Digital Commons Network^™

On The Classification Of Generalized Pseudo-Orthogonal Lie Groups Via Curvature, Cohomology, And Algebraic Structure, Adam C. Fletcher

Graduate Theses, Dissertations, and Problem Reports

The study of Lie groups has yielded a rich catalogue of mathematical spaces that, in some sense, provide a theoretical and computational framework for describing the “world in which we live.” In particular, these topological groups that represent the rigid motions of a space, the behavior of subatomic particles, and the shape of the expanding universe consist of specialized matrices. In what follows, we define a new collection of matrices with a very specific transposition relation and attempt to classify this Lie group algebraically, geometrically, and topologically. We consider fields, $\Bbb{F},$ of characteristic zero and define the group of pseudo-orthogonal …

Evaluating Remote Economic Benefits Of Watershed-Scale Acid Mine Drainage Restoration, Rachel E. Pell

Graduate Theses, Dissertations, and Problem Reports

In 2011, the West Virginia Abandoned Mine Lands and Reclamation Program (WVAML) implemented a watershed-scale restoration project in Three Fork Creek, a 103 square-mile watershed in rural West Virginia impaired by acid mine drainage (AMD). This was accomplished through the installation of four in-stream lime dosers in 2011. Due to the great capital investment in the restoration of Three Fork Creek and an interest in applying this watershed-scale approach to other watersheds throughout West Virginia, it is of great interest to demonstrate the successes of this remediation. It has already been demonstrated that the watershed has visibly improved and is …

Hot-Carrier Dynamics And Transport Mechanisms In Inas/Alassb Multiple Quantum Wells, Herath Pathiranage Janaka Chathuranga Piyathilaka

Graduate Theses, Dissertations, and Problem Reports

Semiconductor photovoltaics convert light into electricity through the extraction of photo-excited charge carriers. Among the most important parameters for a photovoltaic cell are good optical absorption in the desired region of the electromagnetic spectrum, and sufficient excited-state lifetimes and mobilities of the photocarriers to allow for charge separation and extraction before recombination. For solar cell applications there are significant challenges to overcome to improve the efficiency of the light-to-electricity conversion. The cells are most commonly made of silicon, which has a nearly perfect bandgap for absorbing the most solar radiation, an indirect bandgap to give a long photocarrier lifetime and …

On Generalizations Of Supereulerian Graphs, Sulin Song

Graduate Theses, Dissertations, and Problem Reports

A graph is supereulerian if it has a spanning closed trail. Pulleyblank in 1979 showed that determining whether a graph is supereulerian, even when restricted to planar graphs, is NP-complete. Let $\kappa'(G)$ and $\delta(G)$ be the edge-connectivity and the minimum degree of a graph $G$, respectively. For integers $s \ge 0$ and $t \ge 0$, a graph $G$ is $(s,t)$-supereulerian if for any disjoint edge sets $X, Y \subseteq E(G)$ with $|X|\le s$ and $|Y|\le t$, $G$ has a spanning closed trail that contains $X$ and avoids $Y$. This dissertation is devoted to providing some results on $(s,t)$-supereulerian graphs and …

Examining Evolutionary Rate In Xiphosura, Samantha B. Ocon

Graduate Theses, Dissertations, and Problem Reports

Horseshoe crabs, a group of aquatic chelicerate arthropods of the class Xiphosura, are strongly linked with the concept of “living fossils” – a term colloquially used to refer to clades that display a consistently low rate of morphological evolution through time. The concept of living fossils has been hotly debated, as it is considered to simplify or obscure millennia of evolutionary change. Recent methodological and computational advances in the paleobiological sciences have allowed for the investigation of these claims. Xiphosura are a model taxon for this type of investigative study because they exhibit a complex evolutionary history, despite their reputation …

Identifying And Minimizing Sources Of Variability Within Modern Spectroscopic Techniques For The Forensic Analysis Of Glass, Oriana Christy Ovide

Graduate Theses, Dissertations, and Problem Reports

Broken glass is a trace material frequently found at crime scenes such as hit-and-runs, burglaries, assaults, and homicides. Existing research encompassing the forensic analysis of glass evidence is vast. Published studies cover the analysis and interpretation of various types of glass. However, organizations such as the National Institute of Justice (NIJ), National Institute of Standards and Technology Organization of Scientific Area Committees (NIST-OSAC), and American Society of Trace Evidence Examiners (ASTEE) continue to identify glass-specific research needs to strengthen the scientific foundations of the field. Current gaps within the forensic glass community involve understanding modern glass formulations, re-evaluating the performance …

