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Recent Discoveries In The Ni-Cu-Pge Bearing Trill And Parkin Offset Dykes, Sudbury Impact Structure, Canada, Adam B. Coulter

Electronic Thesis and Dissertation Repository

The Sudbury structure hosts world class Ni-Cu-PGE deposits that have been mined, explored and studied for over 130 years. The structure is widely recognized as the erosional remnant of a 1.85 Ga 200- to 250-km tectonically altered multi-ring impact basin located in central Ontario, Canada. The focus of this investigation is on the Trill and Parkin Offset dykes. This study provides updated regional scale geologic maps, detailed geologic maps of newly exposed sections, geochemistry, sulphide analysis and an analysis of the inclusion population and orientation within the dykes. We conclude, the dyke phases display remarkable geochemical homogeneity, the Ni-Cu-PGE mineralization …

Thermodynamic Modeling Of Aqueous Geochemistry Of Chlorine Salts: Application To Stability And Habitability Of Liquid Brines On Mars, Amira Elsenousy

Graduate Theses and Dissertations

The WCL (Wet Chemistry Lab) instrument on board the Mars’s Phoenix Lander has identified the soluble ionic composition of the soil at the landing site. Two important ions were detected at the landing site; perchlorates (ClO4-) with a concentration of ~ 2.4 wt% and chlorides (Cl-) with a concentration of 0.54 wt%. Between chloride and perchlorate ions three other oxidized ions exist and called chlorine ions: hypochlorite ClO - (ox. state +1), chlorite ClO2- (ox. state +3) and chlorate ClO3- (ox. state +5). These oxidized ions might be existed as intermediate species on the surface of Mars but remained undetected. …

Predictive Modeling Of Terrestrial Radiation Exposure From Geologic Materials, Daniel A. Haber

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys are an important tool for national security, scientific, and industrial interests in determining locations of both anthropogenic and natural sources of radioactivity. There is a relationship between radioactivity and geology and in the past this relationship has been used to predict geology from an aerial survey. The purpose of this project

is to develop a method to predict the radiologic exposure rate of the geologic materials in an area by creating a model using geologic data, images from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), geochemical data, and pre-existing low spatial resolution aerial surveys …

Examination Of Banded Iron Formation Through Petrographic, Geochemical And Iron Isotope Analyses, Melissa Margaret Hage

Doctoral Dissertations

Banded iron formation (BIF) has the potential to preserve geochemical signatures critical to interpretation of early Earth because: (1) it is found within the Precambrian when fundamental changes in Earth’s physical, biological and chemical evolution occurred, and (2) it may preserve a record of the depositional environment. Rare earth elements (REE) are useful for investigating BIF because they have characteristic features. One goal of this study was to evaluate the calculation of certain REE ratios to determine if the calculation affected the interpretation. It was concluded that the method for calculating certain ratios may affect the interpretation of redox conditions …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Sequence Stratigraphy, Depositional Environments And Geochemistry Of The Middle Cambrian Bloomington Formation In Northern Utah, Christopher Ryan Jensen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Bloomington Formation (~425 m thick) is a latest Middle Cambrian (~506.5-505 Ma.), mixed warm water, carbonate and shale unit on the Cordilleran passive margin in northern Utah and southern Idaho. The Hodges Shale and Calls Fort Shale Members are shale dominated and the Middle Limestone Member is a thick carbonate. Fossil diversity and abundance is surprisingly low for a Middle Cambrian carbonate/shale formation. Present, however, are 10-50 cm thrombolite mud mounds, associated with Girvanella oncoliths. These mud mounds represent shallow water carbonates that experienced a small flooding event that gives the mud mounds time and proper conditions to build …

Paleoredox Geochemistry And Bioturbation Levels Of The Exceptionally Preserved Early Cambrian Indian Springs Biota, Poleta Formation, Nevada, Usa, Jonah Meron Novek

Theses and Dissertations

The early Cambrian Indian Springs biota, western Nevada, USA exhibits Burgess Shale-type (BST) preservation of a diverse array of animal phyla, including the earliest definitive echinoderms. It therefore provides an important window on animal life during the Cambrian radiation. The objective of this study is to analyze the trace metal paleoredox geochemistry and bioturbation levels of this BST deposit in order to characterize the paleoenvironmental conditions in which these animals lived and their fossils were preserved. A total of 28 rock samples were collected from outcrops at three previously reported intervals of exceptional preservation at the Indian Springs locality, as …

Modeling Background Radiation Using Geochemical Data, Kara Marsac

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys have many applications in geology and science in general, such as locating mining prospects, defining radioactive plumes, and detecting nuclear weapons. Unfortunately there is currently no simple way to separate the natural gamma radiation of soil and rocks from that of contaminants such as radioactive plumes. This project used geochemical data (uranium, potassium and thorium concentrations) collected from national databases, private companies, and the NURE (National Uranium Resource Evaluation) Survey, to create forward models of exposure rates measured by aerial gamma ray surveys. We developed these techniques using an area in north central Arizona known as …

Effects Of Physical Characteristics Of Urban Storm Sewersheds On Water Quality In Bloomington, Il, Alicia Terese O'Hare

