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Evaluating The Interactive Roles Of Soil Nutrients And Polyploidy On Competitive Outcomes Of Chamerion Angustifolium, Angela Walczyk

Dissertations, Master's Theses and Master's Reports

Newly formed polyploids face strong barriers preventing their establishment, but despite these barriers polyploidy is prevalent among angiosperms being a major mechanism of adaptation and speciation. Morphological and phenological differences between diploids and related polyploids often results in different ecological tolerances among cytotypes. Differences in competitive abilities brought on by genome duplication can vary with abiotic and biotic environmental conditions and influence polyploid establishment. In my theses, I test the overall hypothesis that soil nutrient availability and polyploidy interact to affect competition and performance of Fireweed plants (Chamerion angustifolium), which differ in ploidy levels. Additionally, I examined whether …

Pressure Measurements Inside Multiple Cavities Of A Torque Converter And Cfd Correlation, Edward De Jesus Rivera

Dissertations, Master's Theses and Master's Reports

A torque converter was instrumented with 29 pressure transducers. The pressure transducers were located in multiple cavities. The instrumented cavities included, four transducers mounted on the impeller shell, on the channel between blades. Six transducers mounted on the pressure and suction sides on the middle streamline of a turbine blade. Another seven transducers mounted on the pressure and suction sides of the core, middle and shell streamlines of a stator blade. Seven transducers mounted on the torque converter clutch cavity. Finally, five on the cavity between the pressure plate and the turbine shell. The torque converter was part of a …

A Model To Predict Concentrations And Uncertainty For Mercury Species In Lakes, Ashley Hendricks

Dissertations, Master's Theses and Master's Reports

To increase understanding of mercury cycling, a seasonal mass balance model was developed to predict mercury concentrations in lakes and fish. Results indicate that seasonality in mercury cycling is significant and is important for a northern latitude lake. Models, when validated, have the potential to be used as an alternative to measurements; models are relatively inexpensive and are not as time intensive. Previously published mercury models have neglected to perform a thorough validation. Model validation allows for regulators to be able to make more informed, confident decisions when using models in water quality management. It is critical to quantify uncertainty; …

Evaporation Of A Sessile Droplet On A Slope, Mitch Timm

Dissertations, Master's Theses and Master's Reports

We theoretically examine the drying of a stationary liquid droplet on an inclined surface. Both analytical and numerical approaches are considered, while assuming that the evaporation results from a purely diffusive transport of the liquid vapor and that the contact line is a pinned circle. For the purposes of our analytical calculations, we suppose that the effect of gravity relative to the surface tension is weak, i.e. the Bond number (Bo) is small. Then, we express the shape of the drop and the vapor concentration field as perturbation expansions in terms of Bo. When the Bond number is zero, the …

Statistical Methods For Detecting Causal Rare Variants And Analyzing Multiple Phenotypes, Xinlan Yang

Dissertations, Master's Theses and Master's Reports

This dissertation includes two papers with each distributed in one chapter. To date, genome-wide association studies (GWAS) have identified a large number of common variants that are associated with complex diseases successfully. However, the common variants identified by GWAS only account for a small proportion of trait heritability. Many studies showed that rare variants could explain parts of the missing heritability. Since the well-developed common variant detecting methods are underpowered for rare variant association tests unless sample sizes or effect sizes are very large, investigation the roles of rare variants in complex diseases presents substantial challenges. In chapter 1, we …

Application Of Remote Sensing And Machine Learning Modeling To Post-Wildfire Debris Flow Risks, Priscilla Addison

Dissertations, Master's Theses and Master's Reports

Historically, post-fire debris flows (DFs) have been mostly more deadly than the fires that preceded them. Fires can transform a location that had no history of DFs to one that is primed for it. Studies have found that the higher the severity of the fire, the higher the probability of DF occurrence. Due to high fatalities associated with these events, several statistical models have been developed for use as emergency decision support tools. These previous models used linear modeling approaches that produced subpar results. Our study therefore investigated the application of nonlinear machine learning modeling as an alternative. Existing models …

Physicochemical, Spectroscopic Properties, And Diffusion Mechanisms Of Small Hydrocarbon Molecules In Mof-74-Mg/Zn: A Quantum Chemical Investigation, Gemechis Degaga