Deep Radio Observations And The Role Of The Cosmic Web In Galaxy Evolution, Nicholas M. Luber

Graduate Theses, Dissertations, and Problem Reports

A current open question in the evolution of galaxies, is what are the physical mechanisms that cut off galaxies from their primordial gas reservoirs, resulting in the end of their star-formation capabilities? Recent observational programs have shown that the properties of galaxies show dependencies on their placement within the large-scale structure (LSS) of the universe. These observations have motivated recent developments in theoretical work that have shown how a galaxy's interaction with the LSS may impact its connection to primordial gas supply, and ability to continue to accrete gas, the fundamental ingredient in star-formation.

In order to investigate the role …

A Monte Carlo Simulation Of Rat Choice Behavior With Interdependent Outcomes, Michelle A. Frankot

Graduate Theses, Dissertations, and Problem Reports

Preclinical behavioral neuroscience often uses choice paradigms to capture psychiatric symptoms. In particular, the subfield of operant research produces nested datasets with many discrete choices in a session. The standard analytic practice is to aggregate choice into a continuous variable and analyze using ANOVA or linear regression. However, choice data often have multiple interdependent outcomes of interest, violating an assumption of general linear models. The aim of the current study was to quantify the accuracy of linear mixed-effects regression (LMER) for analyzing data from a 4-choice operant task called the Rodent Gambling Task (RGT), which measures decision-making in the context …

Heterogeneous Oxidation Of Multi-Component Aqueous Organic Aerosols: The Effect Of Transport Phenomena And Reaction Compartment On Reaction Kinetics., Tadini Wenyika Masaya

Graduate Theses, Dissertations, and Problem Reports

The surface-bulk partitioning of small organic molecules in aqueous droplets was investigated using molecular dynamics. The air-particle interface was modeled using a 80-Å cubic water box containing series of organic molecules and surrounded by gaseous OH radicals. The properties of the organic solutes within the interface and the water-bulk were examined at a molecular-level using density profiles and radial pair distribution functions. Molecules containing only polar functional groups such as urea and glucose are found predominantly in the water bulk, forming an exclusion layer near the water surface. Substitution of a single polar group by an alkyl group in sugars …

Cycle Decomposition For Integral Current Homology, Kristin Julia Duling

Graduate Theses, Dissertations, and Problem Reports

A standard graph theoretical result states that every element of the cycle space of a graph has a cycle decomposition. Georgakopoulos expands this result to a primitive decomposition and minimal representation of each element in a modified 1-dimensional singular homology. We modify the m-dimensional integral current homology in order to ensure a primitive decomposition for each element.

Polarization Properties Of Millisecond Pulsars: Astrophysical Interpretations And Applications, Haley Megan Wahl

Graduate Theses, Dissertations, and Problem Reports

Pulsars are some of the most extreme objects in the universe; their small yet incredibly predictable spin periods coupled with their strong magnetic fields make them ideal laboratories for study. Not only are they interesting objects themselves, but they can also help us probe different astrophysical environments, such as the interstellar magnetic field and the solar corona.

These stars are highly polarized, and that polarization comes into play in various fields of pulsar physics (such as constraining models of pulsar emission), but obtaining that polarization information can be difficult, as the polarization properties of the light can change as the …

Electronic Structure Of Early Transition Metal Complexes Supported By Pyridine Polypyrrolide Ligands, Dylan Connor Leary

Graduate Theses, Dissertations, and Problem Reports

A thorough study of photoluminescent molecules involving the pyridine polypyrrole(ide) ligand platform has been conducted. A detailed analysis on speciation of the proligand H₂(^MesPDP^Ph) (H₂^MesPDP^Ph = 2,6-bis(5-mesityl-3-phenyl-1H-pyrrol-2-yl)-pyridine) and its dilithium salt Li₂(^MesPDP^Ph) revealed temperature- and solvent-dependent effects. These molecules, along with the hydrochloric acid adduct [H₃(^MesPDP^Ph)]Cl were found to exhibit short-lived photoluminescence in both tetrahydrofuran and benzene solution. These findings confirm the hypothesis that heavy-atom involvement is crucial for the favorable photophysical properties observed for the Zr(PDP)_{2 …}

Structure-Dependent Characterizations Of Multistationarity In Mass-Action Reaction Networks, Galyna Voitiuk

