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Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky
Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky
Theses and Dissertations
Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …
Biochar Applications To The Remediation Of Lead And Polychlorinated Biphenyl Contaminated Water, Victory Itua Igberase
Biochar Applications To The Remediation Of Lead And Polychlorinated Biphenyl Contaminated Water, Victory Itua Igberase
Theses and Dissertations
This study investigated the performance of biochar materials as adsorbents to remove Pb and polychlorinated biphenyl (PCB) in aqueous solutions. Batch adsorption and column experiment packed with biochar and geomaterials (pumice) in 1:1 volume ratio was evaluated to address the efficacy of biochar in removing Pb while only batch adsorption was employed for PCB removal with biochar materials. Overall, PT biochars performed the best (42–53 mg g−1) followed by BE biochars (10–32 mg g−1) and AB biochars (17–27 mg g−1) while high temperature biochars were favored in terms of maximum Pb adsorption capacity. Column Pb breakthrough showed similar results, with …
A Speciation Modeling Study Of Heavy Metal Adsorption To Plastic In Municipal Wastewater Treatment Plant Units, Kaitlyn Hague
A Speciation Modeling Study Of Heavy Metal Adsorption To Plastic In Municipal Wastewater Treatment Plant Units, Kaitlyn Hague
Electronic Theses and Dissertations
Microplastics are an emerging concern due to their harmful effect to organisms and their ability to facilitate transport of contaminants including heavy metals. Microplastics can enter the environment through wastewater treatment plants, landfill leachate, and littering. Once in the environment microplastics can be distributed throughout rivers, the ocean, and lakes. In order to understand the adsorption of heavy metals to microplastics a geochemical modeling study was completed using Visual Minteq. Lab tests were completed to better understand what constituents are available in wastewater at four different locations: influent, clarifiers, digesters, and effluent. These constituents were then used to observe how …