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Articles 1 - 30 of 68
Full-Text Articles in Entire DC Network
Nursing: The Career That Saves Lives [Career Paper], Maggie Flanagan
Nursing: The Career That Saves Lives [Career Paper], Maggie Flanagan
Undergraduate Research Award
No abstract provided.
Modeling Of Gas Production From Shale Reservoirs Considering Multiple Transport Mechanisms, Chaohua Guo, Mingzhen Wei, Hong Liu
Modeling Of Gas Production From Shale Reservoirs Considering Multiple Transport Mechanisms, Chaohua Guo, Mingzhen Wei, Hong Liu
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Gas transport in unconventional shale strata is a multi-mechanism-coupling process that is different from the process observed in conventional reservoirs. In micro fractures which are inborn or induced by hydraulic stimulation, viscous flow dominates. And gas surface diffusion and gas desorption should be further considered in organic nano pores. Also, the Klinkenberg effect should be considered when dealing with the gas transport problem. In addition, following two factors can play significant roles under certain circumstances but have not received enough attention in previous models. During pressure depletion, gas viscosity will change with Knudsen number; and pore radius will increase when …
Photochemistry Of A Series Of Weakly Coupled Dinuclear Ruthenium(Ii) Complexes, Latisha Michelle Puckett
Photochemistry Of A Series Of Weakly Coupled Dinuclear Ruthenium(Ii) Complexes, Latisha Michelle Puckett
Graduate Theses and Dissertations
An improved synthetic method was developed for symmetric ruthenium(II) polypyridine complexes with the form L2Ru(diphen)RuL2. The scope of the reaction was investigated in regards to the ligands, bridging ligands, and starting materials. Several ligands were successful in the synthesis, including 2,2’-bipyridine (bpy), 4,4’-dimethyl-2,2’-dipyridyl (dmb), 1,10-phenanthroline (phen), 4,7-diphenyl-1,10-phenanthroline (dpphen), and 3,4,7,8-tetramethyl-1,10-phenanthroline (tmphen). Ligands that did not react to form symmetric dimeric complexes were 2,2’-bipyrazine, bpz, and 2,2’-bipyrimidine, bpm.
Dpp, 2,3-bis(2-pyridyl)-pyrazine, effectively replaced diphen as the bridging ligand to produce (phen)2Ru(dpp)Ru(phen)24+. However, replacing the [Ru(CO)2Cl2]n with Ru(DMSO)4Cl2 did not prove successful. The newly developed synthesis was also applied to the synthesis of …
Interference-Free Gas-Phase Thermometry At Elevated Pressure Using Hybrid Femtosecond/Picosecond Rotational Coherent Anti- Stokes Raman Scattering, Joseph D. Miller, Chloe Elizabeth Dedic, Sukesh Roy, James R. Gord, Terrence R. Meyer
Interference-Free Gas-Phase Thermometry At Elevated Pressure Using Hybrid Femtosecond/Picosecond Rotational Coherent Anti- Stokes Raman Scattering, Joseph D. Miller, Chloe Elizabeth Dedic, Sukesh Roy, James R. Gord, Terrence R. Meyer
Terrence R Meyer
Rotational-level-dependent dephasing rates and nonresonant background can lead to significant uncertainties in coherent anti-Stokes Raman scattering (CARS) thermometry under high-pressure, lowtemperature conditions if the gas composition is unknown. Hybrid femtosecond/picosecond rotational CARS is employed to minimize or eliminate the influence of collisions and nonresonant background for accurate, frequency-domain thermometry at elevated pressure. The ability to ignore these interferences and achieve thermometric errors of <5% is demonstrated for N2 and O2 at pressures up to 15 atm. Beyond 15 atm, the effects of collisions cannot be ignored but can be minimized using a short probe delay (~6.5 ps) after Raman excitation, …
Chemistry And Biochemistry News, Georgia Southern University
Chemistry And Biochemistry News, Georgia Southern University
Department of Chemistry and Biochemistry News (2015-2023)
- Faculty members from Chemistry and Biology Department Recived a Sustainability Fee Grant
- Teaching Scholarship
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CEMITURE 2015- Research Experience for Undergraduates
College Of Science And Mathematics Newsletter, Fall 2015, College Of Science And Mathematics, Wright State University
College Of Science And Mathematics Newsletter, Fall 2015, College Of Science And Mathematics, Wright State University
College of Science and Mathematics Newsletters
This 6 page newsletter discusses various happenings within the College of Science and Mathematics. It begins with a letter from the dean, and continues on with news, events, alumni news, and other community news.
