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Novel Synthesis Of Xanthene And Benzoxanthene Dyes, Corin Michelle Schowalter May 2007

Novel Synthesis Of Xanthene And Benzoxanthene Dyes, Corin Michelle Schowalter

Honors Theses

No abstract provided.


Applying Model-View-Controller To An Embedded System Simulation, Joseph Dominic Cali Apr 2007

Applying Model-View-Controller To An Embedded System Simulation, Joseph Dominic Cali

Honors Theses

No abstract provided.


Designing A Simulated Testing System For Embedded Systems Development, Abhishek Debchoudry Apr 2007

Designing A Simulated Testing System For Embedded Systems Development, Abhishek Debchoudry

Honors Theses

No abstract provided.


Spatial Ecology, Habitat Selection, And Survival Of Wild Turkey Gobblers In A Managed Bottomland Hardwood Forest, Blake Anthony Grisham Jan 2007

Spatial Ecology, Habitat Selection, And Survival Of Wild Turkey Gobblers In A Managed Bottomland Hardwood Forest, Blake Anthony Grisham

LSU Master's Theses

Wild turkey (Meleagris gallopavo) males were captured and radio-tagged in a bottomland hardwood forest of south-central Louisiana. Turkeys were monitored year round from fixed telemetry stations on Sherburne Wildlife Management Area, Atchafalaya National Wildlife Refuge, and Bayou des Ourses to observe seasonal patterns of space use, habitat selection and survival from 2005-07. The largest seasonal home range was in fall/winter (966.41 ha; Oct 1-Feb 28). Spring home range (767.77 ha; Mar 1- May 31) size was lower than reported in previous studies and was a function of female availability. Season and age interacted to influence core area size (F5/63 …


Early Flotant Establishment And Growth Dynamics In A Nutrient Amended Wetland In The Lower Mississippi River Delta, Caleb W. Izdepski Jan 2007

Early Flotant Establishment And Growth Dynamics In A Nutrient Amended Wetland In The Lower Mississippi River Delta, Caleb W. Izdepski

LSU Master's Theses

Nutrient dynamics and seasonal marsh growth were examined in a newly formed Panicum virgatum floating marsh at Thibodaux LA. The floating marsh formed in a cleared area of forested wetland receiving secondarily treated effluent. Net Areal Primary Productivity (NAPP), total belowground biomass, NO3, and δ15N ratios varied significantly (P <0.05) along a 75m marsh transect while mean δ13C varied between plant species. The upland end of the transect had the highest NAPP (3876 g m-2y-1), total belowground biomass (4079.0 ± 298.5 g m-2), and mean NO3 (5.4 ± 2.9 mg l-1). The mean floating-marsh …


Predicting Water Quality Effects On Bay Anchovy (Anchoa Mitchilli) Growth And Production In Chesapeake Bay: Linking Water Quality And Individual-Based Fish Models, Aaron Thomas Adamack Jan 2007

Predicting Water Quality Effects On Bay Anchovy (Anchoa Mitchilli) Growth And Production In Chesapeake Bay: Linking Water Quality And Individual-Based Fish Models, Aaron Thomas Adamack

LSU Doctoral Dissertations

Water quality in the Chesapeake Bay and the Patuxent River has decreased since the 1950s due to an increase in nutrient loadings. Increased nutrient loads have caused an increase in the extent and duration of hypoxic conditions. Restoration via large-scale reductions in nutrient loadings is now underway. How reducing nutrient loadings will affect water quality is well predicted; however the effect on fish is generally unknown as most water quality models do not include trophic levels higher than zooplankton. I combined two water quality models with bay anchovy models (Anchoa mitchilli) to examine the effects of changes in nutrient loadings …


A Comparison Of Channel Morphology, Marsh Elevation, And Biological Processes In Natural And Dredged Tidal Salt Marshes In Louisiana, Jennifer S. Spicer Jan 2007

A Comparison Of Channel Morphology, Marsh Elevation, And Biological Processes In Natural And Dredged Tidal Salt Marshes In Louisiana, Jennifer S. Spicer

