Digital Commons Network^™

Mercury Emissions From Iron Mining And Copper Mining In The Upper Peninsula, Michigan, Ahmed Al Rahbi

Honors Theses

The wealth in the Upper Peninsula of Michigan has been intimately linked with mining, particularly the extraction of iron and copper. Iron was deposited in the Upper Peninsula 1.9 billion years ago (Gogebic and Ranges, 2020), and copper deposits are believed to be 1.1 billion years old (Blakemore et al., 2016). In the Upper Peninsula, mercury occurs naturally in taconite (iron ore) as elemental mercury (Hg⁰), and within the copper ores as “Mercury copper amalgam” (CuHg). When elemental mercury is released from the ores, it oxidizes in the atmosphere to form inorganic mercury (Hg²⁺) (Risher, 2003; …

Surface Reconstruction Library, Jhye Tim Chi

Honors Theses

The project aims to convert an arbitrary point cloud into a triangular mesh. Point clouds are a list of 3d points that model the topology of an object. Point clouds can have various issues, such as missing or noisy data. For the scope, we had no control over point cloud generation. We were also unable to deal with underlying registration or alignment problems. Triangular meshes are a list of triangles that have 3d vertices. This aggregate list of triangles defines the reconstructed surface. Our project implementation is based on Alexander Hornung and Leif Kobbelt’s method for surface reconstruction using the …

Class Scheduling Web App, Anubhav Rawal

Honors Theses

This Scheduling Web Application in Django was built to allow a user to create a schedule for upcoming semesters. Users with appropriate privileges could upload an excel schedule to which instructors could be assigned. Additionally features included dynamic editing for admin users and viewing the main schedule for general users. Our goal was to create an application from the ground up using the Django framework to accomplish these tasks.

Quantifying Surface Water Capture By Municipal Pumping Wells In An Urban Watershed Impacted By Road Salt, Austen York

Masters Theses

The Spring Valley sub-watershed is located within the Kalamazoo Township contains Spring Valley Lake, a man-made impoundment that ultimately discharges into the Kalamazoo River. Elevated chloride levels in pumped water from the Kalamazoo Station 14 municipal wellfield, located along the shoreline of Spring Valley Lake, has resulted in less than ideal corrosivity values for the water distribution system. Specific project objectives include: (1) identifying the cause of elevated chloride, (2) assessing surface water capture by the Station 14 wellfield, and (3) characterizing of water quality in Spring Valley Lake. Monitoring along a series of sampling transects spanning the sub-watershed, focused …

Using Sedimentary Mercury Geochemistry To Evaluate The Niagara-Salina Transition, Silurian Michigan Basin, Usa, Sara Hayes

Masters Theses

The Niagara-Salina boundary in the Michigan Basin is marked by an abrupt transition from carbonates to evaporites. Though the cause is uncertain, previous work suggests the onset of Salina evaporites was driven by basin restriction, but the presence of several global carbon isotope excursions (CIE) suggest a global driver. This study builds on this discussion using two relatively new geochemical proxies - elemental mercury concentrations [Hg] and Hg isotopes.

Mercury concentrations [Hg] were measured in 88 samples from the State Kalkaska #2-15 core from 6604.03 ft to 6797.42 ft. [Hg] ranges from 0.11 to 0.62 mg/kg and [Hg]/TOC from 0.038 …

Mechanisms And Applications Of Improved Protein Analysis By Desorption Electrospray Ionization Mass Spectrometry (Desi-Ms), Roshan Javanshad

Dissertations

Electrospray ionization mass spectrometry (ESI-MS) is a soft ionization technique that allows detection of macromolecules, such as intact proteins, by the formation of multiply charged ions from solutions. Desorption electrospray ionization mass spectrometry (DESI-MS) is an ambient ionization technique that directly samples analyte from a surface during ESI-MS analysis. Although DESI-MS is highly accomplished at the analyses of metabolites, lipids, and other small molecules, it is far more limited when it comes to protein analysis. While most of the field in ambient ionization MS has moved towards primarily applications, our approach has been to explore the use of DESI-MS and …

