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Physical Sciences and Mathematics

Montclair State University

Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works

2005

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Solvent Extraction Separation And Determination Of Yttrium With Cyanex272, Manjusha Karve, Bhagyashree P. Vaidya Jan 2005

Solvent Extraction Separation And Determination Of Yttrium With Cyanex272, Manjusha Karve, Bhagyashree P. Vaidya

Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works

A simple and selective method for the liquid - liquid extraction of yttrium with Cyanex272 is presented. The influence of the pH of aqueous phase, concentration of extractant, nature of diluent, extraction time, type of stripping agent and stripping time were evaluated to optimize the conditions for quantitative extraction of yttrium. The effect of certain foreign ions on the extraction of yttrium was studied. Yttrium was quantitatively extracted at pH = 7.0 with 5 x 10-4 M Cyanex272 in xylene. It was stripped from the organic phase with 4M nitric acid and determined spectrophotometrically with Arsenazo (Ill) at 650nm.