Chemistry Department Newsletter 2015, Ken Overway
Chemistry Department Newsletter 2015, Ken Overway
Chemistry Department Newsletters
This document contains a summary of news and events from the chemistry department from the 2014-2015 academic year.
The Periodical Fall 2015, Southern Adventist University
The Periodical Fall 2015, Southern Adventist University
the Periodical – Chemistry Department Newsletter
Volume 2, issue 2 of the Periodical includes articles about the Chemistry Department's partnership with Georgia-Cumberland Academy, a pictorial listing of December 2015 graduates, new service-learning tutoring classes, and an alumni spotlight.
Ambiguity In Speaking Chemistry And Other Stem Content: Educational Implications, Mick D. Isaacson, Michelle Michaels
Ambiguity In Speaking Chemistry And Other Stem Content: Educational Implications, Mick D. Isaacson, Michelle Michaels
Journal of Science Education for Students with Disabilities
Ambiguity in speech is a possible barrier to the acquisition of knowledge for students who have print disabilities (such as blindness, visual impairments, and some specific learning disabilities) and rely on auditory input for learning. Chemistry appears to have considerable potential for being spoken ambiguously and may be a barrier to accessing knowledge and to learning. Educators in chemistry may be unaware of, or have limited awareness of, potential ambiguity in speaking chemistry and may speak chemistry ambiguously to their students. One purpose of this paper is to increase awareness of potential ambiguity in speaking chemistry and other STEM fields …
Mining Public Databases For Discovery Of Structure And Function Within The Hotdog-Fold Thioesterase And Had Phosphatase Enzyme Families, Sarah Toews Keating
Mining Public Databases For Discovery Of Structure And Function Within The Hotdog-Fold Thioesterase And Had Phosphatase Enzyme Families, Sarah Toews Keating
Chemistry and Chemical Biology ETDs
For my doctoral work, I have developed strategies to mine public databases for data that can be used to infer structural and functional information for the hotdog-fold and HADSF superfamilies. For the hotdog-fold superfamily, I used curated and automatically applied annotations of structure, taxonomic lineage, function, and subfamily membership from the UniProtKB, gene context and taxonomic information from the NCBI, and the results of several in-depth explorations of subfamily/function and structural class membership. Based on the distribution of the aforementioned annotations mapped onto a sequence similarity network (SSN), I applied structural assignments to sequences and/or specific function/subfamily assignments to ~143,000 …
Metal-Ligand Cooperative Catalysis And Methods For Metal Removal From Organic Transformations, John-Paul J. Bow
Metal-Ligand Cooperative Catalysis And Methods For Metal Removal From Organic Transformations, John-Paul J. Bow
Electronic Thesis and Dissertation Repository
Organometallic catalysis has revolutionized the synthesis of complex organic molecules. Methods for C-C, C-X and C-H bond formation and cleavage are exploited throughout the areas of fine chemicals synthesis, with major applications for pharmaceuticals. This situation raises duel challenges: 1) high-performance catalysts for environmentally and economically sustainable synthesis and 2) efficient methods of catalyst (i.e. metal) removal must be identified. This work tackles both of these areas. The highly tunable cooperative PR2NR'2 ligands have been implemented for the first time for catalytic organic transformations. I show that [Ru(Cp)(PtBu2NBn2)(MeCN)][PF6 …
Chemistry Of The Protolunar Disk And Volatile Depletion Of The Moon, Channon Visscher, Robin M. Canup, Julien Salmon, Bruce Fegley Jr.
Chemistry Of The Protolunar Disk And Volatile Depletion Of The Moon, Channon Visscher, Robin M. Canup, Julien Salmon, Bruce Fegley Jr.
Faculty Work Comprehensive List
In the giant impact theory for lunar origin, the Moon forms from a circumterrestrial disk of silicate debris produced by the collision of a planetary-sized impactor with the early Earth. Recent accretion models suggest that the final 10-60% of the lunar mass may be provided by the accretion of melt material spreading outward from the inner (Roche-interior) disk over the first ~102 years following the giant impact. The chemical and thermal evolution of the inner disk material is thus expected to strongly influence the bulk chemical composition of the Moon.