Lxr Acts As A Differentiator In The Regulation Of Fas And G6pdh Gene Expression Under Insulin Resistant Conditions, Jaafar Hachem

Dissertations

Diabetes is a chronic disease that effects 10 percent of the world’s population and causes more than 1.5 million deaths a year and billions of dollars in associated health care cost. It can lead to very serious complications such as renal failure, liver cirrhosis, heart attack, and vision loss. The most common type of diabetes is type 2 diabetes. Type 2 diabetes arises when blood glucose levels remain chronically high due to insulin resistance. The reason for this elevation is due to the failure of insulin to allow tissues to uptake glucose causing problems in subsequent metabolic pathways. Over the …

Development Of Sensor, Sensory System And Signal Processing Algorithm For Intelligent Sensing Applications, Xingzhe Zhang

Dissertations

Sensors have been receiving significant attention in the last decade and the demand for sensory systems has increased in recent years due to the rapid growth in the field of artificial intelligence (AI). Sensors can improve people’s awareness by providing them with real-time information on the environment and their immediate health conditions. This dissertation presents the fulfilment of three main projects and focuses on the development of a sensor, a sensory system, and a sensor signal recognition system for AI applications by employing printed electronics, analog circuit design, and digital signal processing techniques.

In the first project, a multi-channel stethograph …

Estimation Of Odds Ratio In 2 X 2 Contingency Tables With Small Cell Counts, Guohao Zhu

Dissertations

This study is focusing on properties of estimators of odds ratio or its logarithm in case of 2x2 tables with small counts. The odds ratio represents the odds that an outcome of interest will occur given a particular exposure, compared to the odds of the outcome occurring in the absence of that exposure. Both parameters are often used to quantify the strength of association of two binary variables and are common measurements reported in case-control, cohort, and cross-sectional studies.

Because of their wide applicability, both parameters, odds ratio, and its logarithm, have been intensively studied in the literature. However, most …

Impact Of Calcium Carbonate Reactant Size And Mineralogy On Dolomite Stoichiometry, Katharine G. Rose

Masters Theses

Dolomite is a common, diagenetic, Mg-Ca carbonate mineral. Dolomitization occurs by a dissolution-precipitation reaction between a CaCO₃ precursor (calcite or aragonite) and Mg bearing fluids. The amount of Mg in dolomite, referred to as dolomite stoichiometry (mol% MgCO₃), varies in natural dolomites (38-50 mol% MgCO₃). Laboratory experiments have shown that dolomite stoichiometry is dependent on physiochemical factors of the diagenetic fluids (i.e., temperature, salinity, and Mg/Ca). The impact of the CaCO₃ precursor on stoichiometry, however, has not been studied directly. This study tests how the CaCO₃ precursor size (sieve size) and mineralogy (calcite …

On Cup-Products Of Cofibers Of Maps Between Moore Spaces, Hopf Invariant, And Lusternik-Schnirelmann Category, Marwa A.S. Mosallam

Masters Theses

In this thesis we make a detailed investigation of the cohomology rings of the cofibers C_β of Moore spaces of dimension 2 by computing the cup products in cofibers and to do so we prove that the Hopf invariant in case of Moore spaces in the zero and nonzero homomorphism case is a homomorphism. We have shown when is 𝓍_r,_k a Co-H-Map. We calculated the homologies and cohomologies of Moore spaces of dimension 2 and of the cofibers C_β where β=𝓍_r,k. We used Lusternik-Schnirelmann category to determine the complexity of C …

Per- And Polyfluorinated Alkyl Substances (Pfas) Cycling Within Michigan: Connections Between Contaminated Sites, Landfills, And Wastewater Treatment Plants, Ross W. Helmer