Dissertations, Master's Theses and Master's Reports

In petroleum refining industries, the fracturing process allows for the cracking of long-chain hydrocarbons into a mixture of small olefin and paraffin molecules that are then separated via the energetically and monetarily demanding cryogenic distillation process. In an attempt to mitigate both energetic and capital consumptions, selective sorption of light hydrocarbons by tunable sorbents, such as metal-organic frameworks (MOFs), appears to be the most promising alternative for a more efficient gas separation process. MOFs are novel porous materials assembled from inorganic bricks connected by organic linkers. From a crystal engineering stand point, MOFs are advantageous in creating a range …

Evaluation, Improvement, And Application Of Models Of Environmental Fate And Transport Of Atmosphere-Surface Exchangeable Pollutants (Aseps), Tanvir Khan

Dissertations, Master's Theses and Master's Reports

Certain toxic, semivolatile chemicals, also known as atmosphere-surface exchangeable pollutants (ASEPs) are emitted into the environment from anthropogenic activities and natural sources. This dissertation focused on the (i) evaluation and improvement of dry particle deposition and atmosphere-surface exchange parameterizations of ASEPs for use in chemical transport models (CTMs), and (ii) application of a dynamic multimedia model to examine recovery of Lake Superior from historical inputs of polychlorinated biphenyl (PCB) compounds (a class of ASEPs) contamination.

Current knowledge has been inadequate to propose quantitative measures of the relative performance of available dry particle deposition parameterizations. In Chapter 1 of this dissertation, …

Ground Deformation Studies And Evacuation Behavior During Eruptions At Guatemalan Volcanoes, Hans Lechner

Dissertations, Master's Theses and Master's Reports

Volcanic eruptions can be an especially problematic hazard when considering the uncertainty in eruption timing and magnitude coupled with challenges associated with delivering warnings to remote areas and facilitating effective evacuations. The hazards presented by Guatemala’s active volcanoes demand enhanced monitoring capabilities and instrumentation infrastructure. Strengthening the link between the physical and social sciences should lead to more accurate, reliable, and timely hazard information to the people living in proximity to the volcano and facilitate rational decisions and actions that reduce their level of risk. While there is no one single technique that can provide unambiguous diagnostics about the timing, …

Disaster Risk In The Lake Nyos Area, Cameroon: Effects Of The Gas Hazard And Socially Produced Vulnerability, Mary Witucki

Dissertations, Master's Theses and Master's Reports

Effective disaster risk reduction (DRR) efforts depend on comprehensive risk assessments that consider potential hazard events and social vulnerability. The Lake Nyos Disaster (LND) caused the deaths of about 1,700 people, forced another 4,000 people from their homes, and left survivors more vulnerable to future hazards. There is considerable research on the gas hazard and some work on local vulnerability; however studies rarely consider both aspects of disaster risk (DR). This study addresses both the hazard and vulnerability and uses several qualitative and quantitative methods which have never been applied to LND survivor vulnerability or gas hazard. Interviews, participant observation, …

Optimization And Control Of An Array Of Wave Energy Converters, Jianyang Lyu

Dissertations, Master's Theses and Master's Reports

This study explored optimal configuration of both the array layout and the dimension of each WEC in the array. The array contains heaving buoys with full interaction and exact hydrodynamics. Optimization of dimension was done on each WEC in the array with a given optimal layout, and a higher q-factor was achieved. Both impedance matching optimal control and derivative control were employed, which provides both theoretical maximum energy and a more realistic case. Then the work was expanded to optimization of both the array layout and the dimension of each WEC in the array. An average of 39.21% higher q-factor …

Effects Of Mass And Distance Uncertainties On Calculations Of Flux From Giant Molecular Clouds, Matt Coel

Dissertations, Master's Theses and Master's Reports

It is assumed that the distribution of the Milky Way cosmic rays, the cosmic ray ‘sea,’ is even throughout the Galaxy. This assumption can be tested by measuring gamma rays produced from cosmic ray interactions with Giant Molecular Clouds. The gamma ray flux depends on the mass and distance of a given molecular cloud as well as the cosmic ray flux in its vicinity. Thus a predicted gamma ray flux can be compared to actual flux data from a detector. Uncertainties from measuring the mass of and distance to the clouds are taken into account for this prediction. This report …