In a previous study we explored the chemistry of the …
Morphology-Property Relationship For Binary Organic Thin Films, Alyssa Lynn Griffin
Morphology-Property Relationship For Binary Organic Thin Films, Alyssa Lynn Griffin
Master's Theses
Organic thin films can be readily mass-produced through solution-based fabrication methods including ink-printing and solution-casting because their light weight, flexibility, and inexpensive sources. Their applications range from organic field-effect transistors (OFET), organic solar cells (OSC), to organic light emitting diodes (OLEDs). Compared with pure component films, binary organic thin films (BOTF) allows for novel characteristics and specialized features to handle more demanding tasks. Due to the complex intermolecular interactions in BOTF, various microscopic phases with different morphological and electronic properties may be formed and this information is difficult to extract through conventional bulk measurements.
Organic thin films can be readily …
The Role Of Blowing Snow In The Activation Of Bromine Over First-Year Antarctic Sea Ice, R. M. Lieb-Lappen, R. W. Obbard
The Role Of Blowing Snow In The Activation Of Bromine Over First-Year Antarctic Sea Ice, R. M. Lieb-Lappen, R. W. Obbard
Dartmouth Scholarship
It is well known that during polar springtime halide sea salt ions, in particular Br-, are photochemically activated into reactive halogen species (e.g., Br and BrO), where they break down tropospheric ozone. This research investigated the role of blowing snow in transporting salts from the sea ice/snow surface into reactive bromine species in the air. At two different locations over first-year ice in the Ross Sea, Antarctica, collection baskets captured blowing snow at different heights. In addition, sea ice cores and surface snow samples were collected throughout the month-long campaign. Over this time, sea ice and surface snow …
Investigation Of Irrigation Water Quality Of Surface And Groundwater In The Kütahya Plain, Turkey, Berihu Abadi Berhe, Mehmet Çeli̇k, Uğur Erdem Dokuz
Investigation Of Irrigation Water Quality Of Surface And Groundwater In The Kütahya Plain, Turkey, Berihu Abadi Berhe, Mehmet Çeli̇k, Uğur Erdem Dokuz
Bulletin of the Mineral Research and Exploration
The Kütahya plain is one of the plains in Kütahya/Turkey, where drinking, agricultural and industrial water supplies are highly dependent on groundwater resources. The local population largely depends on water from alluvial shallow aquifer waters and some on the Felent and Porsuk rivers. Appraisal of surface and groundwater quality is extremely important to make sure the sustainable use of it for drinking, agricultural, and industrial purposes. The chemical quality of surface and groundwater of Kütahya plain has been studied in detail in order to have better understanding of potential water quality. A total of 21 groundwater samples and 6 surface …
Study Of Displacement Efficiency And Flow Behavior Of Foamed Gel In Non-Homogeneous Porous Media, Yanling Wang, Jiafeng Jin, Baojun Bai, Mingzhen Wei
Study Of Displacement Efficiency And Flow Behavior Of Foamed Gel In Non-Homogeneous Porous Media, Yanling Wang, Jiafeng Jin, Baojun Bai, Mingzhen Wei
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Field trials have demonstrated that foamed gel is a very cost-effective technology for profile modification and water shut-off. However, the mechanisms of profile modification and flow behavior of foamed gel in non-homogeneous porous media are not yet well understood. In order to investigate these mechanisms and the interactions between foamed gel and oil in porous media, coreflooding and pore-scale visualization waterflooding experiments were performed in the laboratory. The results of the coreflooding experiment in non-homogeneous porous media showed that the displacement efficiency improved by approximately 30% after injecting a 0.3 pore volume of foamed gel, and was proportional to the …
Change At The Core: An Initial Implementation Of Active Learning Strategies In Large, Lecture Science Courses, Travis Salmi
Change At The Core: An Initial Implementation Of Active Learning Strategies In Large, Lecture Science Courses, Travis Salmi
Scholars Week
Change at the Core (C-Core) is a faculty professional development program designed to investigate and employ the benefits of student focused learning in introductory science courses. It is a multidisciplinary effort among science educators at three higher education institutions to understand different possible learning strategy implementations. We are using case studies to investigate these implementations, the challenges involved, and the student responses to these approaches. Previous research has shown that students respond with greater learning outcomes towards alternatives to lectures. Data are being collected through classroom observations, student surveys, and faculty interviews. So far, we have observed a range of …
Removal Of Pb And H2s From Acs Test Procedure For Meta-Phosphoric Acid, Christopher Atlas, Ron Lacock
Removal Of Pb And H2s From Acs Test Procedure For Meta-Phosphoric Acid, Christopher Atlas, Ron Lacock
Student Scholar Symposium Abstracts and Posters