Masters Theses

The disposal and treatment of Per- and Polyfluorinated Alkyl Substances (PFAS) contaminated solid and liquid wastes, and associated cycling within the natural and engineered environment is a complex topic. PFAS data on contaminated sites, landfill leachates, the influent, effluent, and biosolids from wastewater treatment plants (WWTPs) within Michigan were compiled from publicly available and private sources. Most of the datasets are based on a 28-analyte suite generated using a modified form of the US EPA 537 analytical method, with a subset of data from the 18-analyte ASTM D7979-19 method. Approximately 70% of the 171 contaminated sites in Michigan have maximum …

Understanding Potential Climate Change Impacts On Water Resources Within A Fractured Rock Watershed In Northern Togo, Mahawa-Essa Mabossani Akara

Dissertations

More than 72% of sub-Saharan Africa land surface is comprised of hard rock with fractured rock aquifers supplying water to an estimated 25% of the rural population. Given low porosity and storativity, fractured rock aquifers are particularly vulnerable to stresses such as projected population growth and climate variability. General circulation models of sub-Saharan Africa predict increases in temperature and in occurrences of extreme precipitation trends, such as flooding and drought. Adaptation strategies that promote optimal uses of water resources have emerged, although, most focus exclusively on surface water resources. This project investigates the potential impact of climate change on surface …

Synthesis And Characterization Of Novel Organic Ligands With Their Complexes Of Platinum, Copper And Uranium, Mustafa Adnan Yasin Aldulaimi

Dissertations

Transition metal complexes of symmetrical and asymmetrical Schiff bases have played a significant role in the field of coordination, inorganic, and bioinorganic chemistry as models for biological, analytical, industrial, and pharmaceutical applications. Over recent years a great deal of interest has developed in new transition metal complexes of Schiff base ligand. The preparation of novel organic ligands is the most important step in the development of metal complexes that exhibit unique properties and novel reactivity. To highlight the presentation of this dissertation and to provide more detailed investigations, the dissertation was separated into six chapters according to the sequence of …

"Not In My Town": A Community's Response To Water And Soil Pollution, Karolina Staros

Dissertations

At the core of this dissertation is the acknowledgment that social movements are complex networks of people who face many obstacles in their efforts to achieve social change. One critique of social movements is that their goals and mission are limited to short term ideas and not long-term, systemic transformation. The lack of long term, systemic change can be observed when social movement groups mobilize for the same cause over and over again with what appears to be little progress over a period of time. The exact blueprint for a social movement’s success does not exist, but it is posited …

Novel Low Temperature Properties Of Filled And Unfilled Single Crystal Irsb3, Matthew Cook

Dissertations

The skutterudite family of materials has garnered a lot of attention in the condensed matter community and it persists to be an important system for exploring the fundamental physics of solids. The initial interest into compounds with this common structure was due to their promising thermoelectric properties giving the possibility of efficient energy harvesting. Since, there has been a huge effort to systematically synthesize new filled skutterudite compounds, as nearly every type of strongly correlated behavior has been found within this family. As the field of topological materials has gained momentum, these materials have also been given a renewed interest …

Characterizing Undergraduate Students’ Proving Processes Around “Stuck Points”, Yaomingxin Lu

Dissertations

Learning to prove mathematical propositions is a cornerstone of mathematics as a discipline (de Villiers, 1990). However, since proving is a different mathematical activity as compared to students’ prior experience, research has also shown that many undergraduate students struggle to learn to prove, including those who major in mathematics (Moore, 1994; Selden, 2012). While the field has generated research that has analyzed the final products of proof (Selden & Selden, 2009) and there are frameworks for analyzing problem-solving processes (e.g., Carlson & Bloom, 2005; Schoenfeld, 1985, 2010), much remains to be known about analyzing undergraduate students’ proving processes. With a …