Evaluating The Effectiveness Of Current Atmospheric Refraction Models In Predicting Sunrise And Sunset Times, Teresa Wilson

Dissertations, Master's Theses and Master's Reports

The standard value for atmospheric refraction on the horizon of 34', used in all publicly available sunrise and sunset calculators, is found to be inadequate. The assumptions behind atmospheric models that predict this value fail to account for real meteorological conditions. The result is an uncertainty of one to five minutes in sunrise and sunset predictions at mid-latitudes (0° - 55° N/S). A sunrise/set calculator that interchanges the refraction component by varying the refraction model was developed. Two atmospheric refraction models of increasing complexity were tested along with the standard value. The predictions were compared with data sets of observed …

Long-Term Changes In Extreme Air Pollution Meteorology And Implications For Air Quality, Pei Hou

Dissertations, Master's Theses and Master's Reports

Extreme air pollution meteorology, such as heat waves, temperature inversions, and atmospheric stagnation episodes, can significantly affect air quality. In this study, we analyze their long-term trends and the potential impacts on air quality. The significant increasing trends for the occurrences of extreme meteorological events in 1951-2010 are identified with the reanalysis data, especially over the continental regions. A statistical analysis combining air quality data and meteorological data indicates strong sensitivities of air quality, including both average air pollutant concentrations and high pollution episodes, to extreme meteorological events. Results also show significant seasonal and spatial variations in the sensitivity of …

On The Density Of The Odd Values Of The Partition Function, Samuel Judge

Dissertations, Master's Theses and Master's Reports

The purpose of this dissertation is to introduce a new approach to the study of one of the most basic and seemingly intractable problems in partition theory, namely the conjecture that the partition function $p(n)$ is equidistributed modulo $2$. We provide a doubly-indexed, infinite family of conjectural identities in the ring of series $\Z_2[[q]]$, which relate $p(n)$ with suitable $t$-multipartition functions, and show how to, in principle, prove each such identity. We will exhibit explicit proofs for $32$ of our identities. However, the conjecture remains open in full generality. A striking consequence of these conjectural identities is that, under suitable …

Probing The Precambrian Geodynamo: Analysis Of The Geomagnetic Field Behavior And Calibration Of Pseudo-Thellier Paleointensity Method For Mesoproterozoic Rocks, Marine Foucher

Dissertations, Master's Theses and Master's Reports

Understanding the geomagnetic field direction and strength (e.g., paleomagnetism and paleointensity, respectively) recorded by Precambrian rocks is essential to obtain insight into the nature and evolution of the Earth’s early geodynamo and for constraining models of planetary evolution. Major milestones of our planet’s history, such as beginning of plate tectonics, development of the atmosphere and life, took place during the first four billion years. However, the available data on the Earth’s magnetic field in the Precambrian are very limited, especially the information about the field intensity which represents one of the most challenging aspect of paleomagnetic research. Many Precambrian rocks …

First-Principles Investigation Of The Interfacial Properties Of Boron Nitride, Kevin Waters

Dissertations, Master's Theses and Master's Reports

The interactions of nanomaterial surfaces with biological compounds, e.g. proteins, DNA, etc., unites the biological regime and nanomaterial world. Hybrid systems of boron-nitride nanotubes (BNNTs) and biological compounds are well-suited for a broad range of applications. First-principles methods are used to characterize the interface of these hybrid systems. Previous work has shown that the sensing capabilities of pristine BNNT are limited by long-ranged interactions. In this study the surfaces of pristine and functionalized BNNTs are investigated. The surfaces of the functionalized BNNTs give new properties to the tubes, which may enhance their sensing capabilities, while retaining their stability and chemical …

The Abiotic Stress Response Of Hydroponic Vetiver Grass (Chrysopogon Zizanioides L.) To Acid Mine Drainage And Its Potential For Environmental Remediation, Jef Kiiskila

Dissertations, Master's Theses and Master's Reports

Mining activities can generate acid mine drainage (AMD), an acidic discharge that contains elevated sulfate (SO₄^2-), soluble metals, and orange-yellow metal-containing particulates. AMD imposes ecological risks from metal toxicity and physical stress, which may physically spread to nearby water sources or biologically through bioaccumulation. Current methods for AMD treatment, such as chemical or passive biological treatments, are often non-sustainable. Chemical treatments can be expensive and create large amounts of secondary waste, whereas biological treatments like anaerobic wetlands require continuous maintenance through input of organic nutrients. The end goal of this research is to develop a cost-efficient and …