In the pursuit of green chemistry, adequate substitutes for lead acetate and hydrogen sulfide were investigated for use in the ACS test procedure for stabilizer in meta-phosphoric acid. In the current ACS procedure lead acetate is used to form insoluble lead phosphate. In order to remove lead from the solution lanthanum chloride was investigated with positive results. Hydrogen Sulfide is currently used to precipitate lead by forming insoluble lead sulfide. Several substitutes including oxalic acid and sulfuric acid were investigated. Preliminary testing showed that lanthanum chloride and oxalic acid are sufficient in precipitating phosphate and lead out of the sample …
Relative Reaction Rates Of The Amino Acids Cysteine, Methionine, And Histidine With Analogs Of The Anti-Cancer Drug Cisplatin, Cynthia A. Tope
Relative Reaction Rates Of The Amino Acids Cysteine, Methionine, And Histidine With Analogs Of The Anti-Cancer Drug Cisplatin, Cynthia A. Tope
Mahurin Honors College Capstone Experience/Thesis Projects
We are studying the reaction of analogs of the anticancer drug cisplatin with amino acids that differ in size and shape. The reaction of cisplatin with proteins likely precedes reaction with DNA in the body, forming a variety of products that may be toxic to the human body. The size and shape of the platinum(II) complexes often affects the rate of reaction with proteins, more so than with DNA. In this study, triamine cisplatin analogs are reacted with the amino acids cysteine, methionine, and histidine simultaneously. These reactions are monitored by NMR spectroscopy. The effect of the bulk of the …
Impact Of Ocean Acidification On Aphotic Biogeochemical Production Of Reactive Oxygen Species, Sarah Ann Murphy
Impact Of Ocean Acidification On Aphotic Biogeochemical Production Of Reactive Oxygen Species, Sarah Ann Murphy
Theses and Dissertations
Reactive oxygen species (ROS) are critical to global maintenance of the global organic carbon cycle, sulfur cycle, oxygen cycle, and transition metal cycles. The primary source of ROS is commonly considered to be photolysis or photochemically driven reactions, however ROS also exist in aphotic zones. A geochemical mechanism for the same in dark environments based on the tidally driven, episodic movement of anoxic groundwaters through oxidized, Fe(III) rich sediments is shown. Predictive models were developed based on in vitro experiments and tested using sediment samples collected from a saline tidal creek in the estuary at Murrell’s Inlet, South Carolina. These …
Facile Method For Large Scale Alignment Of One Dimensional Nanoparticles And Its Biomedical Application, Sheng Feng
Facile Method For Large Scale Alignment Of One Dimensional Nanoparticles And Its Biomedical Application, Sheng Feng
Theses and Dissertations
Topographical cues can profoundly affect cellular behaviors. This thesis investigate how to utilize the topographical cues generated by two techniques, flow assembly and electrospinning, to regulate cellular behaviors.
First of all, a facile and robust method to align one-dimensional (1D) nanoparticles (NPs) in large scale has been developed. Using flow assembly, representative rod-like nanoparticles, including tobacco mosaic virus (TMV), gold nanorods and bacteriophage M13, have been aligned inside capillaries by controlling flow rate and substrate surface properties. The properties of 1D NPs, such as stiffness and aspect ratio, play a critical role in the alignment. Furthermore, these hierarchically organized structures …
Metals On Titania/Hopg As Models For Heterogeneous Catalysts, Randima Piyumalie Galhenage
Metals On Titania/Hopg As Models For Heterogeneous Catalysts, Randima Piyumalie Galhenage
Theses and Dissertations
The work done in this thesis is mainly focused on understanding the nanoscale morphology and activity of model heterogeneous catalysts. In order to do this we design and prepare model catalytic surfaces in ultrahigh vacuum (UHV) and study these surfaces using electron and ion based microscopies and spectroscopies. The nucleation, growth and chemical activity of mono and bimetallic clusters on TiO2(110) were investigated in order to understand how activity is influenced by cluster sizes, interactions with the oxide support and surface compositions of the bimetallic clusters. For example, Au-based and Pt-based bimetallic clusters such as Co-Au, Co-Pt, and …
Methodology Development In Green Chemistry: Oxoammonium Salt Oxidations And Fluoroform Incorporation, Rebecca J. Wiles
Methodology Development In Green Chemistry: Oxoammonium Salt Oxidations And Fluoroform Incorporation, Rebecca J. Wiles
University Scholar Projects
Central to the advancement of small molecule synthesis is the ability to develop methodologies that reimagine well known chemistry in a new, environmentally friendly manner. In this thesis two central themes emerge: oxoammonium salt oxidations and trifluoromethyl incorporation using fluoroform gas. Several projects have been developed surrounding oxoammonium salt chemistry, which are featured by their mild conditions, ease of use, and the metal-free, recyclable nature of the oxidant. Trifluoromethylation using fluoroform gas finds its utility in the use of a potent greenhouse gas waste product as a benchtop reagent.