Dominating Functions In Graphs, Maria Talanda-Fisher

Dissertations

Domination in graphs has become one of the most popular areas of graph the- ory, no doubt due to its many fascinating problems and applications to modern society, as well as the sheer mathematical beauty of the subject. While this area evidently began with the work by the French mathematician Claude Berge in 1958 and the Norwegian-American mathematician Oystein Ore in 1962, domination did not become an active area of research until 1977 with the appearance of the survey paper by Ernest Cockayne and Stephen Hedetniemi. Since then a large number of variations of domination have surfaced and provided numerous …

Development Of High Throughput Assays For Identification And Evaluation Of Small Molecule Inhibitors Of Microrna-31 Expression, Jackline A. Onyango

Masters Theses

Dysregulated expression of miRNAs has been linked to numerous cancers. On the other hand, miRNAs are potential drug targets due to the ability of their precursor molecules to fold into ligand binding structures. Small-molecule modulators of miRNAs offers opportunity for the development of new therapeutic agents and tools to further probe the mechanisms of miRNA functions. To facilitate the identification of miRNA modulators, the appropriate screening systems are needed, which would be adaptable for high-throughput applications, and allow for quantitative measurements. In this text, we present a molecular beacon-based assay to identify molecules that inhibit miRNA-31 processing by Dicer and …

Using Low-Flow Sampling Data To Estimate Hydraulic Conductivity In Aquifers, Joy Kiefer

Masters Theses

Hydrogeologists sample wells to test aquifer water quality and use slug tests to estimate aquifer permeability. Robbins et al. (2009) proposed a more efficient way to obtain the goals of the two tests—the use of low-flow sampling and the use of the resulting flow rate and drawdown data to estimate aquifer hydraulic conductivity (K). The Robbins et al. method calculates K by using the slope of the best fit line from the graph of flow rate vs. drawdown for all low-flow pumping data collected at a well. When the method was applied to low-flow data from four Kalamazoo, MI, it …

An Integrated Approach For The Assessment And Monitoring Of Land Deformation In The Riyadh City And Its Surroundings For Identifying The Controlling Factors, Abdulaziz Ibrahim Aljammaz

Dissertations

An integrated approach (remote sensing, field, geodesy, geology, and hydrogeology) was conducted to assess and monitor land deformation at Riyadh city and its surroundings. Two settings were investigated. The first, Jinadriyah area (1.5 km²), an urban area located east of Riyadh city, was selected to assess deformation associated with urbanization over desert lands. The second location was Al Kharj area (19,790 km²) to the south of Riyadh city, a reclaimed desert land that was selected to assess the deformation associated with agricultural groundwater extraction from fossil aquifers. My investigations revealed high subsidence rates (up to -30 …

Advancing The Use Of Quality Control Tools For High-Density Data In Modern Manufacturing, Romina Dastoorian

Dissertations

In modern manufacturing, advanced metrology systems are continually being incorporated into quality control (QC) systems to provide high-density (HD) datasets. These datasets can contain millions of measurements that can be used to represent a part’s whole geometry. While integrating HD datasets into QC systems has brought several opportunities to enhance the performance of QC systems, it has resulted in new challenges in this area as well. While significant amounts of research have been performed in this area, the QC research community still strives to tackle these challenges. This study identifies key challenges regarding incorporating HD datasets into QC systems. Specifically, …

From Multi-Prime To Subset Labelings Of Graphs, Bethel I. Mcgrew

Dissertations

A graph labeling is an assignment of labels (elements of some set) to the vertices or edges (or both) of a graph G. If only the vertices of G are labeled, then the resulting graph is a vertex-labeled graph. If only the edges are labeled, the resulting graph is an edge-labeled graph. The concept was first introduced in the 19th century when Arthur Cayley established Cayley’s Tree Formula, which proved that there are n^n-2 distinct labeled trees of order n. Since then, it has grown into a popular research area.

