Digital Commons Network^™

Making And Breaking Bonds: Studying Intrinsic Chemistry In The Gas-Phase, Luke Metzler

Electronic Theses and Dissertations

The nature of chemical interactions can be difficult to ascertain in the condensed phase; chemistry can be observed, but with the plethora of variables such as solvation, mixes of counter-ions, and complex equilibria, the true intrinsic chemical properties of a given chemical species may be obfuscated. By conducting research in the gas-phase, many of these variables can be reduced, if not eliminated entirely, which can allow for the careful observation of the true physical phenomena driving chemical reactivity.

The research presented herein focuses on the use of ion-trapping (specifically in a linear ion trap) as a method for unveiling the …

Evaluation Of Changes In Evaporative Losses From Lake Powell Reservoir Contributions In The Colorado River Basin, Maria Mlinarcik

Electronic Theses and Dissertations

The Colorado River Basin (CRB) is one of the most critical water sources for the western United States (U.S.) and Mexico. For over a century, numerous policies and regulations have been implemented in attempts to manage the Colorado River Basin to address the concern of overuse, collectively referred to as the “Law of the River.” The USGS hydrologist E.C. LaRue warned that the optimistic estimates used in negotiating the Colorado River Compact did not align with the actual water availability in the river. His analysis in 1925 revealed a potential deficit if all allocated water was utilized, exacerbated by overallocation …

Interactive Effects Of Sublethal Concentrations Of Fracking Biocides And Abandoned Mine Drainage On Amphipod Behavior, Kelly Lenhart

Electronic Theses and Dissertations

This thesis examined the sublethal effects of three pollutants, namely glutaraldehyde, 4,4-dimethyloxazolidine (DMO), and abandoned mine drainage (AMD), on amphipods. The primary objective was to investigate their combined effects on amphipods. The three pollutants, despite having the potential to combine in the environment, have not been studied to determine their potential for detrimental interactive effects which could result in unexpected environmental damage.

The research employed a series of experimental setups involving controlled exposure of amphipods to varying, putatively sublethal, concentrations of the chemicals of interest. Subsequently, effects were assessed via both behavioral and feeding assessments. To facilitate this analysis, novel …

Environmental Problems With Space Exploration, Julia Halvas

D.U.Quark

No abstract provided.

The Cost Of Climate Change, Emily Ambery

D.U.Quark

No abstract provided.

Proposing A Measure Of Ethicality For Humans And Ai, Alejandro Jorge Napolitano Jawerbaum

Electronic Theses and Dissertations

Smarter people or intelligent machines are able to make more accurate inferences about their environment and other agents more efficiently than less intelligent agents. Formally: ‘Intelligence measures an agent’s ability to achieve goals in a wide range of environments.’ (Legg, 2008)

In this dissertation we extend this definition to include ethical behaviour and we will offer a mathematical formalism and a way to estimate how ethical an action is or will be, both for a human and for a computer, by calculating the expected values of random variables. Formally, we propose the following measure of ethicality, which is computable, or …

Examining The Effectiveness Of Using Point-Of-View Video Modeling On Mathematics Improvement In Students With Learning Disabilities In Saudi Arabia, Tirad Alsaluli

Electronic Theses and Dissertations

Video Modeling (VM) is one of the most widely used approaches by researchers to improve many skills, such as academic skills in students with Learning Disabilities (LD; Boon et al., 2020). As the incidence rate of individuals with LD in Saudi Arabia increase (Almedlij & Rubinstein-Ávila, 2018), the need for evidence-based math interventions focused on the math development of individuals with LD also increases. Although VM is recognized as an Evidence-based Practice (EBPs), a limited number of studies have implemented VM as an intervention to improve mathematic skills. Implementing VM as a math intervention strategy would explore its effects on …

Indirect Aggression And Victimization: Investigating Instrument Psychometrics, Gender Differences, And Its Relationship To Social Information Processing, Taylor Steeves

Electronic Theses and Dissertations

The study of indirect bullying behaviors, relational aggression and social aggression, has been of theoretical importance and interest to researchers and psychologists within the last few decades. In this investigation, using a convenience sample of 451 late adolescents attending a private university in the mid-Atlantic U.S., I examined the factor structure of two measures of indirect bullying, the Young Adult Social Behavior Scale – Victim (YASB-V) and the Young Adult Social Behavior Scale – Perpetrator (YASB-P). Using confirmatory factor analysis (CFA), I found that the YASB-V comprised a four-factor model, differing from the model that had been identified in the …