LSU Doctoral Dissertations

Channel networks in tidal marshes serve as conduits for the exchange of water between the estuary and the marsh surface and form the spatial structure that regulates the flow of organisms, materials, and energy throughout the marsh system. Canal dredging creates channels with distinct linear shapes, and the artificial levee created from the dredged material creates ‘spoil banks’ along either side of the channel edge. Differences in morphology and adjacent marsh surface elevation between natural and dredged channel systems have not been well quantified, but may have important implications for the functioning of tidal channels as habitat for marsh-dependent species. …


Shelf-Margin Delta Morphology As A Paleo Sea Level Indicator: Implications On Late Quaternary Relative Sea-Level Changes In The Northeast Gulf Of Mexico, Swati Ghoshal Jan 2007

Shelf-Margin Delta Morphology As A Paleo Sea Level Indicator: Implications On Late Quaternary Relative Sea-Level Changes In The Northeast Gulf Of Mexico, Swati Ghoshal

LSU Doctoral Dissertations

A new technique to determine relative sea level history at siliciclastic settings is proposed in this dissertation. The clinoform break (defined as the topset-foreset transition point) of the modern Mississippi River Delta shows a direct relationship with sea level elevation. The analysis of Holocene lobes 8 and 9 belonging to the St. Bernard delta complex of the Mississippi Delta suggests that delta clinoforms can be significantly modified by post-abandonment processes, and hence a detailed stratigraphic evaluation is necessary to determine whether the clinoform geometry is a result of wave erosion or any other post-abandonment processes. The strategy was tested on …


Interactions Of The Triaquatricarbonylrhenium(I) Cation With Nucleotides And Other N-Donor Ligands, Kristie Marie Adams Jan 2007

Interactions Of The Triaquatricarbonylrhenium(I) Cation With Nucleotides And Other N-Donor Ligands, Kristie Marie Adams

LSU Doctoral Dissertations

Transition metal centers possessing an octahedral geometry are useful for understanding the natural role of metal ions in biology. Complexes based on such metals might improve upon the widely used square planar Pt(II) anticancer drug cisplatin, cis-[Pt(NH3)2Cl2]. The octahedral triaquatricarbonylrhenium(I) cation, fac-[Re(CO)3(H2O)3]+, has been shown to possess anticancer activity. Furthermore, Re(I) complexes containing unstable rhenium isotopes have found utility as radiodiagnostic and radiotherapeutic agents. Thus, this work focuses on elucidating the fundamental coordination chemistry of fac-[Re(CO)3(H2O)3]+ …


The Ecology Of Blacktail Redhorse Moxostoma Poecilurum In West Fork Thompson Creek, Louisiana, Jesse Adam Bahm Jan 2007

The Ecology Of Blacktail Redhorse Moxostoma Poecilurum In West Fork Thompson Creek, Louisiana, Jesse Adam Bahm

LSU Master's Theses

This study was designed to examine home range sizes and habitat use of blacktail redhorse Moxostoma poecilurum in West Fork Thompson Creek, Louisiana. Blacktail redhorse are a common non-game species found in Louisiana and other southeastern states. Adult blacktail redhorse (N=40; 187-273 mm total length) were implanted with radio transmitters and tracked twice weekly from February to September 2006 and from February to July 2007. To assess blacktail redhorse diet I analyzed 32 stomachs from fish collected by backpack electrofishing. I also conducted mark-recapture surveys of fish sampled monthly from May 2006 until July 2007. To assess homing ability in …


Properties Of Silica-Polypeptide Composite Particles, Jianhong Qiu Jan 2007

Properties Of Silica-Polypeptide Composite Particles, Jianhong Qiu

LSU Doctoral Dissertations

Studies of grafting polymer on surfaces with chemical bonds started in the 1970’s, but few projects have focused on grafting polypeptide on spherical particles. In this research, polypeptides poly(å-carbobenzyloxy-L-lysine) (PCBL) or poly(ã-benzyl-L-glutamate) (PBLG) were grafted on silica sphere surfaces by using the “grafting from” method. The polypeptide-grafted silica spheres are called SiPCPs. The growth of polypeptide chains as a function of monomer amount and reaction time was explored. The properties of a mixture of PBLG rod-like polymer and PBLG SiPCPs were investigated. At high concentrations of these two components, the phase behavior was studied. At low concentrations of PBLG, the …


Investigation Of Phospholipid Tubule Morphology For Use In Drug Delivery, Colleen Colson Garrett Jan 2007