Theses and Dissertations

Increasing urbanization has consequences for surface water quality. Stormwater is a large component of urban water degradation that is poorly understood. Precipitation is quickly transported via underground pipes, from the land to the stream without following water's natural flow path. Studies have correlated detention ponds with improved water quality and impervious surface cover with degraded water quality. However, other physical characteristics within a storm sewer shed including the presence of sump pumps, area and pipe miles may also affect the stormwater quality. We chose 18 storm sewer systems in Bloomington, IL. We measured pH, temperature, conductivity, dissolved oxygen, chloride, nitrate, …

Augite In Komatiitic Basalts: A Study Of The Mobility Of Trace Elements During Rock Alteration, Alesha C. Morabito

LSU Master's Theses

Komatiitic basalts are ultramafic rocks formed from volcanic liquids containing less than 18 wt.% magnesium oxide that can be linked, spatially, geochemically and texturally to komatiites. Archean komatiites and komatiitic basalts are critical to models of early Earth’s mantle evolution. Major and trace elements in these rocks are poorly preserved due to early sub-seafloor alteration with superimposed regional metamorphism: in particular the alkali, alkaline earths, and other elements with low valence numbers. Current analytical methods focus on analyzing whole rock, fresh olivines and melt inclusions to evaluate elemental concentrations and for petrogenetic studies. Although these methods establish elemental concentrations, REE, …

Rare Earth Element Patterns In Conodont Apatite From The Upper Ordovician: Testing Enrichment Sources And Possible Oceanographic Changes, Cody Christian Schulte

LSU Master's Theses

The Mohawkian series of the Middle Late Ordovician was a time of great lithological and faunal changes that coincide with a positive ä13C excursion known as the Guttenberg Isotopic Carbon Excursion (GICE). Two prevailing hypotheses have been proposed to explain the cause of these changes. The “cold-water” hypothesis suggests that global cooling caused the tropical belt to shrink and cold water to invade the epicontinental sea while the “tectonic-forcing” hypothesis suggests that increased weathering rates led to basinal deepening, resulting in cooler oceanic waters invading the midcontinent sea. This study tests if regional tectonics caused by the Taconic Orogeny led …

Tracing Sediment In The Subsurface Using Beryllium-7: Green River Basin, Ky, Caroline Adams Broderick

LSU Master's Theses

As water flows through areas of limestone, karst inevitably develops, creating sinking streams and sinkholes that transport alumino-silicate particles from the surface into the subsurface. Sediment budget studies on short term scales through karst are rare. Thus, a feasibility study using beryllium-7 (7Be), which attaches to soil particles and can be used as a short-term (2-3 month) tracer of the movement of fine-grained sediment in karst was investigated. Sediment samples were collected from a karstic catchment within Green River basin, Kentucky, both on the surface and in the subsurface along a cave stream. Samples were collected prior to and immediately …

The Champlain Sea/Lake Champlain Transition Recorded In The Northeast Arm Of Lake Champlain, Usa-Canada, Ashliegh Theresa Belrose

Graduate College Dissertations and Theses

Sediment accumulated on a lakebed archives information about past climate and changes in the regional environment. Previous studies (Burgess, 2007; Koff, 2011; Palmer, 2012) in the Northeast Arm of Lake Champlain, specifically Missisquoi Bay and Saint Albans Bay, showed a period (~9,400 - 8,600 yBP) of elevated organic matter deposition in both bays, indicating a productive event that pre-dated any possible anthropogenic influence. However, the record was abruptly cut off and any documentation representing the span of time leading up to this event was not found. The elevated organic matter levels were explained as being the result of a warm, …

Accelerated Degradation Of Chlorinated Solvents By Copper-Modified Nanoscale Zero Valent Iron (Cu-Nzvi) Stabilized With Carboxymethyl Cellulose, Andrew Franze

Browse all Theses and Dissertations

Nanoscale zero valent iron (nZVI) is a remediation technology that can be used to treat chlorinated hydrocarbons (CHCs) in contaminated aquifers. Nanoparticles remain mobile in water and can be transported with groundwater flow to contaminated zones. However, due to magnetic and van der Waals forces, unstabilized nZVI agglomerates. Carboxymethylcellulose (CMC) was used as a polyelectrolyte stabilizer in this study. nZVI serves as an electron donor and can dechlorinate CHCs. nZVI reactivity with CHCs can be enhanced by addition of a secondary metal catalyst. This study evaluates the potential of copper amended nZVI (Cu-nZVI) to degrade select CHCs. The objective of …

Interpretation Of Geochemical Signatures From Modern Carbonate Springs To The Rock Record, Benjamin Maas

LSU Doctoral Dissertations

Despite the importance of carbonate aquifers as reservoirs of oil, of water, and of carbon dioxide, questions remain about the diagenetic processes that enhance porosity and permeability. Some of the questions are: 1) what are the water-rock interactions that control the geochemistry of spring waters; 2) are the geochemical signatures of saline-fresh water mixing zones preserved in the carbonate rock record; and 3) how much carbon dioxide outgases along spring runs? To address these questions, two field sites, one in Oklahoma (the site of an active saline-fresh water mixing zone) and the other in Colorado, the location of a former …