Comparative Life Cycle Assessment Of Small Vertical-Axis Wind Turbines And Natural Gas Facility At An Urban University, Mary Kate Ranii

Electronic Theses and Dissertations

Fossil fuels generate the majority of the electricity in the United States and generate pollutants that negatively affect public and environmental health. Renewable energy projects serve as an opportunity for low-pollution and low-carbon electricity; small-scale projects, such as vertical axis wind turbines (VAWTs), provide opportunities for generation in urban areas close to consumers. Researchers collected wind speed and directional data from a potential turbine installation site at Duquesne University to better demonstrate the potential benefits in an urban university location. The data was used in a life cycle assessment framework and a social review to better understand the value of …

Do Integrated Circuits Make For An Integrated Supply Chain? A Network Analysis Of Trade Flows, Noah Martens

Electronic Theses and Dissertations

Integrated circuits (colloquially referred to as chips) are an increasingly critical commodity experiencing continuous and substantial rises in demand. These increases in demand recently resulted in shortages. This paper seeks to understand the market for chips and construct a framework by which a network analysis of trade flows can evaluate concentration in the international market for a particular product category. Leveraging this framework and proposing a new model, I evaluate the level and nature of concentration in the chips sector, as well as two key inputs to the manufacturing process, silicon and chip fabricators. I find moderate-to-high levels of concentration …

Identification Of Sulfate Reducing Bacteria For Abandoned Mine Drainage Bioremediation, Lance Daley, Nancy Trun Phd

D.U.Quark

No abstract provided.

Mother Earth, Lance Daley

D.U.Quark

No abstract provided.

"In The Beginning, God Created Atoms", Samiya L. Henry

Undergraduate Research and Scholarship Symposium

Genesis 1:1 states “In the beginning, God created the heavens and the earth.” This is the defining statement in the Bible and acts as the foundation of creation and God’s power in the Christian faith. On the other hand, many scientists believe the Big Bang Theory and the discoveries made in other fields of science solely define the creation of the universe and explain life as we know it, also disproving the Christian creation story and the overall existence of God. However, the exact opposite is true; God is science.

Alone, neither of these concepts (faith and science) fully solve …

Applying Bentham's Theory Of Fallacies To Chief Justice Robert's Reasoning In West Virginia V. Epa, Dana Neacsu

Duquesne Law Review

There are two issues in West Virginia v. EPA.¹ One regards justiciability, and the other delegation. Article III of the Federal Constitution limits justiciability to controversies, to disputes involving an injured party whose harm the judiciary believes it can remedy. The Constitution is silent on delegation.

This Essay summarizes the Court's decision in West Virginia v. EPA.² It also analyzes Chief Justice Roberts' reasoning and addresses the case's flaws from two perspectives. It references the Court's decision connecting it to the so-called New Deal Cases,³ because in both Panama Refining Co. v. Ryan,^{4 …}

Hydrologic Modeling With Remote Sensing For The Estimation Of Groundwater Resources Within The Sand River Catchment, South Africa, Sophia Bakar

Electronic Theses and Dissertations

The Sand River Catchment is an important tributary of the transboundary Limpopo River in South Africa, which spans Botswana, Mozambique, South Africa, and Mozambique. Groundwater is a critical resource in the region, especially in the context of population growth and climate change. Data are needed for proper management of these water resources. In regions where groundwater data are sparse in time, space, or both, the most promising solutions come from satellites and hydrologic models. Regional literature suggests that the Soutpansberg Mountains, located within the Sand Catchment, are high-elevation water towers with uncertain groundwater resources. Improved understanding of groundwater resources in …

Assessments Of Water Chemistry And Fish Community Structure In The Buffalo Creek Watershed, Tributary To The Allegheny River In Armstrong And Butler Counties, Pennsylvania, Kathleen Wilson

Electronic Theses and Dissertations

The Buffalo Creek watershed has experienced water quality impairments for various reasons, including but not limited to, agricultural influence, abandoned mine drainage (AMD), on-site wastewater malfunction, and stormwater. The source and cause of the most prevalent impaired areas remains unknown. The goal of this study was to analyze water chemistry using state water quality standards and mass ratio analysis, then to conduct fish community analysis. We found toxic metal pollution across the watershed, with iron, cadmium, copper, and selenium frequently exceeding criteria. We determined which streams are polluted by resource extraction activities by conducting mass ratio analysis. We found conventional …