Wildfire Emissions In The Context Of Global Change And The Implications For Mercury Pollution, Aditya Kumar

Dissertations, Master's Theses and Master's Reports

Wildfires are episodic disturbances that exert a significant influence on the Earth system. They emit substantial amounts of atmospheric pollutants, which can impact atmospheric chemistry/composition and the Earth’s climate at the global and regional scales. This work presents a collection of studies aimed at better estimating wildfire emissions of atmospheric pollutants, quantifying their impacts on remote ecosystems and determining the implications of 2000s-2050s global environmental change (land use/land cover, climate) for wildfire emissions following the Intergovernmental Panel on Climate Change (IPCC) A1B socioeconomic scenario.

A global fire emissions model is developed to compile global wildfire emission inventories for major atmospheric …

Magnetless And Topological Edge Mode-Based On-Chip Isolators And Spin-Orbit Coupling In Magneto-Optic Media, Dolendra Karki

Dissertations, Master's Theses and Master's Reports

The rapid growth of optical communication networks requires monolithic integration of various optical components such as lasers, modulators, detectors, amplifiers. Optical feedback due to reflected light at the interfaces of several components in a photonic circuit has detrimental effects to the normal operation of laser by increasing noise, forcing laser to oscillate into different lasing modes etc. So optical isolators are crucial components to make complex optical circuits possible by preventing the feedback signal from coupling back to the lasers sources. For this purpose, an optical isolator that can reduce the feedback signal by > 30 dB and at the same …

Nondestructive Evaluation Of Salvage White Spruce, Tyler Hovde

Dissertations, Master's Theses and Master's Reports

Knowledge of wood quality in dead standing trees is an important topic with recent increases in defoliation across North America. Obtaining wood quality information for defoliated trees would help stakeholders in the timber products industry sort and sell salvaged material for the highest possible value. This research investigates the ability to measure wood quality of white spruce (Picea glauca) after spruce budworm (Choristoneura fumiferana) attack using acoustic nondestructive evaluation. We compared stress wave velocities measured on standing trees to trees’ visual appearance. After harvest and processing of selected trees into bolts, standing-tree stress wave velocities were compared to bolt acoustic …

Joint Analysis Of Multiple Phenotypes In Association Studies, Xiaoyu Liang

Dissertations, Master's Theses and Master's Reports

Genome-wide association studies (GWAS) have become a very effective research tool to identify genetic variants of underlying various complex diseases. In spite of the success of GWAS in identifying thousands of reproducible associations between genetic variants and complex disease, in general, the association between genetic variants and a single phenotype is usually weak. It is increasingly recognized that joint analysis of multiple phenotypes can be potentially more powerful than the univariate analysis, and can shed new light on underlying biological mechanisms of complex diseases. Therefore, developing statistical methods to test for genetic association with multiple phenotypes has become increasingly important. …

Characterizing Cdom Spectral Variability From Seas To Space, Brice Grunert

Dissertations, Master's Theses and Master's Reports

Colored dissolved organic matter (CDOM) absorption varies significantly across the global oceans, presumably due to differences in source and degradation pathways. Tracking this variability on a global, or even regional, scale requires broad temporal and spatial sampling at high frequency. Satellite remote sensing provides this platform; however, current and near future sensors are/will be limited to measurements within the UV and visible wavelengths (> 350 nm) while most optical proxies estimating CDOM composition, and relevant for understanding largescale biogeochemical processes, use wavelengths less than 350 nm. This dissertation examines global variability in CDOM spectral variability utilizing a variety of optical …

Offline And Online Density Estimation For Large High-Dimensional Data, Aref Majdara

Dissertations, Master's Theses and Master's Reports

Density estimation has wide applications in machine learning and data analysis techniques including clustering, classification, multimodality analysis, bump hunting and anomaly detection. In high-dimensional space, sparsity of data in local neighborhood makes many of parametric and nonparametric density estimation methods mostly inefficient.

