Digital Commons Network^™

The Effects Of Environmental Restoration On Housing Prices In Northern Colorado, Jack Steketee

Capstones and Honors Theses

Hedonic valuation is a method of using a market, such as the housing market, to estimate the value of non-market goods. An example of a non-market good we might want to value is environmental quality. Proper valuation of the environment can help make informed policy decisions, as well as help better protect or restore it. We use the hedonic valuation model This research uses data from a housing market in Colorado to estimate the value homeowners place on an environmental restoration project. We hypothesized that overall, we would see an increase in home value after a restoration project was completed …

Integrated Techno-Economic And Life Cycle Analyses Of Biomass Utilization For Value-Added Bioproducts In The Northeastern United States, Yuxi Wang

Graduate Theses, Dissertations, and Problem Reports

A multi-stage spatial analysis was first conducted to select locations for lignocellulosic biomass-based bioproduct facility, using Geographical Information System (GIS) spatial analysis, multi-criteria analysis ranking algorithm, and social-economic assessment. A case study was developed to determine locations for lignocellulosic biorefineries using feedstocks including forest residue biomass and three energy crops for 13 states in the northeastern United States. In the entire study area, 11.1% of the counties are high-suitable, 48.8% are medium-suitable for biorefinery siting locations. A non-parametric analysis of cross-group surveys showed that preferences on biorefinery siting are homogeneous for experts in academia and industry groups, but people in …

Searches For Fast Radio Bursts Using Machine Learning, Devansh Agarwal

Graduate Theses, Dissertations, and Problem Reports

Fast Radio bursts (FRBs) are enigmatic astrophysical events with millisecond durations and flux densities in the range 0.1-100 Jy, with the prototype source discovered by Lorimer et al. (2007). Like pulsars, FRBs show the characteristic inverse square sweep in observing frequency due to propagation through an ionized medium. This effect is quantified by the dispersion measure (DM). Unlike pulsars, FRBs have anomalously high DMs, which are consistent with an extragalactic origin. Over 100 FRBs have been published at the time of writing, and 13 have been conclusively identified with host galaxies with spectroscopically determined redshifts in the range 0.003 ≤ …

Synthesis Of Graphene Using Plasma Etching And Atmospheric Pressure Annealing: Process And Sensor Development, Andrew Robert Graves

Graduate Theses, Dissertations, and Problem Reports

Having been theorized in 1947, it was not until 2004 that graphene was first isolated. In the years since its isolation, graphene has been the subject of intense, world-wide study due to its incredibly diverse array of useful properties. Even though many billions of dollars have been spent on its development, graphene has yet to break out of the laboratory and penetrate mainstream industrial applications markets. This is because graphene faces a ‘grand challenge.’ Simply put, there is currently no method of manufacturing high-quality graphene on the industrial scale. This grand challenge looms particularly large for electronic applications where the …

Ultrafast Optical Properties Of La0.7sr0.3mno3 Thin Films, Saeed Yousefi Sarraf

Graduate Theses, Dissertations, and Problem Reports

Thin film solids often exhibit different physical properties in the ultra-thin regime. Enhancement of surface to bulk ratio results in the domination of surface/interface related phenomena such as surface recombination. Moreover, in the ultra-thin regime, quantum size and quantum confinement effects can alter the band gap of the system and constrain the strain wave propagation in the thin film. Ultrafast properties of solids can also be drastically altered in the ultra-thin regime due to the aforementioned phenomena. Experimentally, observation of these phenomena is challenging due to the insufficient material to absorb and interact with the electromagnetic wave. This dissertation addresses …

Process Based Analysis Of Fluvial Stratigraphic Record: Middle Pennsylvanian Allegheny Formation, North-Central Wv, Oluwasegun O. Abatan

Graduate Theses, Dissertations, and Problem Reports

Fluvial deposits represent some of the best hydrocarbon reservoirs, but the quality of fluvial reservoirs varies depending on the reservoir architecture, which is controlled by allogenic and autogenic processes. Allogenic controls, including paleoclimate, tectonics, and glacio-eustasy, have long been debated as dominant controls in the deposition of fluvial strata. However, recent research has questioned the validity of this cyclicity and may indicate major influence from autogenic controls. To further investigate allogenic controls on stratal order, I analyzed the facies architecture, geomorphology, paleohydrology, and the stratigraphic framework of the Middle Pennsylvanian Allegheny Formation (MPAF), a fluvial depositional system in the Appalachian …

Cycle Double Covers And Integer Flows, Zhang Zhang

Graduate Theses, Dissertations, and Problem Reports

My research focuses on two famous problems in graph theory, namely the cycle double cover conjecture and the integer flows conjectures. This kind of problem is undoubtedly one of the major catalysts in the tremendous development of graph theory. It was observed by Tutte that the Four color problem can be formulated in terms of integer flows, as well as cycle covers. Since then, the topics of integer flows and cycle covers have always been in the main line of graph theory research. This dissertation provides several partial results on these two classes of problems.

