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Ua66/7/2 Newsletter, Wku Chemistry

WKU Archives Records

Newsletter created by and about the WKU Chemistry department.

Mössbauer Properties Of Synthetic Analogs Of Active Sites Of The Iron-Sulfur Proteins, Richard B. Frankel, B. A. Averill, R. H. Holm

Physics

Mössbauer spectroscopy of the synthetic tetramers [Fe₄S₄(SR)₄]^2- (R = alkyl, aryl) and the corresponding trianions obtained by one-electron reduction, when compared with available data for 4-Fe and 8-Fe iron-sulfur proteins, shows that these tetramers are electronic analogs of the active sites of the proteins.

Methyl Proton Nmr Shifts Of Coordinated Methanol In A Series Of Co(Ch,0h),X2+ Compounds, J.R Vriesenga, Jerry Goodisman

Chemistry - All Scholarship

The isotropic contact NMR shifts of the coordinated cis and tram methanol methyl proton resonances of a series of Co(CH30H)5X2+ complexes were measured, where the ligand X was pyridine, /I- and a-picoline, DMF, DMSO, acetonitrile, and water. The question of how to separate the observed shifts into their respective Fermi contact and dipolar (pseudocontact) contributions was examined in detail with the result that a new procedure for carrying out the separation was proposed. The dipolar shifts for these complexes were found to vary widely, with the acetonitrile complex exhibiting the largest dipolar shift. For the DMSO and water complexes the …

An Experimental Investigation Of Highly Undercooled Magnesium Silicate Chondrule-Like Spherules, Harry Nicholas Planner

Earth and Planetary Sciences ETDs

A series of experiments, involving molten magnesium silicate spherules that were subjected to high initial cooling rates and allowed to nucleate at high temperatures (985-1350°C), were performed so as to compare their thermal histories to the resulting internal features. Such comparisons could be used to decipher the thermal history of chondrules and the conditions surrounding their formation based on their mineralogy, crystal morphology, and overall texture. Various features of the spherules were correlated with the initial high cooling rate process, nucleation temperature, and the maximum temperature attained during the recalescance to demonstrate the restrictions resulting from or their sensitivities to …

Geochemistry And Petrology Of The Orbicular Rocks, Sandia Mountains, New Mexico, Robert David Enz

Earth and Planetary Sciences ETDs

Orbicular rock located on the west side of the Sandia Mountains, New Mexico, at W. long. 106° 29' 30", N. lat. 35° 13' 04", was first reported by Fitzsimmons (1966). Recently Thompson and Giles (1974) published a paper describing.three types of orbicular rock in the locality which they believed to have been formed by a metasomatic process. Without knowledge of the work of Thompson and Giles, this thesis was initiated as a detailed field, petrographic, geochemical and geochronologic study of these orbicular rocks.

Four types of orbicular rock, including another previously unreported occurrence of orbicular granite about 2 km north …

Kinectics Of The Ground State Transformation In Fe(Ii) (N, N -Dicyclohexylthiourea)6(Cio4)2, R. Latorre, J. A. Costamagna, E. Frank, C. R. Abeledo, Richard B. Frankel

Physics

The high spin complex Fe(II) (N, N'-dicyclohexylthiourea)₆(ClO₄)₆ exists in two forms which only differ in the distortion from octahedral symmetry of the environment of the Fe ion. Thermodynamic data for the transformation from one form to the other as obtained from Mössbauer spectroscopy are presented and a method to derive kinetic parameters is described.

Amphicyon Major Blainville Discovered In The Middle Miocene Beds Of Çandir, Mustafa Gürbüz

Bulletin of the Mineral Research and Exploration

No abstract provided.

Vertebres Fossiles Recemment Decouverts En Turquie Et Leurs Gisements, İbrahim Tekkaya

Bulletin of the Mineral Research and Exploration

No abstract provided.

Beitrag Zur Kenntnis Der Geologie Des Oligozäns Von Mittelthrakien (Türkei), Richard F. Lebküchner

Bulletin of the Mineral Research and Exploration

No abstract provided.

Geology Of The Çandir (Kaleci̇k) Area, Şuayip Üşenmez

Bulletin of the Mineral Research and Exploration

No abstract provided.

Premiers Resultats Des Fouilles Effectuees A Çalta, Ankara, Turquie, Şevket Şen, Emile Heintz, Leonard Gi̇nsburg

Bulletin of the Mineral Research and Exploration

No abstract provided.

Etudes Palynologiques Des Veines Du Namurien Et Du Westphalien A, Recoupees Par Les Ailes Sud Et Est D'Une Galerie De Cote —50 A Asma, Üzülmez-Zonguldak, Erol Akyol

Bulletin of the Mineral Research and Exploration

No abstract provided.

Bakir İzabesi̇nde Çi̇nko Problemi̇ Ve Bu Açidan Kompleks Bakir-Çi̇nko Sülfürlü Cevherleri̇n Değerlendi̇ri̇lme İmkânlari, Fuat Yavuz Bor

Bulletin of the Mineral Research and Exploration

No abstract provided.