Investigation Of Phospholipid Tubule Morphology For Use In Drug Delivery, Colleen Colson Garrett

LSU Doctoral Dissertations

Spherical vesicles consisting of phosphatidylcholines in which diacetylene groups have been inserted in the hydrocarbon tail centers give rise to hollow cylindrical tubes, known as “tubules”. The study of tubules has become an area of intense interest in recent years due to their unusual morphology, which raises several profound theoretical issues and suggests their use in a variety of applications. Tubule hollowness suggests medical and industrial encapsulations as well as filtration and purification applications. These potential uses, e.g., for drug and gene delivery, requires optimization of their morphology for the application. Tubules have many technologically desirable properties, such as a …


Establishment And Chemical Analysis Of Hairy Roots Of Eucommia Ulmoides, Xiaojun Wu Jan 2007

Establishment And Chemical Analysis Of Hairy Roots Of Eucommia Ulmoides, Xiaojun Wu

LSU Doctoral Dissertations

The bark of Eucommia ulmoides Oliver (Eucommiaceae) has been used over thousands of years as a folk remedy. Extracts from the bark exhibit multiple pharmacological functions, especially in lowering blood pressure. Geniposidic acid (GA), pinoresinol diglucoside (PG) and chlorogenic acid (CA) are three compounds isolated from the bark of the Eucommia tree, which display enormous bioactivities. As a type of plant tissue culture, the hairy root culture system displays prospective application over traditional cell or callus cultures, which are characterized by rapid growth, and stable biochemical and genetic capacity. The present dissertation discusses the establishment and chemical analysis of E. …


Empirical Modeling Of Late Quaternary Sediment Supply To The Gulf Of Mexico Shelf Margin In A Cool Lowstand World, Jill Hattier Womack Jan 2007

Empirical Modeling Of Late Quaternary Sediment Supply To The Gulf Of Mexico Shelf Margin In A Cool Lowstand World, Jill Hattier Womack

LSU Master's Theses

During the last glacial period, river systems responded to the lowering of sea level by incising valleys, extending across the continental shelf, and depositing deltas on the shelf margin and upper slope of surrounding basins. These deltas represent important repositories for sediment delivered to the coastal ocean and provide partial records of sediment discharged from continental landmasses. Over relatively short time scales, like that of the last glacial-interglacial cycle, hinterland drainage areas, relief and lithology can be considered constants while the primary variable of significance is climate change (Syvitski and Milliman, 2007). It is reasonable to assume, therefore, that supply …


Spatial Ecology Of Gray Foxes On A Longleaf Pine Forest And The Surrounding Landscape In Southwestern Georgia, Danielle Lolene Temple Jan 2007

Spatial Ecology Of Gray Foxes On A Longleaf Pine Forest And The Surrounding Landscape In Southwestern Georgia, Danielle Lolene Temple

LSU Master's Theses

In the southeastern United States, industrial agriculture dominates the landscape, and much of the native land cover is in decline. Longleaf pine forests were once a dominant ecosystem in this region, but have largely disappeared. However, little research has been conducted on how this loss affects wildlife, especially mammalian predators. With increasing restoration efforts for longleaf pine it is important to assess the impact on species that inhabit those landscapes. Gray foxes (Urocyon cinereoargenteus) are native to the Southeast, but are adaptable to a wide range of habitats. Therefore, during 2002-2006 I studied a population of gray foxes on land …


The Application Of Controlled Radical Polymerization Processes On The Graft Copolymerization Of Hydrophobic Substituents Onto Guar Gum And Guar Gum Derivatives, Veronica Holmes Jan 2007

The Application Of Controlled Radical Polymerization Processes On The Graft Copolymerization Of Hydrophobic Substituents Onto Guar Gum And Guar Gum Derivatives, Veronica Holmes

LSU Doctoral Dissertations

Guar gum is a naturally occurring polysaccharide; guar gum and its derivatives, such as carboxymethyl guar gum (CMG) are widely used in the oil and gas industry. A hydraulic fracturing fluid for rock formations to enhance oil recovery (EOR) is comprised of viscosifier, gelled CMG, and sand particles (proppants). The gel is mixed with proppant (sand) and pumped at high rate and high pressure into an oil/gas well to the hydrocarbon-producing zone. The applied pressure will force the rock formation to fracture allowing entry of the guar gel/sand mixture. The mixture then fills the resultant fracture. The viscosity of the …