In this study, we first review several types …

Institutional Changes In Western Michigan University For Incorporation Of Education For Sustainability, Saman Khan

Dissertations

Higher Education institutions (HEIs) have the potential to be significant contributors in the pursuit of a sustainable world through the incorporation of Education for Sustainability (EFS). However, HEIs are entrenched with structures and values that are often resistant to change. The literature reveals that instructors’ beliefs and institutional contexts are the two main factors that impact the implementation of institutional change for sustainability education. Western Michigan University (WMU) has created new required curriculum “WMU Essential Studies” (WES) for undergraduate students and they have targeted sustainability as an essential learning outcome, by integrating and applying it in content courses. Using a …

Dolomite Stoichiometry As A Proxy For Fluid Chemistry, Cameron J. Manche

Dissertations

The origin of massive dolomites is a contentious issue in geology. Because modern dolomite is rare, interpretation of ancient dolomites requires the use of proxy resources, most of which provide ambiguous information. High-temperature dolomite synthesis experiments have shown that dolomite stoichiometry, the degree of cation ordering, and reaction rate are controlled by Mg:Ca, temperature, molarity, and salinity of the formative solution. Thus, it is posited here that dolomite stoichiometry may be a useful proxy for fluid chemistry, as are stable isotope and trace element composition of ancient dolomites. High-frequency sample intervals (cm-scale) from the Cretaceous Upper Glen Rose Formation (Comanche …

On Problems In Random Structures, Ryan Cushman

Dissertations

This work addresses two problems in optimizing substructures within larger random structures. In the first, we study the triangle-packing number v(G), which is the maximum size of a set of edge-disjoint triangles in a graph. In particular we study this parameter for the random graph G(n,m). We analyze a random process called the online triangle packing process in order to bound v(G). The lower bound on v(G(n,m)) that this produces allows for the verification of a conjecture of Tuza for G( …

On Prediction Of Early Signs Of Alzheimer’S— A Machine Learning Framework, Abdalrahman Alsaedi

Dissertations

Dementia is a collective term used to indicate a loss of memory functions with the presence of at least one additional loss of a major cognitive ability that hinders a person’s previous level of functioning. Studies show that dementia is highly age- associated and that the most common cause of dementia is Alzheimer’s disease. Early recognition of Alzheimer’s disease, before irreversible damage to the brain has already occurred, is paramount to slowing or preventing the disease. Therefore, algorithms for the prediction of early signs of dementia are essential. Machine learning approach has been reported to use several data sources such …

Building Institutional Knowledge Into Student Leaders: A Repository Of Student-Led Climate Change Initiatives At Wmu, Aida Amirul Bahri

Honors Theses

Students and registered student organizations (RSO) at Western Michigan University (WMU) have increasingly shown interest in climate change and environmental issues. However, student leadership roles are often held short-term due to the rapid displacement cycle of student bodies caused by graduation, institution transfers and other factors. New leaders often struggle with picking up where former students left off and advancing previously established efforts. WMU student groups lack an effective system of maintaining institutional knowledge, including student-led campaigns and accomplishments, to support a smoother transition that would empower student leaders and build upon prior progress. The goal of this project is …

Temperature Scale Influence On Perceptions Of Climate Risk, Chelsea Spaman

Honors Theses

This study explored how the use of the temperature scales Fahrenheit and Celsius in climate science communication affects climate change concern. The study specifically targeted Americans due to their familiarity with the Fahrenheit scale, which is not the primary temperature scale used in scientific communication. The study employed a survey, in which the anonymous participants read a short introduction about climate change and temperature rise and then answered a series of questions regarding levels of climate change concern. These questions covered concerns about climate change in general and its potential to harm individual survey participants, flora and fauna, future generations, …

Edmms Temperature Controller, Anthony Kirkland

Honors Theses

Temperature control systems in consumer appliances like that of a thermostat interfacing with HVAC systems, refrigerators and ovens are oscillatory in nature. There is a temperature at which the machine that causes the change in the system comes on and a different temperature at which it comes off. While sufficient for humans, welding, metal casting, and other metallurgical processes require precise temperature control, more precise than the hysteresis of a consumer system.

Proportional integral derivative (PID) provides a better way of monitoring the way temperature changes when the entity that changes the environment comes on and renders changes in system …