This work presents development of computationally efficient algorithms for high-dimensional density estimation, based on Bayesian sequential partitioning (BSP). Copula transform is used to separate the estimation of marginal and joint densities, with the purpose of reducing the computational complexity and estimation error. Using this separation, a parallel implementation of the density estimation algorithm on a 4-core CPU is …

Direct Measurement Of Rupture Force Of Single Triazole Molecule By Atomic Force Microscope And Solid Phase Synthesis Of Monodisperse Polyethylene Glycols, Ashok Khanal

Dissertations, Master's Theses and Master's Reports

This dissertation includes two topics, which are related to each other: (1) Rupture force measurement of single triazole molecule by atomic force microscope (AFM) and (2) Solid phase stepwise synthesis of polyethylene glycols (PEGs).

The reaction of an alkyne and an azide to form a 1,2,3- triazole has found wide applications. However, the stability of triazole under mechanical stress is unclear. We investigated the cycloreversion at the single molecular level using atomic force microscopy. A mica surface functionalized with a molecule containing a 1,2,3-triazole moiety in the middle and an activated ester at the end was prepared. An AFM tip …

Pseudo-Companion Matrices For Polynomial Systems, Melinda Kleczynski

Dissertations, Master's Theses and Master's Reports

Roots of a scalar polynomial in one variable are frequently found by computing the eigenvalues of the standard companion matrix. In this exploratory work, we introduce the pseudo-companion matrix for finding roots of multivariable polynomial systems. In some cases, a perturbation of the polynomial system is used for the matrix construction, yielding approximate roots of the original polynomial system. The coordinates of the roots, or their approximations, are obtained from the eigenvectors of this matrix. In this thesis, we describe the process of constructing the pseudo-companion matrix and computing the polynomial roots using illustrative examples.

Modeling Data Center Co-Tenancy Performance Interference, Wei Kuang

Dissertations, Master's Theses and Master's Reports

A multi-core machine allows executing several applications simultaneously. Those jobs are scheduled on different cores and compete for shared resources such as the last level cache and memory bandwidth. Such competitions might cause performance degradation. Data centers often utilize virtualization to provide a certain level of performance isolation. However, some of the shared resources cannot be divided, even in a virtualized system, to ensure complete isolation. If the performance degradation of co-tenancy is not known to the cloud administrator, a data center often has to dedicate a whole machine for a latency-sensitive application to guarantee its quality of service. Co-run …

Comparison Of Karstification Methods And Isostatic Rebound In The Suwannee River Basin, Florida, Toni Larche

Dissertations, Master's Theses and Master's Reports

Plio-Pleistocene beach ridges in northern Florida are nearly 50 m above current sea level, but sea level during that time is not known to have been more than 25 m above current sea level. The height of beach ridges in northern Florida therefore create a conundrum because Florida is located on a passive margin in what is considered a tectonically stable environment. A series of recent studies have suggested that uplift on the Florida peninsula may be the result of the removal of subsurface crustal mass. Karstification of Florida’s carbonate matrix may provide a mechanism for subsurface crustal mass removal …

Resource Optimization In Wireless Sensor Networks For An Improved Field Coverage And Cooperative Target Tracking, Husam Sweidan

Dissertations, Master's Theses and Master's Reports

There are various challenges that face a wireless sensor network (WSN) that mainly originate from the limited resources a sensor node usually has. A sensor node often relies on a battery as a power supply which, due to its limited capacity, tends to shorten the life-time of the node and the network as a whole. Other challenges arise from the limited capabilities of the sensors/actuators a node is equipped with, leading to complication like a poor coverage of the event, or limited mobility in the environment. This dissertation deals with the coverage problem as well as the limited power and …

Study Of The Cygnus Region With Fermi And Hawc, Andrew Robare

Dissertations, Master's Theses and Master's Reports

The Cygnus Cocoon is an extended source of high-energy gamma-ray emission in the Cygnus region. The gamma-ray emission has been attributed to a volume 50pc in diameter of freshly-accelerated particles near the Supernova Remnant γ Cygni which is located 1.4kpc from the solar system [Ackermann et al., 2011], [Tibaldo et al., 2013]. Since its discovery in 2011, Fermi LAT has improved their event reconstruction to allow analysis at higher energies, and recorded six additional years of data. An analysis was performed on the entire dataset to reproduce the previous results, then expand on them with higher energies and larger time …