Quantum Dynamics Of Loop Quantum Gravity, Muxin Han Jan 2007

Quantum Dynamics Of Loop Quantum Gravity, Muxin Han

LSU Master's Theses

In the last 20 years, loop quantum gravity, a background independent approach to unify general relativity and quantum mechanics, has been widely investigated. The aim of loop quantum gravity is to construct a mathematically rigorous, background independent, nonperturbative quantum theory for the Lorentzian gravitational field on a four-dimensional manifold. In this approach, the principles of quantum mechanics are combined with those of general relativity naturally. Such a combination provides us a picture of "quantum Riemannian geometry", which is discrete at a fundamental scale. In the investigation of quantum dynamics, the classical expressions of constraints are quantized as operators. The quantum …


Exploring The Binding Of Amine And Sulfonamide Ligands In Rhenium(I) Tricarbonyl And Platinum(Ii) Complexes, Anna Maria Christoforou Jan 2007

Exploring The Binding Of Amine And Sulfonamide Ligands In Rhenium(I) Tricarbonyl And Platinum(Ii) Complexes, Anna Maria Christoforou

LSU Doctoral Dissertations

Platinum is the metal present in various classes of inorganic medicinal agents directed at important diseases such as cancer or viral infections. Several new Pt(II) complexes of polyamine ligands bearing a dansyl moiety linked by a sulfonamide group were prepared; in some cases the sulfonamide nitrogen formed a bond to Pt. The sulfonamido group donates strongly to Pt and places the dansyl group close to a vacant coordination position, allowing it to stack with bound guanine base (G) when G binds. The emission of the fluorophore decreases with decreasing distance to Pt. Metal nuclide radiopharmaceuticals contain a metal core and …


Chemical Analysis Of Extracts From Port-Orford Cedar Wood And Bark, Heng Gao Jan 2007

Chemical Analysis Of Extracts From Port-Orford Cedar Wood And Bark, Heng Gao

LSU Master's Theses

This study investigated a Soxhlet extract procedure to separate chemical components in the wood and bark of Port-Orford cedar (POC) (Chamaecyparis lawsoniana). The bio-activities, antioxidant properties, and decay resistance were evaluated. The heartwood extracts were analyzed by gas chromatography-mass spectrometry (GC-MS). Three vitro assays including (1) 1, 1-diphenyl-2-picrylhydrazyl hydrate (DPPH• ) radical scavenging assay, (2) 2,2-azinobis ( 3-ethylbenzothiszoline-6-sulfonic acid) diammonium salt (ABTS) radical cation scavenging ability assay, and (3) metal chelating activity assay were carried out to evaluate the antioxidant activity. The total phenol content of the extracts was determined by the Folin-Ciocalteu method and expressed as Gallic Acid Equivalent …


Evaluation Of Mvct Images With Skin Collimation For Electron Treatment Planning, Allen Beardmore Jan 2007

Evaluation Of Mvct Images With Skin Collimation For Electron Treatment Planning, Allen Beardmore

LSU Master's Theses

Purpose: To evaluate the accuracy of electron beam dose calculations in MVCT images containing lead alloy masks. Method and Materials: A phantom consisting of two 30x30x5 cm3 slabs of CIRS plastic water® was imaged using kVCT (GE Lightspeed-RT) and MVCT (TomoTherapy Hi·Art). Nine MVCT scans were taken with different square masks of lead alloy (Cerrobend®, density = 9.4 g·cm-3) on top of the phantom. The masks contained square apertures of 3x3 cm2, 6x6 cm2 and 10x10 cm2 and had thicknesses of 6 mm, 8 mm and 10 mm. The same collimation was simulated …


Evolution Of An Allochthonous Salt System, Southern Mars-Ursa Basin, Northern Gulf Of Mexico, Angela Bordelon Pell Jan 2007

Evolution Of An Allochthonous Salt System, Southern Mars-Ursa Basin, Northern Gulf Of Mexico, Angela Bordelon Pell

LSU Master's Theses

This study examines the evolution of an allochthonous salt system in the southern Mars-Ursa basin. A seismic stratigraphic framework and biostratigraphic markers provided constraints on basin development and sediment accumulation from late Miocene to middle Pliocene time. External geometries of tectonostratigraphic packages are identified in the study area and are combined with analyses of brittle deformation to track salt evacuation in the study area. External geometries identified in the study include: wedge, layer and trough. Fifty-nine faults were mapped in basin and suprasalt strata and five phases of brittle deformation were identified. Eight evolutionary stages were identified for the time …