Family Forest Owners Satisfaction With Timber Transactions, Jeffrey M. Lee

Graduate Theses, Dissertations, and Problem Reports

Forest industries in the eastern U.S. rely heavily on family forest owners to supply fiber needs for their mills. As of 2017, 79 percent of West Virginia is classified as forestland and of this roughly 86.5 percent is privately owned. With such a heavy reliance on wood from private forest lands, family forest owner satisfaction is extremely important if companies want to continue harvesting or working with these landowners in the future.

Timber transactions are complex. No two timber transactions are exactly the same. They often involve many different parties apart from the landowner. Site conditions, land cover, and landowner …

Modeling The Galactic Compact Binary Neutron Star Population And Studying The Double Pulsar System, Nihan Pol

Graduate Theses, Dissertations, and Problem Reports

Binary neutron star (BNS) systems consisting of at least one neutron star provide an avenue for testing a broad range of physical phenomena ranging from tests of General Relativity to probing magnetospheric physics to understanding the behavior of matter in the densest environments in the Universe. Ultra-compact BNS systems with orbital periods less than few tens of minutes emit gravitational waves with frequencies ~mHz and are detectable by the planned space-based Laser Interferometer Space Antenna (LISA), while merging BNS systems produce a chirping gravitational wave signal that can be detected by the ground-based Laser Interferometer Gravitational-Wave Observatory (LIGO). Thus, BNS …

A Machine Learning And Data-Driven Prediction And Inversion Of Reservoir Brittleness From Geophysical Logs And Seismic Signals: A Case Study In Southwest Pennsylvania, Central Appalachian Basin, Tobi Micheal Ore

Graduate Theses, Dissertations, and Problem Reports

In unconventional reservoir sweet-spot identification, brittleness is an important parameter that is used as an easiness measure of production from low permeability reservoirs. In shaly reservoirs, production is realized from hydraulic fracturing, which depends on how brittle the rock is–as it opens natural fractures and also creates new fractures. A measure of brittleness, brittleness index, is obtained through elastic properties of the rock. In practice, problems arise using this method to predict brittleness because of the limited availability of elastic logs.

To address this issue, machine learning techniques are adopted to predict brittleness at well locations from readily available geophysical …

Theory And Techniques Of Convergence Of Topological Transformation Group Actions, Murtadha Jaber Sarray

Graduate Theses, Dissertations, and Problem Reports

n this dissertation, we present new set functions called strongly limit and strongly prolongation limit sets. We show the new sets, especially strongly prolongation limit sets, characterize proper action under an arbitrary setting. That is, we characterize proper action for wider class of proper ܩ-spaces. Also, we show the new version of the sets could be derived from strongly exceptional sets which have been used as a good technique for the characterization of a proper maps. Moreover, we review properties of well-known limit sets and prolongations and properties for the new version of limit sets under an arbitrary setting on …

Investigating Effects Of Carbonate Minerals On Shale- Hydraulic Fracturing Fluid Interactions In The Marcellus Shale, Brennan Matthew Ferguson

Graduate Theses, Dissertations, and Problem Reports

Natural gas extracted from tight shale formations, such as the Marcellus Shale, represent an important and developing front in energy exploration. By fracturing these formations using pressurized fracturing fluid, previously unobtainable hydrocarbon reserves may be tapped. While pursuing this resource hydraulic fracturing operations leave chemically complex fluids in the shale formation for at least two weeks. This provides a substantial opportunity for the hydraulic fracturing fluid (HFF) to react with the shale formation at reservoir temperature and pressure. In this study, we investigated the effects of the carbonates on shale-HFF reactions with a focus on the Marcellus Shale. We determined …

Three Essays On Health Economics And Policy Evaluation, Shishir Shakya

Graduate Theses, Dissertations, and Problem Reports

This dissertation consists of three essays on the U.S. Health care policy. Each paragraph below refers to the three abstracts for the three chapters in this dissertation, respectively. I provide quantitative evidence on how much Prescription Drug Monitoring Programs (PDMPs) affects the retail opioid prescribing behaviors. Using the American Community Survey (ACS), I retrieve county-level high dimensional panel data set from 2010 to 2017. I employ three separate identification strategies: difference-in-difference, double selection post-LASSO, and spatial difference-in-difference. I compare how the retail opioid prescribing behaviors of counties, that are mandatory for prescribers to check the PDMP before prescribing controlled substances …

