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Physical Sciences and Mathematics

University of Texas Rio Grande Valley

Theses and Dissertations

Decomposition

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Hydrodesulfurization Of Dibenzothiophene Using Lanthanum Doped Comos2, Carolina Valdes Bracamontes Dec 2017

Hydrodesulfurization Of Dibenzothiophene Using Lanthanum Doped Comos2, Carolina Valdes Bracamontes

Theses and Dissertations

Hydrodesulfurization (HDS) is a technique used in petrochemical industry for the removal of sulfur from crude oil. Using dibenzothiophene (DBT) as a target molecule and CoMoS2 catalysts doped with various concentrations of lanthanum were studied for catalytic activity in the removal of DBT from solution. Catalysts were synthesized using ammonium tetrathiomolydate, cobalt chloride and lanthanum nitrate under a solvothermal decomposition in decalin at 350 °C with H2 gas at 160 psi. To evaluate decomposition effects, a second set of catalyst precursors were decomposed in a tube furnace at 450 °C under a constant flow of 10%/90% H2/Ar. Characterizations of the …


Decomposition Of Black Mangrove (Avicennia Germinans ) Leaf Litter: Calibrating Estuarine Indicators Of Functional Recovery, Leticia Martinez Contreras May 2017

Decomposition Of Black Mangrove (Avicennia Germinans ) Leaf Litter: Calibrating Estuarine Indicators Of Functional Recovery, Leticia Martinez Contreras

Theses and Dissertations

Decomposition of plant material produced by mangroves and other macrophytes in estuaries occurs in both sediments and the water column. Early and intense processing could be more common in the water. In a previous study, in situ decomposition rates of Black Mangrove (Avicennia germinans ) leaf litter suspended in the water column differed among three estuaries in south Texas with moderate differences in salinity, water temperature, available nitrogen (N), and tidal flow. A series of microcosm experiments were conducted to determine the influence, within observed ranges in the estuaries, of these water variables on mass loss of Black Mangrove …


Decomposition And Nitrogen Dynamics Of Turtle Grass (Thalassia Testudinum) In A Subtropical Estuarine System, Monica Delgado Dec 2015

Decomposition And Nitrogen Dynamics Of Turtle Grass (Thalassia Testudinum) In A Subtropical Estuarine System, Monica Delgado

Theses and Dissertations

Seagrass beds are pivotal in the functioning of coastal ecosystems in terms of productivity, organic matter turnover and nutrient cycling. Aiming to document decay and nitrogen (N) dynamics of turtle grass (Thalassia testudinum) in a subtropical estuarine system, decomposition patterns of leaves and rhizomes were characterized and compared. Nitrogen usage during decomposition of tissues, and of live tissues and epiphytes growing on live leaves, was also quantified and compared. Stable isotope ratios allowed tracing N within the seagrass bed, following N incorporation into seagrass tissues from the surrounding media (water, sediment). Leaves had a higher N content and decomposed at …