The Ophiolitic Series Of Turkey*, Nuriye Pinar-Erdem

Bulletin of the Mineral Research and Exploration

No abstract provided.

Discussions On The Metamorphic Map Of Turkey In A Scale Of 1:2,500,000 And Geotectonic Evolution Of Some Metamorphic Belts, Ergüzer Bi̇ngöl

Bulletin of the Mineral Research and Exploration

No abstract provided.

Ultrabasic Tectonites And Layered Peridotites Of The Hatay Area (Turkey), H. Ersen Çoğulu

Bulletin of the Mineral Research and Exploration

No abstract provided.

Deni̇zli̇ Bölgesi̇ Neojeni̇ni̇n Paleontoloji̇k Ve Strati̇grafi̇k Etüdü*, Güler Taner

Bulletin of the Mineral Research and Exploration

No abstract provided.

A New Species Of Tortonian Anthropoid (Primates, Mammalia) From Anatolia, İbrahim Tekkaya

Bulletin of the Mineral Research and Exploration

No abstract provided.

Distribution-Free Interval Estimation Of The Largest Α-Quantile, William E. Plouff

Masters Theses

No abstract provided.

Public Access To The Beaches Of Connecticut, Don W. Oswalt

Theses and Major Papers

Elements of the public of Connecticut are engaged in direct conflict against private and municipal property rights over the issue of increased public access to beaches of the state. In Connecticut, as well as the nation, definite solutions to the problem are slow to materialize. The public's right to the whole beach is being clarified by only a few states, while public access under common law remains a clouded issue nationwide. The research study I am proposing would examine in detail the legal issues involved, the state and federal legislative actions, geographical considerations, etc. I feel that the resulting collation …

On The Benefactive Feature In Transitivity, Dale Ellen Gaucas

Electrical Engineering and Computer Science - Technical Reports

An elaboration on the transitivity system network introduced by M. A. K. Halliday is developed. This extension consists of a separate feature system network for the participant role of “beneficiary”. The formulation of the proposed grammar rules to conjoin this network and Halliday's is facilitated by building up the transitivity network to describe "systemically” and uniquely each type of benefactive and range clause presented by Halliday. Systemic descriptions of these clauses are given as examples throughout the discussion.

The Algorithm Selection Problem Iii - Approximation Theory Machinery, John R. Rice

Department of Computer Science Technical Reports

No abstract provided.

Antithesis In Physical Science, Russell W. Maatman

Pro Rege

No abstract provided.

Christian Astronomy Vs. Secular Astronomy, Richard G. Hodgson

Pro Rege

No abstract provided.

Geology Of Klump's Cave, Perry County, Missouri, Ernest L. Kern

Masters Theses

No abstract provided.

Spin-Flip In 12C (P,P') 12C Near The 9.14 Mev Doublet, John Ambani Muhanji

Masters Theses

No abstract provided.

Development And Preliminary Application Of Mathematical Models To The Weber Basin, W. J. Grenney, D. S. Bowles, M. D. Chambers, J. P. Riley

Reports

The adoption of stream standards, whether for direct application or for the establishment of realistic effluent standards, creates a need to predict the impact of pollution loads on river water quality during critical flow periods or as the result of future user demands. Because of the complexity of aquatic systems, mathematical models are an excellent medium for bringing together the state-of-the-art knowledge from a variety of disciplines into a form which can be readily applied to practical problems. Applying a mathematical model to a river system has the added advantage of providing a structure for the systematic consideration of the …

Geology Of The Northern Part Of The Sierra Cuchillo, Socorro And Sierra Counties, New Mexico, Florian Maldonado

Earth and Planetary Sciences ETDs

The northern Sierra Cuchillo, Socorro and Sierra Counties, New Mexico is approximately 32 miles northwest of Truth or Consequences, New Mexico. The Sierra Cuchillo is a narrow fault-block range in the Basin-Range province and is a structurally high element west of the Rio Grande trough. It is bordered on the west by the Winston graben and the Black Range and on the east by Monticello graben and the San Mateo Mountains.

Permian rocks consist of the Yeso and San Andres Formation, with an aggregate thickness of 2100 ft (640 m). Upper Cretaceous rocks, 40 ft (10 m) thick, consist of …

Asymmetric Induction In Grignard Reactions In A Chiral Solvent, John E. Davis

Dissertations

No abstract provided.

Models For Estimating Psychiatric Bed Needs, Patricia A. Brenneman

Loma Linda University Electronic Theses, Dissertations & Projects

Inland Counties Comprehensive Health Planning Council wished to estimate the psychiatric bed needs by type (such as state hospitals, board and care homes, etc.) in San Bernardino County from the distributions of patient arrivals and of lengths of stay. A statistical description of the system during 1973 was considered the first step toward estimating future bed needs. A computer simulation model using IBM's programming language General Purpose Simulation System (GPSS) was developed and was found to be unsatisfactory.

Theorems were then developed for a statistical model, seeking to predict future bed needs. The most convenient of these theorems states that …