Relating Recharge Mechanisms To Chemical Changes In An Updip Appalachian Coal Mine Discharge: A Case Study From Lambert Run, West Virginia, Matthew Lewis Bell

Graduate Theses, Dissertations, and Problem Reports

Impaired drainage from active and abandoned mines degrades the water quality of receiving streams and aquifers. Coal mine drainage (CMD) has been studied for decades in Appalachia, but unknowns and uncertainties are still present, including the influence of mine hydrogeology on the outflow chemistry of above-drainage mines. To evaluate the influence of recharge type on above-drainage mine chemistry, samples were collected every two weeks at a CMD outflow treatment system in Harrison County, West Virginia.

Samples were collected to measure geochemical changes taking place in the mine workings and along the flowpath of the passive treatment system. Samples were divided …

Evolution Of Extreme Continental Saline Environments: A Sedimentological Investigation Of Permo-Triassic Redbeds And Evaporites In Northern Ireland And Kansas, Anna Sofia S. Andeskie

Graduate Theses, Dissertations, and Problem Reports

The Permo-Triassic was a time of extreme environments, unusually warm and arid climates, and biotic crises. This study investigates Pangean environments and climate leading to extreme acid saline lake systems represented by the Permian Nippewalla Group of Kansas and the Triassic Mercia Mudstone Group of Northern Ireland. Sedimentological observations of the underlying rocks, the Permian Hutchinson Salt Member of Kansas and the Permian Belfast Harbour Evaporite Formation of Northern Ireland, help to understand trends in environmental and climatic conditions leading to these extreme environments. This dissertation also refines the geographic extent of extreme acid saline lake and groundwater systems through …

Representation Learning With Adversarial Latent Autoencoders, Stanislav Pidhorskyi M.S.

Graduate Theses, Dissertations, and Problem Reports

A large number of deep learning methods applied to computer vision problems require encoder-decoder maps. These methods include, but are not limited to, self-representation learning, generalization, few-shot learning, and novelty detection. Encoder-decoder maps are also useful for photo manipulation, photo editing, superresolution, etc. Encoder-decoder maps are typically learned using autoencoder networks.
Traditionally, autoencoder reciprocity is achieved in the image-space using pixel-wise
similarity loss, which has a widely known flaw of producing non-realistic reconstructions. This flaw is typical for the Variational Autoencoder (VAE) family and is not only limited to pixel-wise similarity losses, but is common to all methods relying upon …

Capillary Electrophoresis Analysis Of Proteins Using Phospholipid Based Materials, Cassandra L. Crihfield

Graduate Theses, Dissertations, and Problem Reports

Capillary electrophoresis has many advantages that make it a powerful technique for the analysis of proteins, which is challenging due to the natural heterogeneity of proteins. The small sample volume required for each analysis (nano- and pico-liter), fast separation times (<30 >min), and ability to couple the separation to mass spectrometry are all factors that make capillary electrophoresis an ideal technology for protein separations. Capillary zone electrophoresis and capillary gel electrophoresis are the two most commonly employed modes for protein analysis and allow for rapid, high resolution separations that can be automated. This makes capillary electrophoresis ideal for meeting the …

Genetic And Biochemical Characterization Of Ergot Alkaloid Synthesizing Fungi And Their Symbionts, Matthew Duane Maust

Graduate Theses, Dissertations, and Problem Reports

Ergot alkaloids are fungal tryptophan derived toxins which affect mammalian circulation and neurotransmission. These compounds are biosynthesized by a conserved genetic pathway, known as the ergot alkaloid synthesis (EAS) pathway by fungi belonging to the ascomycete families Trichocomaceae and Clavicipitaceae. Several Ipomoea species and related plants in the morning glory family harbor vertically transmitted symbiotic fungi in the genus Periglandula, also members of Clavicipitaceae, that produce ergot alkaloids. Metabolomic analysis of seeds identified a previously uncharacterized glycoside form of the pharmaceutically important ergot alkaloid, ergonovine. Several species belonging to the fungal genus Metarhizium have recently been shown to have the …

Paleoecological Successions From Shallow-Marine Depositional Environments In Upper Silurian Carbonate Rocks Of Blair County, Pennsylvania, Shadya El-Ashkar