Structural Manipulation Of Pyrrole-Terminated Dendrimers To Create A More Efficient Encapsulation/Release System, Henry Wiggins Jan 2007

Structural Manipulation Of Pyrrole-Terminated Dendrimers To Create A More Efficient Encapsulation/Release System, Henry Wiggins

LSU Doctoral Dissertations

This work demonstrates the ability to manipulate the structure of pyrrole-terminated dendrimers by modifying solution conditions which directly affects their encapsulation properties. Investigations were conducted using FTIR and 2D NMR to determine the location of end groups. NMR relaxation studies were conducted at various temperatures and different solution pH to gain an understanding of the relative mobility and rigidity of different areas of the dendrimer. It was found that that the release properties were affected by the solution pH and the presence of salt. Further the effectiveness of retaining molecular guests by oligo-pyrrole terminated dendrimers with a range of oligomer …


Stereochemical And Regiochemical Trends In The Selective Spectrophotometric Detection Of Biological Molecules, Shan Jiang Jan 2007

Stereochemical And Regiochemical Trends In The Selective Spectrophotometric Detection Of Biological Molecules, Shan Jiang

LSU Doctoral Dissertations

Useful mechanistic studies to date concerning sugar detection by arylboronic acid chemosensors have mainly involved the elucidation of equilibrium constants and the role of boron-nitrogen interactions in signal transduction. However, several discreet sugarboronate complexes exist in solution. This is due to the complex equilibria between isomeric species of even the simplest monosaccharides. Relatively few reports have been devoted to a systematic study of the structures of each of the corresponding individual sugar-boronate complexes. We have investigated some of the precise regio- and stereochemical features of the various equilibrating sugar isomers that induce selective signal transduction. As a result of this …


Synthesis Of Quaternary Dendronized Cellulose Derivatives And Their Potential Biological Applications, Changde Zhang Jan 2007

Synthesis Of Quaternary Dendronized Cellulose Derivatives And Their Potential Biological Applications, Changde Zhang

LSU Doctoral Dissertations

In this dissertation, novel dendronized cellulose derivatives with biodegradable backbones were created by using sodium carboxymethyl cellulose (CMC) as the starting material. CMC was first transformed into its corresponding tetrabutyl ammonium salt, which reacted with 2-chloro-N-methylpyridinium iodide (CMPI) to produce an activated ester of [2-(N-methyl pyridium) carboxymethyl cellulose] iodide (MPCMCI). The reaction of MPCMCPI and di-tert-butyl 4-[2-(ter-butoxycarbonyl)ethyl]-4-aminoheptanedicarboxylate (BA) produced a new derivative with BA dendron elaborated on cellulose backbone (CMCBA). The degree of substitution (DS) of CMCBA was adjusted by controlling the relative concentration of CMPI and by choosing CMC with different DS or different molecular weights. Thermogrametric analysis (TGA) …


Synthesis And Properties Of Isoporphyrins And Related Derivatives For Application In Photodynamic Therapy, Sandra Celinah Mwakwari Jan 2007

Synthesis And Properties Of Isoporphyrins And Related Derivatives For Application In Photodynamic Therapy, Sandra Celinah Mwakwari

LSU Doctoral Dissertations

Isoporphyrins are tautomers of porphyrins with an interrupted macrocyclic conjugation owing to the presence of a sp3 hybridized meso-carbon. Due to their absorption at long wavelengths (~800nm), isoporphyrins are potential candidates as photosensitizers in photodynamic therapy (PDT), a ternary modality of cancer treatment. They are also of biological interest due to their unique redox properties among porphyrin derivatives and could be a new class of near-IR dyes. Isoporphyrins are known to be unstable with respect to transformation back to the fully conjugated porphyrin chromophore except when the meso-carbon is geminally substituted and for this reason a detailed study of this …


The Effects Of Trawling And Habitat Use On Red Snapper And The Associated Community, Robert Joseph David Wells Jan 2007

The Effects Of Trawling And Habitat Use On Red Snapper And The Associated Community, Robert Joseph David Wells