Graduate Theses, Dissertations, and Problem Reports

This project explores a topic in Chemical Reaction Network Theory. We analyze networks with one dimensional stoichiometric subspace using mass-action kinetics. For these types of networks, we study how the capacity for multiple positive equilibria and multiple positive nondegenerate equilibria can be determined using Euclidian embedded graphs. Our work adds to the catalog of the class of reaction networks with one-dimensional stoichiometric subspace answering in the affirmative a conjecture posed by Joshi and Shiu: Conjecture 0.1 (Question 6.1 [26]). A reaction network with one-dimensional stoichiometric subspace and more than one source complex has the capacity for multistationarity if and only …

Characterizing The Effects Of Solvent And Analyte Properties On Ionization Efficiency By Novel Field-Free And Field-Enabled Ionization Techniques, Kinkini Udara Jayasundara

Graduate Theses, Dissertations, and Problem Reports

In recent years the mass spectrometry (MS) area of field and/or direct analysis has grown dramatically. As a result, field-portable and miniaturized mass spectrometers, introduced only a few years ago, are proliferating. A highly desired feature for field-portable MS, or in-field analysis, is the ability to use ionization techniques requiring very little sample preparation as well as an ability to generate the ions under ambient conditions. Recently, a new ambient ionization technique termed vibrating sharp-edge spray ionization (VSSI) has been introduced which overcomes the field-portable limitations of other spray-based methods including the requirements for auxiliary components (e.g., nebulizing gas and …

Novel Modes Of Synchronization And Extreme Events In Coupled Chemical Oscillators, David Allen Mersing

Graduate Theses, Dissertations, and Problem Reports

We experimentally and computationally investigate dynamical behaviors in coupled chemical oscillators. These networks of chemical oscillators are created using catalytic Ru(bpy)₃²⁺ loaded cation exchange beads submerged in catalyst-free Belousov-Zhabotinsky (BZ) solutions. Various network structures are created by utilizing the photosensitive nature of the Ru(bpy) ₃²⁺ catalyst. The response of the oscillators due to light stimuli can be characterized by constructing a phase response curve (PRC). The PRC quantifies the excitatory and inhibitory responses of BZ oscillators due to applied light perturbations as a function of the oscillators' phase. Different initial concentrations of reactants in the BZ reaction …

Ion Velocity Distribution Functions In Cutting-Edge Plasmas, Mitchell Cameron Paul

Graduate Theses, Dissertations, and Problem Reports

Cutting-edge plasma experiments continue to push the frontiers of plasma science. Two such groups of experiments, helicon sources and laboratory magnetic reconnection, are the focus of this thesis. The relatively high plasma density achieved for modest input powers makes helicon source plasmas ideal testbeds for fusion-relevant phenomena without the complexities associated with fusion devices. Examples include plasma-material interaction (PMI) studies, divertor region studies, and boundary physics studies. As advancements in helicon source design and technology make operation at higher power for longer times possible, understanding of the plasma dynamics, particularly ion dynamics, is vital.

Laboratory experiments are essential to advancing …

Pathfinding Fast Radio Bursts Localizations Using Very Long Baseline Interferometry, Pranav Rohit Sanghavi

Graduate Theses, Dissertations, and Problem Reports

Fast radio bursts (FRBs) are millisecond-duration, bright radio transients of extragalactic origin. The Canadian Hydrogen Intensity Mapping Experiment (CHIME) telescope’s CHIME/FRB instrument and other radio telescopes across the globe have detected hundreds of FRBs. Their origins are a mystery. Precise localization within the host is critical to distinguish between progenitor models. This can be achieved through Very Long Baseline Interferometry (VLBI). Until now, VLBI localizations have only been carried out in targeted follow-up observations of some repeating sources which comprise a small fraction of the FRBs.

For this work, an interferometric array of 6m dishes was constructed at the Green …

Evaluating The Validity And Reliability Of Textile And Paper Fracture Characteristics In Forensic Comparative Analysis, Zachary Bailey Andrews

Graduate Theses, Dissertations, and Problem Reports

In a comparative forensic analysis, an examiner can report that a physical fit exists between two torn or separated items when they realign in a manner unlikely to be replicated. Due to the common belief that it is unlikely that two unrelated fractured objects would match with distinctive characteristics, a physical fit represents the highest degree of association between two items. Nonetheless, despite the probative value that this evidence could have to a trier of fact, few studies have demonstrated such assumptions' scientific validity and reliability. Moreover, there is a lack of consensus-based standard protocols for physical fit comparisons, making …