Graduate Theses, Dissertations, and Problem Reports

Studies of paleoenvironment and paleoecology are important for investigating relationships between the different environmental and biological variables that influenced biodiversification patterns during the Silurian Period. The mixed carbonate and siliciclastic rocks of the Bloomsburg and Mifflintown Formations in central Pennsylvania represent transitions between carbonate ramp and deltaic settings. The goal of this study was to assess changes in depositional environment and paleoecology of an undescribed Bloomsburg/Mifflintown locality in Bellwood, Pennsylvania. In central Pennsylvania, the interfingered relationship of mixed carbonate and siliciclastic mudstones of the Mifflintown Formation with red fine-grained sandstones and shales of the Bloomsburg Formation presented challenges for deciphering …

Silver-Mediated Decarboxylation Reactions: Expanding Reaction Scope Through Kinetic Analysis, Robert Anthony Crovak

Graduate Theses, Dissertations, and Problem Reports

Transition metal-catalyzed decarboxylative coupling reactions have received considerable attention in recent years as a method to obtain biaryl compounds. However, the oxidative version of this reaction class is still in its infancy, limited to specific substitution patterns on the benzoic acids – ortho-substitution - used in these transformations. This thesis describes our attempts to understand the key decarboxylation step of this important class of reactions. The first chapter of this thesis discusses an introduction into cross-coupling reactions, decarboxylative cross-coupling reactions, and outlines relevant physical organic parameters. The following chapter details the synthesis of a series of (1,10-phenanthroline)silver(benzoate) complexes. This chapter …

Mechanistic Analysis Of Reductive Boracarboxylation Using Low Valent Copper And Co2, Notashia Nicole Baughman

Graduate Theses, Dissertations, and Problem Reports

The synthesis of organoboron compounds is of contemporary importance in the chemistry community given their utility in subsequent functionalization reactions as well as their growing therapeutic potential in the treatment of human disease. This, coupled with the ubiquity of carboxylic acid functional groups in pharmaceuticals and fine chemicals, has led to interest in one-pot difunctionalization reactions using CO₂ and a boron source. An (ICy)copper(I)-catalyzed boracarboxylation reaction was recently developed wherein CO₂ and a pinacolboryl group is added across the double bond of vinyl arenes was recently developed, providing access to α-aryl-β-boryl propionic acid derivatives. A subsequent publication detailed …

Development Of New Synthetic Methods For Carbon Nanohoops, Merfat Aljhdli

Graduate Theses, Dissertations, and Problem Reports

Carbon nanotubes have received much attention from the material chemists after the synthesis and structure analysis by Iijima in 1991. It was envisioned that cycloparaphenylenes (CPPs), which comprise a sequence of benzene units connected at para position to make a cyclic ring structure, are possible templates for growing carbon nanotubes of a single chirality and single diameter for nanotechnology application. Recently, chemists turned their attention to synthesizing aromatic carbon nanobelts proposed as a general term for carbon molecules composed of fused benzene rings in cylindrical structure shape. Cyclophenacenes (CPAs) as carbon nanobelts are expected to be more suitable candidates for …

Mapping Surficial Geology In The New River Gorge National River And Bluestone National Scenic River, West Virginia, Using Lidar-Derived Digital Elevation Data, Marla K. Denicola

Graduate Theses, Dissertations, and Problem Reports

The purpose of this thesis was to determine if the surficial geology of Bluestone National Scenic River (BLUE) and New River Gorge National River (NERI), two areas of similar geology, can be mapped using visual interpretation methods applied to digital elevation models (DEMs) derived from light detection and ranging (LiDAR) data. Surficial geology in BLUE was field mapped using GPS, following definitions and characterizations for surficial geology units established with the guidance of Dr. J. Steven Kite. A 2m x 2m LiDAR-derived DEM was used for BLUE and most of NERI using US Army Corps of Engineers (USCOE) LiDAR data, …

Interpretations Of Bicoherence In Space & Lab Plasma Dynamics, Gregory Allen Riggs

Graduate Theses, Dissertations, and Problem Reports

The application of bicoherence analysis to plasma research, particularly in non-linear, coupled-wave regimes, has thus far been significantly belied by poor resolution in time, and/or outright destruction of frequency information. Though the typical power spectrum cloaks the phase-coherency between frequencies, Fourier transforms of higher-order convolutions provide an n-dimensional spectrum which is adept at elucidating n-wave phase coherence. As such, this investigation focuses on the utility of the normalized bispectrum for detection of wave-wave coupling in general, with emphasis on distinct implications within the scope of non-linear plasma physics. Interpretations of bicoherent features are given for time series from …

Enabling And Threatening Factors Affecting Persistence. A Qualitative And Quantitative Study On Rural First-Generation Stem Students’ And Stem Faculty's Perspectives., Travis A. Miller

Graduate Theses, Dissertations, and Problem Reports

This study focuses on the factors that enable and threaten rural first-generation STEM students’ persistence. Limited empirical studies are available that focus on rural first-generation STEM majors’ persistence. Quantitative analysis was conducted using Kruskal Wallis H and Mann-Whitney U tests to determine any significant differences with the survey results. Content and thematic analysis was conducted on the student and faculty interviews to determine themes of enabling and threatening factors affecting persistence.