LSU Doctoral Dissertations

The primary impediment to the recovery of Gulf of Mexico (GOM) red snapper is believed to be high levels of bycatch of age 0 and age 1 individuals in shrimp trawls. Thus, conservation of GOM red snapper involves evaluating both habitat-specific function and effects of shrimp trawls on red snapper and the associated benthic ecosystem. The two goals of this study were to evaluate the effects commercial shrimp trawls have on juvenile red snapper life history parameters, on associated fish and invertebrate communities and their habitat, and to identify essential fish habitat (EFH) for red snapper by applying all four …


Heavy Mineral Analysis Of The Pecan Island Complex, Louisiana Chenier Plain, Southwest Louisiana, Cherie' Jenae Lee Jan 2007

Heavy Mineral Analysis Of The Pecan Island Complex, Louisiana Chenier Plain, Southwest Louisiana, Cherie' Jenae Lee

LSU Master's Theses

This study reports the results of a heavy mineral analysis of samples from Pecan Island and associated ridges on the Louisiana Chenier Plain. The goal of the study is to provide additional insight on the origins of the sand comprising the ridges. Chenier plains are multi-membered, progradational ridge-interridge mudflat sequences (Augustinus, 1989). The various suggested sources of the sand grains include: the Mississippi River, especially the Teche sub-delta; the Mermentau and Calcasieu Rivers; and the reworking of older mudflat and chenier ridges. Several liters of sand were collected from a depth of 0.5 to 2.0 meters at locations near the …


Multiplicative Renormalization Method For Orthogonal Polynomials, Suat Namli Jan 2007

Multiplicative Renormalization Method For Orthogonal Polynomials, Suat Namli

LSU Doctoral Dissertations

To study the orthogonal polynomials, Asai, Kubo and Kuo recently have developed the multiplicative renormalization method. Motivated by infinite dimensional white noise analysis, it is an alternative to the computational part of the classical Gram-Schmidt process to find the orthogonal polynomials for a given measure. Instead of finding the orthogonal polynomials recursively as described in the Gram-Schmidt process, one analyzes different types of generating functions systematically in order to obtain polynomials after power series expansion. This work also produces the Jacobi-Szego parameters easily and paves the way for the study of one-mode interacting Fock spaces related to these parameters. They …


Elementary Reactions Involved In Pollutant-Forming Mechanisms, Cheri Ann Mcferrin Jan 2007

Elementary Reactions Involved In Pollutant-Forming Mechanisms, Cheri Ann Mcferrin

LSU Doctoral Dissertations

The reactions of the hydroxyl radical (OH) with molecular chlorine (Reaction 1), methane (Reaction 2), and propane (Reaction 3) have been studied experimentally using a pulsed laser photolysis/pulsed-laser-induced fluorescence technique over wide ranges of temperatures (297-826, 298-1009, and 296-908 K, respectively) and at pressures between 6.68 and 24.15 kPascals. The rate coefficients for these reactions exhibit no dependence on pressure and exhibit positive temperature dependences that can be represented with modified three-parameter Arrhenius expressions within their corresponding temperature ranges: k1 = 3.59 x 10-16T1.35exp(-745K/T)cm3molecule-1sec-1, k2 = 3.82 x 10-19T2.38 exp(-1136K/T)cm3molecule-1sec-1, and k3 = 6.64 x 10-16T1.46 exp(-271K/T)cm3molecule-1sec-1. For the OH …


Protocol Development For Pro-Active Emergency Responses By Veterinary Clinics And Hospitals, Laura Marie Basirico Jan 2007

Protocol Development For Pro-Active Emergency Responses By Veterinary Clinics And Hospitals, Laura Marie Basirico

LSU Master's Theses

The Gulf Coast hurricanes of 2005 necessitated the development of a guidance document concerning emergency preparedness and response for veterinary clinics and hospitals. The aftermaths of the largest natural disasters in United States' history, namely Hurricanes Katrina and Rita, brought to light the need for a protocol designed specifically for veterinarians and veterinary practitioners. Disaster management information was synthesized and modified to be subject-specific for the veterinary community. This synthesis resulted in the creation of the Veterinary Emergency Preparedness and Response (VEPR) manual and website. Two types of data were collected to develop the emergency protocol; interviews with veterinarians and …