Using Landsat-Based Phenology Metrics, Terrain Variables, And Machine Learning For Mapping And Probabilistic Prediction Of Forest Community Types In West Virginia, Faith M. Hartley

Graduate Theses, Dissertations, and Problem Reports

This study investigates the mapping of forest community types for the entire state of West Virginia, USA using Global Land Analysis and Discovery (GLAD) Phenology Metrics analysis ready data (ARD) derived from the Landsat time series and digital terrain variables derived from a digital terrain model (DTM). Both classifications and probabilistic predictions were made using random forest (RF) machine learning (ML) and training data derived from ground plots provided by the West Virginia Natural Heritage Program (WVNHP). The primary goal of this study is to explore the use of globally consistent ARD data for operational forest type mapping over a …

Synthetic Methods For Improved Scope And Efficiency Of Copper-Catalyzed Regioselective Alkene Boracarboxylation, Steven William Knowlden

Graduate Theses, Dissertations, and Problem Reports

The synthesis of carboxylic acids is important to the chemistry community, owing to the broad applicability of these compounds as fine chemicals and pharmaceuticals. Method development over the last decade has focused on the preparation of carboxylic acids through transition metal catalysis utilizing CO₂ as a C1 synthon. Copper-catalyzed heteroelement(bora and sila)-carboxylation protocols provide functional group rich carboxylic acid products, yet remain underdeveloped and thus underutilized. Consequently, catalytic reductive difunctionalization methodologies in which CO₂ and B(pin) (pin = pinacolate: 2,3-dimethyl-2,3-butanediolate) are installed across the double bond of a vinyl arene were recently developed. These boracarboxylation protocols provided novel, …

Fashion Compatibility Prediction Using Ensemble Learning, Nathan Utzman

Graduate Theses, Dissertations, and Problem Reports

Fashion is important both financially and for self-expression. There are many tasks in the fashion domain which can be addressed with artificial intelligence. The task of fashion compatibility prediction is to determine how well a set of items work together to form an outfit. Two main tasks are typically used to evaluate the performance of a fashion compatibility prediction model – Outfit Compatibility Prediction and Fill in the Blank.

In this work, a compatibility prediction model, which is based on the graph autoencoder, is evaluated. This same model is then used in a homogeneous ensemble learning approach, proposed to improve …

Red Spruce Ecological Sites, Ecological States, And Restoration Pathways Quantified Through Soil Organic Carbon, James Edward Leonard

Graduate Theses, Dissertations, and Problem Reports

Tools used by agencies and organizations like the Forest Service (FS), the Natural Resource Conservation Service (NRCS), the Nature Conservancy (TNC), and the Central Appalachian Spruce Restoration Initiative (CASRI) to help guide red spruce (Picea rubens) ecosystem restoration within Central Appalachia could better address outcomes from management practices implemented in terms of soil organic carbon (SOC) stock changes. These high-elevation landscapes have a natural capacity to produce diverse ecosystem services that affect humans, animals, and plants alike. Ecological site descriptions (ESD) are an important tool used to restore impacted landscapes and provide detailed management prescriptions specific to red spruce ecological …

Calcite Depression In Bastnaesite-Calcite Flotation System Using Organic Acids, Emmy Muhoza

Graduate Theses, Dissertations, and Problem Reports

Bastnaesite is the primary source of light REEs, namely cerium (Ce), lanthanum (La), praseodymium (Pr), neodymium (Nd), to name a few. Bastnaesite is typically concentrated using the froth flotation beneficiation method. Flotation of bastnaesite suffers from high reagent consumption due to the similar surface characteristics of bastnaesite and associated gangue minerals, including calcite. Additionally, complex stages of high-temperature conditioning are often required to suppress the detrimental impact of dissolved calcium ions on the flotation of bastnaesite. This research seeks to investigate the capabilities of organic acids in the bastnaesite-calcite flotation systems to selectively depress calcite minerals and effectively chelate calcium …

Essays On Clean Water Act And Safe Drinking Water Act, Sharaban Tahura Anica

Graduate Theses, Dissertations, and Problem Reports

This dissertation empirically examines three issues related to CWA and SDWA: 1) Financial Assistance and Environmental Compliance; 2) Financial Assistance Priorities from the Clean Water State Revolving Fund; and 3) Drinking Water Compliance during COVID-19 Pandemic.