Enabling factors affecting persistence were found to be: Drive or Motivation, Experiences and skills, and Support. These were both faculty and student interview themes whereas a …

Relating Sonic Velocities, Minimum Horizontal Stress, And Natural Fracture Distribution To Stimulation Efficiency During Completion Of The Marcellus Shale Mip-3h Unconventional Well, West Virginia, Usa, Kaitlin Gayle Evans

Graduate Theses, Dissertations, and Problem Reports

Log data from the Marcellus Shale Energy and Environment Laboratory (MSEEL) was acquired along the lateral of the MIP-3H well. This unconventional shale-gas well was completed within the Marcellus Shale just above the Cherry Valley Limestone, a thin limestone member separating organic rich units of the Marcellus. The geomechanical moduli, Poisson’s Ratio (PR) and Young’s Modulus (YME), were generated using compressional and shear sonic logs to indicate zones of increasing brittleness for each of the 28 stages along the 6124 ft. (1867m) horizontal lateral. Brittle reservoir rock is more readily fractured during hydraulic stimulation than more malleable rock. Stages with …

Advancing Quantitative Understanding Of Escherichia Coli Concentrations In A Contemporary Mixed Land-Use Watershed, In West Virginia, Usa, Fritz Petersen

Graduate Theses, Dissertations, and Problem Reports

A scarcity of field-based research investigating the relationships between E. coli (fecal matter) concentration, suspended particulate matter (SPM; including size distribution), physicochemical parameters (water temperature, pH, SPC, DO, chloride) and land use practices and the importance of these relationships, particularly for human health, policy makers, and water resource managers, provided the impetus for this research. A 22-site, nested-scale, experimental watershed study design was implemented to investigate E. coli concentrations and the aforementioned relationships in a contemporary mixed land use watershed in the Appalachian region of the eastern United States. Results from a reduced (n=4 sites) study showed SPM in the …

Microbial Responses To Unconventional Oil And Gas Development May Alter Ecosystem Function In Headwater Streams, Rachel Michaels

Graduate Theses, Dissertations, and Problem Reports

The demand for natural gas, and the need for efficient extraction, has led to the development of unconventional oil and natural gas (UOG) techniques. Due to the novelty of UOG, the potential impacts to freshwater ecosystems are not fully understood. We used a dual pronged approach to study the effects of UOG development on microbial biodiversity and function via a laboratory microcosm experiment and a survey study of streams with and without UOG development within their watersheds. The laboratory microcosm study simulated stream contamination with produced water, a byproduct of UOG operation, using sediment collected from one high water-quality stream …

Protein/Peptide Characterization Using Mass Spectrometry And Molecular Dynamics Simulations, Ahmad Kiani Karanji

Graduate Theses, Dissertations, and Problem Reports

Mass spectrometry (MS) based-techniques and molecular dynamics (MD) simulations have been used to characterize protein/peptide structure as well as their interactions with lipid vesicles and detergents. Chapter 1 introduces an introduction to the concepts and tools that were used in this work. In Chapter 2, the dominant gas-phase conformer of [M+3H]3+ ions of the model peptide Acetyl-PSSSSKSSSSKSSSSKSSSSK are examined with ion mobility spectrometry (IMS), gas-phase hydrogen deuterium exchange (HDX), and mass spectrometry (MS) techniques. This section furthers the development of a protein structural prediction tool by providing information about gas-phase ion conformers of two model peptides having different solution conformational …

Time-Dependent Reliability Framework For Durability Design Of Frp Composites, Rajneesh Kumar Bharil

Graduate Theses, Dissertations, and Problem Reports

The life-cycle performance, durability, and aging characteristics of Fiber Reinforced Polymer (FRP or Structural Composites) have been of keen interest to the engineers engaged in the FRP design, construction, and manufacturing. Unlike conventional construction materials such as steel and concrete, the design guidelines to account for the aging of FRP are somewhat scattered or not available in an approved or consistent format. Loss of strength over time or aging of any structural material should be of concern to engineers as the in-service lifespan of many engineering structures is expected to exceed 100 years. Use of durability strength-reduction factors or factors …