Speciated Isotope Dilution Mass Spectrometry In Combination With Thor’S Hammer Metaspike Technology For The Assessment Of Low-Level Biomarkers For Human Health Evaluation, Ashley Ebert

Electronic Theses and Dissertations

Our research team has been focused on quantifying important biological analytes in human blood samples to delineate the biochemical processes underlying certain states of dysfunction and evaluate treatment efficacy. These efforts have been guided by laboratory measurements with the input of medical experts. Speciated isotope dilution mass spectrometry (SIDMS) explained in detail in EPA Method 6800 has been successfully applied in the quantification of an important biomarker analyte for immune function and detoxification processes: glutathione. Past research has proven the molecule a biomarker for autism spectrum disorder (ASD) in the form of the reduced/oxidized glutathione (GSH/GSSG) ratio, and literature has …

Quantum Computations And Molecular Dynamics Simulations: From The Fundamentals Of Antimicrobial Resistance To Neurological Diseases, Angel Tamez

Electronic Theses and Dissertations

Biophysical phenomena are modeled using a combination of quantum and classical methods to interpret and supplement three distinct and diverse problems in this dissertation. In the first project, decarboxylation reactions are ubiquitous across chemical and biological disciplines, yet the origin of non-catalytic solvent effects remains elusive. Specific solvent structure and energetics have not been well described for the monoanion of malonate, nor corrected from the gas-phase charge-assisted intramolecular hydrogen bond model known as “pseudochair”. In the aqueous phase, a low-lying energy conformer known as the “orthogonal conformation” is computed to be preferred by a three-water cluster of hydrogen bonding over …

Mathematical Models Yield Insights Into Cnns: Applications In Natural Image Restoration And Population Genetics, Ryan Cecil

Electronic Theses and Dissertations

Due to a rise in computational power, machine learning (ML) methods have become the state-of-the-art in a variety of fields. Known to be black-box approaches, however, these methods are oftentimes not well understood. In this work, we utilize our understanding of model-based approaches to derive insights into Convolutional Neural Networks (CNNs). In the field of Natural Image Restoration, we focus on the image denoising problem. Recent work have demonstrated the potential of mathematically motivated CNN architectures that learn both `geometric' and nonlinear higher order features and corresponding regularizers. We extend this work by showing that not only can geometric features …

Synthesis And Physicochemical Characterization Of Noncentrosymmetric Quaternary Sulfides With Potential Nonlinear Optical Applications, Andrew J. Craig

Electronic Theses and Dissertations

In this work, several new quaternary sulfides were synthesized and investigated for their potential applications in optics. Chapter 1 provides an overview of nonlinear optical (NLO) materials in general, including their applications, ideal characteristics, current deficiencies, and strategies for the discovery of new candidate NLO materials, particularly those for use in the infrared (IR). Two families of compounds are investigated in this work, including Ln₃LiTS₇ (3-1-1-7) compounds and I₄-II-IV₂-VI₇ (4-1-2-7) diamond-like semiconductors (DLSs). All products were synthesized via traditional high-temperature, solid-state synthesis and their structures were solved and refined through single crystal …

Theory Of Aqueous Solvation: Uninterrupted, Cyclic Hydrogen-Bonding Essential For Accurate Keto-Enol Energies And Grotthuss Tautomerism Of Acetone, Mark Recznik

Electronic Theses and Dissertations

Keto-enol tautomerization (KET) is a fundamental process impacting a range of molecular phenomena in organic and biochemistry. However, the accurate computation of solution-phase KET energies remains a challenge, even for prototypical acetone.

In Part I, keto-enol tautomers of acetone were incorporated into solvent clusters that interact via uninterrupted, cyclic hydrogen-bonding (UCHB) networks. An empirical model was created to predict accurate KET energies, E_taut, of simple carbonyl compounds. Based on the availability of experimental data and structural simplicity, acetone was selected as a prototype. A discrete-continuum strategy was employed – accounting simultaneously for local noncovalent interactions and bulk-phase effects …

Assessing The Risk Of Land Subsidence In The Lower Limpopo River Basin, Mozambique With Remote Sensing, Gabriella Zuccolotto

Electronic Theses and Dissertations

Land subsidence is a threat to coastal cities around the world. In the lower Limpopo River Basin, the presence of compaction-prone alluvial sediments, groundwater use, and reports of saltwater intrusion suggest that subsidence could be occurring. Using interferometric synthetic aperture radar (InSAR) from Sentinel-1, combined with in-situ sea level and river height measurements, this study aims to determine if land subsidence could contribute to increased saltwater intrusion. InSAR results indicate that subsidence in the lower Limpopo River valley has occurred at an average rate of -2.98 cm/yr based on data from the dry seasons (May to October) of 2017-2021. River …

