cognitive Performance And Neuronal Activation, Stephan Albrecht, Helen Morris, Michelle Vieyra
Dose Dependent Effects Of Caffeine On Cognitive Performance And Neuronal Activation, Stephan Albrecht, Helen Morris, Michelle Vieyra
Journal of the South Carolina Academy of Science
Many students assume that the more caffeine you drink, the better your cognitive performance. Over-consumption of caffeine has many negative effects, so if there are no dose related cognitive benefits to large amounts of caffeine, then college students should limit their intake. This study looked at whether ingesting a medium dose (200 mg) versus a lower dose (100 mg) of caffeine improved short term memory as measured by Flanker and n-back tests, compared to a control group. In addition, we looked at whether larger doses of caffeine produced a difference in neuronal activation during these tests as measured by functional …
An Improved Fibonacci Inequality, Cameron T. Cooper, Fidele F. Ngwane, Wei-Kai Lai
An Improved Fibonacci Inequality, Cameron T. Cooper, Fidele F. Ngwane, Wei-Kai Lai
Journal of the South Carolina Academy of Science
Fibonacci numbers and Fibonacci sequences play a key role in many areas of mathematics and other sciences. Many inequalities satisfied by Fibonacci sequences have been established. In this paper we prove a new Fibonacci inequality using Candido's identity.
Fourier Analysis Of Phase Resetting Curves Of Neural Oscillators, Robert A. Raidt, Sorinel A. Oprisan
Fourier Analysis Of Phase Resetting Curves Of Neural Oscillators, Robert A. Raidt, Sorinel A. Oprisan
Journal of the South Carolina Academy of Science
We investigated the impact of changes in biologically relevant control parameters, such as the shape of an external perturbation or the conductance values of an individual model neuron, on the shape of the phase resetting curve (PRC) of that neuron. For that purpose, PRCs were generated for groups of Morris-Lecar (ML) model neurons with different conductance values but similar firing periods (within 0.005ms) using external rectangular, triangular, or trapezoidal perturbations of varying areas. These PRCs were numerically described and analyzed as a series of coefficient values using a Fourier Discrete Sine Transform (DST). We found that changes in the shape …
Nmr Determination Of Enantiomeric Composition Of Chiral Alcohols Using Camphorsulfonate Esters, Steven Bondi Fcrh '11, Thomas Lobasso Fcrh '09, Christa Iwanoski Fcrh '09, Shahrokh Saba, Donald Clarke
Nmr Determination Of Enantiomeric Composition Of Chiral Alcohols Using Camphorsulfonate Esters, Steven Bondi Fcrh '11, Thomas Lobasso Fcrh '09, Christa Iwanoski Fcrh '09, Shahrokh Saba, Donald Clarke
The Fordham Undergraduate Research Journal
Most biologically active compounds, including pharmaceuticals, have chiral molecular structures. With increased recognition that enantiomers of chiral drugs are metabolized differently, there has been enormous interest in the development of enantioselective methodologies for the synthesis of chiral compounds. NMR spectroscopy has emerged as a powerful method for discrimination of enantiomers of chiral compounds. 1 One strategy by which the NMR method is exploited is based on converting the enantiomers of a chiral compound to diastereomers using a chiral derivatizing agent. These diastereomers often display anisochronous NMR signals, which can be identified and integrated affording quantitative measurements of the optical purity …
Synthesizing Population, Health, And Place, Martin Raubal, Geoffrey Jacquez, John Wilson, Werner Kuhn
Synthesizing Population, Health, And Place, Martin Raubal, Geoffrey Jacquez, John Wilson, Werner Kuhn
Journal of Spatial Information Science
No abstract provided.
An Interactive Bibliography On Temporal Gis, Willington Siabato, Christophe Claramunt, Miguel Ángel Bernabé-Poveda
An Interactive Bibliography On Temporal Gis, Willington Siabato, Christophe Claramunt, Miguel Ángel Bernabé-Poveda
Journal of Spatial Information Science
No abstract provided.
Formalizing Spatiotemporal Knowledge In Remote Sensing Applications To Improve Image Interpretation, Christelle Pierkot, Samuel Andrés, Jean François Faure, Frédérique Seyler
Formalizing Spatiotemporal Knowledge In Remote Sensing Applications To Improve Image Interpretation, Christelle Pierkot, Samuel Andrés, Jean François Faure, Frédérique Seyler
Journal of Spatial Information Science
Technological tools allow the generation of large volumes of data. For example satellite images aid in the study of spatiotemporal phenomena in a range of disciplines such as urban planning environmental sciences and health care. Thus remote-sensing experts must handle various and complex image sets for their interpretations. The GIS community has undertaken significant work in describing spatiotemporal features and standard specifications nowadays provide design foundations for GIS software and spatial databases. We argue that this spatiotemporal knowledge and expertise would provide invaluable support for the field of image interpretation. As a result we propose a high level conceptual framework …
Multi-Scale Window Specification Over Streaming Trajectories, Kostas Patroumpas
Multi-Scale Window Specification Over Streaming Trajectories, Kostas Patroumpas
Journal of Spatial Information Science
Enormous amounts of positional information are collected by monitoring applications in domains such as fleet management cargo transport wildlife protection etc. With the advent of modern location-based services processing such data mostly focuses on providing real-time response to a variety of user requests in continuous and scalable fashion. An important class of such queries concerns evolving trajectories that continuously trace the streaming locations of moving objects like GPS-equipped vehicles commodities with RFID's people with smartphones etc. In this work we propose an advanced windowing operator that enables online incremental examination of recent motion paths at multiple resolutions for numerous point …
The Semantic Similarity Ensemble, Andrea Ballatore, Michela Bertolotto, David C. Wilson
The Semantic Similarity Ensemble, Andrea Ballatore, Michela Bertolotto, David C. Wilson
Journal of Spatial Information Science
Computational measures of semantic similarity between geographic terms provide valuable support across geographic information retrieval data mining and information integration. To date a wide variety of approaches to geo-semantic similarity have been devised. A judgment of similarity is not intrinsically right or wrong but obtains a certain degree of cognitive plausibility depending on how closely it mimics human behavior. Thus selecting the most appropriate measure for a specific task is a significant challenge. To address this issue we make an analogy between computational similarity measures and soliciting domain expert opinions which incorporate a subjective set of beliefs perceptions hypotheses and …
Semantic And Conceptual Issues In Geographic Information Systems, Eliseo Clementini, Esteban Zimanyi
Semantic And Conceptual Issues In Geographic Information Systems, Eliseo Clementini, Esteban Zimanyi
Journal of Spatial Information Science
No abstract provided.
Testing Ogc Web Feature And Coverage Service Performance: Towards Efficient Delivery Of Geospatial Data, Gregory Giuliani, Alain Dubois, Pierre Lacroix
Testing Ogc Web Feature And Coverage Service Performance: Towards Efficient Delivery Of Geospatial Data, Gregory Giuliani, Alain Dubois, Pierre Lacroix
Journal of Spatial Information Science
OGC Web Feature Service (WFS) and Web Coverage Service (WCS) specifications allow interoperable access to distributed geospatial data made available through spatial data infrastructures (SDIs). To ensure that a service is sufficiently responsive to fulfill users’ expectations and requirements performance of services must be measured and monitored to track latencies bottlenecks and errors that may negatively influence its over- all quality. Despite the importance of data retrieval and access little research has been published on this topic and mostly concentrates on the usability of services when integrating distributed data sources. Considering these issues this paper extends and validates the FOSS4G …