Using the National Pollution Discharge Elimination System compliance and the Clean Water State Revolving Funds (CWSRF) data for wastewater treatment plants in nine states between 2010 and 2018, chapter 2 examines a) the effect of non-compliance on the distribution and size of awarded CWSRF loans, and b) the effects of the CWSRF provision and award size on post-funding compliance. Funded facilities are found to …

Understanding Surface Water--Groundwater Connectivity And Discharge In Arctic Deltas, Lindsey N. Aman

Graduate Theses, Dissertations, and Problem Reports

Increased warming is driving unprecedented hydrologic changes within arctic deltas with implications for water storage, solute processing, and terrestrial and marine ecology. Thermokarst lakes within Arctic deltas store flood waters and filter solutes and sediments, thus moderating the impact of flood water discharge to arctic seas. However, this moderating influence is diminishing as lakes shrink on annual and seasonal time scales, especially close to active channels where lakes are shrinking most rapidly. This study investigates surface water-groundwater connectivity in arctic delta plains with coupled flow and heat transport models to provide a mechanistic understanding of how lake-channel proximity will impact …

Wetland Mitigation Performance Standards: The Intersection Of Science, Practice, And Policy, Jessica Anne Bryzek

Graduate Theses, Dissertations, and Problem Reports

Wetland ecosystem spatial extent and integrity have declined due to conversion to anthropogenic land uses. Wetland mitigation offsets the impact on wetlands encountered during development by restoring a previously degraded wetland or creating new wetlands. This activity creates an ecosystem service market where wetland impacts (debits) are offset by wetland restoration/creation (credits). Mitigation aims to replace functions provided by aquatic resources lost during development. Post-restoration monitoring criteria known as performance standards are used to evaluate and verify restored wetland functionality and regulate mitigation credit release. Therefore, performance standards are vital in ascertaining wetland restoration techniques and mitigation processes. In Chapter …

Hydrocarbon Pay Zone Prediction Using Ai Neural Network Modeling., Darren D. Guedon

Graduate Theses, Dissertations, and Problem Reports

This paper captures the ability of AI neural network technology to analyze petrophysical datasets for pattern recognition and accurate prediction of the pay zone of a vertical well from the Santa Fe field in Kansas.

During this project, data from 10 completed wells in the Santa Fe field were gathered, resulting in a dataset with 25,580 records, ten predictors (logs data), and a single binary output (Yes or No) to identify the availability of Hydrocarbon over a half feet depth segment in the well. Several models composed of different predictors combinations were also tested to determine how impactful some logs …

Electrochemical And Mass Spectrometry Methods For Identification Of Gunshot Residues (Gsr) In Forensic Investigations, Kourtney A. Dalzell

Graduate Theses, Dissertations, and Problem Reports

Gun violence continues to be one of most significant challenges straining the USA society causing thousands of human lives lost every year. In 2020 alone, firearm-related incidents including homicide, accidents, and suicides, reached a staggering number of over 43,000.^1,2 With the increase in these types of incidents, several service areas in crime laboratories are heavily impacted by the number of cases run on a yearly basis. These include firearm examinations, gunshot residue (GSR) analysis, bullet hole identification, and shooting distance determination, which are crucial to support a criminal investigation and, overall, the justice system in our country. These areas …

Multifunctional Organoboron Compounds And Boralactonate Salts, Randika T. Abeysinghe

Graduate Theses, Dissertations, and Problem Reports

Organoboron compounds have gathered an important significance within the chemistry community on account of their wide range of applications in synthesis, catalysis, and medicinal chemistry. Even though the uses of boron compounds in drug discovery have been overlooked until the last several decades, boronic acid containing molecules have garnered increased attention due to the unique chemical properties of the boron center. Boron-functionalized ��-aryl propionic acid non-steroidal anti-inflammatory drug derivatives (bora-NSAIDs) can be accessed via copper(I)-catalyzed alkene boracarboxylation, using CO2 and B2pin2. To explore and expand the current synthetic and future medicinal chemistry applications of these bora-NSAIDs, methods …

Classifying Blood Glucose Levels Through Noninvasive Features, Rishi Reddy

Graduate Theses, Dissertations, and Problem Reports

Blood glucose monitoring is a key process in the prevention and management of certain chronic diseases, such as diabetes. Currently, glucose monitoring for those interested in their blood glucose levels are confronted with options that are primarily invasive and relatively costly. A growing topic of note is the development of non-invasive monitoring methods for blood glucose. This development holds a significant promise for improvement to the quality of life of a significant portion of the population and is overall met with great enthusiasm from the scientific community as well as commercial interest. This work aims to develop a potential pipeline …