The Importance Of Understanding And Developing Identification Techniques In Wildlife Crime, Savannah Nguyen

D.U.Quark

Wildlife crime continues to grow annually and globally, impacting several species and ecosystems. New advancements of technologies and techniques can track criminals and aid the affected victims. Highlighting the complexity of conservation and the development of identification techniques helps tackle this widespread dilemma. New developing techniques in wildlife forensics can differentiate an animal between wild and poached to pave the way for further advancement in understanding wildlife crimes. Hence, though the wildlife forensics field is still new, emphasizing the need for intricate identification techniques can help save threatened species.

Steps Toward The Total Synthesis Of The Chrysosporazine Family, Katie Kaczynski

Electronic Theses and Dissertations

Cancer is one of the leading causes of death worldwide, with 19.3 million new cancer cases and 10 million deaths in 2020 alone. In the United States, cancer was the second leading cause of death after heart disease. One of the reasons that cancer is so frequently terminal is that cancerous cells frequently develop multidrug resistance (MDR) to frontline chemotherapeutical treatments, resulting in cancers cannot be treated and are inevitably fatal. This makes the discovery of ways to combat MDR so important in the treatment of cancer. The chrysosporazines are a family of recently discovered (2019) natural products that have …

Rooted In The Earth: An Igbo Sacramental Nature Of The Universe, A Model For Igbo Christian Ecological Ethics, Kenneth Oguzie

Electronic Theses and Dissertations

The contemporary Igbo society faces a lot of challenges. These include political, religious, and moral crises. These crises affect the environment in many ways. They threaten the peace and harmony of the Igbo society. As a result, it touches on faith. The Igbo society holds a holistic view of life. Whatever affects one aspect of life affects the other areas. Ecologically, various factors are responsible for the crises. These include changes in lifestyle from the traditional way of living to modern style of life with its penchant on consumerism. Also, colonialism and its lingering residues, civil unrests, politics, population growth, …

Biomaterials: From Scaffold Design To Implant Optimization, Jennifer Marie Armen

Electronic Theses and Dissertations

This work encompasses three individual projects concerning biomaterials and their modifications. Chemically-Induced Cross-Linking of Peptidic Fibrils for Scaffolding Polymeric Particles and Macrophages EAK16-II (EAK) is a self-assembling peptide (SAP) that forms β-sheets and βfibrils through ionic-complementary interactions at physiological ionic strengths. The soft materials can be injected in vivo, creating depots of drugs and cells for rendering pharmacological and biological actions. The scope of the applications of EAK is sought to extend to tissues through which the flow of extracellular fluid tends to be limited. In such anatomical locales the rate and extent of the fibrilization are limited insofar as …

Turbulent Transport Of Dissolved Oxygen In Natural Channels, Alanna Bachtlin

Electronic Theses and Dissertations

The transport and mixing of dissolved oxygen (DO) is important to replenish the oxygen depleted by natural processes; gas transfer in general has implications for ecosystem metabolism and greenhouse gas transfer. Currently, reaeration coefficients can be found through gas tracer methods, which estimates one-way gas transfer. For this project, a net oxygen consumption rate, , was developed using the similarity equations, which provides a value from DO and velocity profiles specific to a stream site. Additionally, three models to calculate friction velocity, which is required for oxygen consumption rate, were compared. Reynolds stresses, mathematically developed in the Reynolds-Averaged Navier-Stokes Equations, …

The Contribution Of Ethical Governance Of Artificial Intelligence & Machine Learning In Healthcare, Tina Nguyen

Electronic Theses and Dissertations

With the Internet Age and technology progressively advancing every year, the usage of Artificial Intelligence (AI) along with Machine Learning (ML) algorithms has only increased since its introduction to society. Specifically, in the healthcare field, AI/ML has proven to its end-users how beneficial its assistance has been. However, despite its effectiveness and efficiencies, AI/ML has also been under scrutiny due to its unethical outcomes. As a result of this, two polarizing views are typically debated when discussing AI/ML. One side believes that AI/ML usage should continue regardless of its unsureness, while the other side argues that this technology is too …

Into The Depths: Climate Change Part 4, Felicia Bedford

D.U.Quark

No abstract provided.

Into The Depths: Climate Change Part 3, Felicia Bedford

D.U.Quark

No abstract provided.