Methodology Development In Green Chemistry: Oxoammonium Salt Oxidations And Fluoroform Incorporation, Rebecca J. Wiles
Methodology Development In Green Chemistry: Oxoammonium Salt Oxidations And Fluoroform Incorporation, Rebecca J. Wiles
Honors Scholar Theses
Central to the advancement of small molecule synthesis is the ability to develop methodologies that reimagine well known chemistry in a new, environmentally friendly manner. In this thesis two central themes emerge: oxoammonium salt oxidations and trifluoromethyl incorporation using fluoroform gas. Several projects have been developed surrounding oxoammonium salt chemistry, which are featured by their mild conditions, ease of use, and the metal-free, recyclable nature of the oxidant. Trifluoromethylation using fluoroform gas finds its utility in the use of a potent greenhouse gas waste product as a benchtop reagent.
Chemistry And Biochemistry News, Georgia Southern University
Chemistry And Biochemistry News, Georgia Southern University
Department of Chemistry and Biochemistry News (2015-2023)
- Chemistry Students Make a Splash at GSU Research Symposium
Learning Chemistry Through Experimentation, Brent Kamba `, Dr. Jennifer Nielson
Learning Chemistry Through Experimentation, Brent Kamba `, Dr. Jennifer Nielson
Journal of Undergraduate Research
There is a great need for students to learn scientific skills in Uganda. Very few students pass the national chemistry exams (about 40%) and even fewer go on to study science fields in higher education. The teaching methods in Uganda are a little bit old fashion where students often just learn facts and practise rote memorization. Rarely do they develop the critical and analytical skills to help them succeed in science jobs. Teachers also express that the curriculum is very theoretical, and not experimental.
Microbial Communities Of The Providence River, Jacqueline Kratch
Microbial Communities Of The Providence River, Jacqueline Kratch
Honors Projects in Science and Technology
The Providence River has been industrialized for over one-hundred years. Industries such as oil storage and metal recycling facilities have left high levels of pollutant metals, including lead (Pb), in the soil and water. The elevated Pb concentrations in these environments influence the selection of Pb resistance mechanisms in the bacterial community1. One mechanism of heavy metal resistance is the Pb efflux pump, consisting of proteins in the cell membrane that aid in the transport of Pb out of the cell2. In this study we investigated the co-occurrence of Pb efflux pumps and antibiotic efflux pumps in bacteria from Pb …
Chemistry And Biochemistry News, Georgia Southern University
Chemistry And Biochemistry News, Georgia Southern University
Department of Chemistry and Biochemistry News (2015-2023)
- Eagles Fly to Denver for Chemistry Presentations
Assessment Of Silk Degradation Using Pyrolysis, Conor Makepeace
Assessment Of Silk Degradation Using Pyrolysis, Conor Makepeace
Honors Projects in Science and Technology
The purpose of this research is to investigate the molecular constitution of silk and the specific causes of post-production degradation in silk material. This capstone project focused specifically on the conditions and degradation of ancient Chinese silk products provided by the Chinese National Silk Museum. Modern silk products were artificially degraded and compared to the ancient silk using Py-GC-MS and comparative analytic techniques. This investigation revealed that the ancient silk products most likely underwent degradation in elevated temperatures while in the presence of moisture and the absence of sunlight or UV radiation during long term burial.
A Comparison Of Student Perceptions To Actual Performance In Chemistry, Ross Hudson
A Comparison Of Student Perceptions To Actual Performance In Chemistry, Ross Hudson
Dr Ross Hudson
This research was part of a larger study into student performance in senior chemistry with regard to question type and content. This paper examines student perceptions about question type and context and compares these perceptions to actual performance. How students perceive different types of questions and how it influences their self-belief and motivation were the focus of this study. Student responses to different styles or types of questions have been well researched over time. In this study Year 11 chemistry students were quizzed about their preferences to Multiple-Choice questions and Open Response question types and how the presence of each …