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Phase Shift Analysis Of Protons Elastically Scattered By 016 Near EP = 8.3 Mev, Glenn D. Westin

Masters Theses

Chapter I

Introduction

The study of the resonances in the scattering cross section of the p + O¹⁶ reaction can reveal information regarding the energy levels of the compound nucleus F¹⁷. The analysis is simplified because of the zero spin of the O¹⁶ nucleus. Also, the low binding energy of the proton added to O¹⁶ allows examination of the low-lying energy levels in F¹⁷.¹ The reaction has been intensively investigated at the University of Wisconsin in a series of experiments using an electrostatic accelerator as a source of protons.

The Calculation Of The Cross-Section Of The Interaction Between Two Yang-Mills Fields, Richard A. Starr

Masters Theses

The Problem and Its Background

This thesis presents a study of the interaction between two arbitrary fields, named Yang-Mills fields¹ for their originators. The basic equations for the calculations of the Yang-Mills interaction are due to modern quantum field theory and its specific application to quantum electrodynamics.²

Much useful information can be obtained from the formulation of the dynamical equations for a classical system: for example, the classical description of the electromagnetic field, based on Maxwell's equations, leads to wave concepts. Then using this formalism as a starting point, one can proceed to the quantum theory of free …

The Preparation Of 5-Arylazopyrimidines, Frederic Edwin Dutton

Masters Theses

Introduction

The synthesis of 5-arylazopyrimidines was undertaken in search of potential anticancer agents.

While many azo compounds have carcinogenic activity, it has been shown by several workers in this area that some 5-arylazopyrimidines have anticancer properties. S. Hibino(1) has shown that p-(2,4,6-triamino-5-pyrimidinylazo) benzene-sulfonic acid shows promise as an effective anticancer agent when used in conjunction with 6-mercaptopurine and adrenal steroidal hormones. When tested clinically, total remission of the leukemic process was achieved in 85.7% of the cases treated. In comparison, total remission was achieved in only 57.5% of the cases treated with a mixture of 6-MP and the hormone which …

Plant-Derived Pigments And Dyes Used By Artists, Samuel C. Rizzetta

Masters Theses

History

Uses of Biologically-derived Products in Painting

Throughout history man has relied heavily on plant-derived materials in the production of paintings. Plant products have been used to fulfill each of the material requirements of painting. The ground or surface upon which an artist applies paint -is usually of plant origin, such as woven fabrics and paper. The ancient Egyptians painted on canvas (from Linum usitatissimum L.), papyrus, (from Cyperus papyrus L.), and wood (Lucas, 1934:149-150, 201-203; Laurie, 1910:17, 31-32).

At the time of Theophilus leather parchment, preferably of horsehide, was popular for painting (Bazzi, 1960:13). After parchment, walls and wooden …

The Reaction Of Metal Hydrides With Azoacetates, Thomas H. Althuis

Masters Theses

Introduction

The term aliphatic azo compound refers to those azo compounds in which at least one of the two nitrogen atoms is linked to a tetrahedral, that is, sp³ -hybridized carbon atom. Di-imides, RN=NH, however, are not being considered. Mixed aliphatic-aromatic azo compounds are those in which one nitrogen atom is linked to an sp³ -hybridized carbon atom and the other to an aromatic sp² -hybridized carbon atom. If present, a symmetry element (point or plane) is determined by the mid-point between the two nitrogen atoms.

Study Of The Stereochemistry Of A Carbanion Generated From An Azoacetate, Nguyen Thanh Buu

Masters Theses

Introduction

The reaction of lead tetraacetate with ketohydrazones to form azoacetates has been reported recently by Iffland, Salisbury and Schafer (13) and may be represented by the following equation:

R₂C=N-NH-R' + Pb(0Ac)₄ → R₂C-N=N-R' + Pb(OAc)₂ + HOAc OAc

Of principal interest has been the base-catalyzed decomposition of an azoacetate in a protonic solvent to give a ketone, a hydrocarbon, nitrogen and an acetate salt. The following sequence of steps has been proposed to account for these products (11).

Aminomethylation And Hydroxymethylation Of 6-Mercaptopublne And 6-Alkylthiopubines, Charles P. Bryant

Masters Theses

Introduction

The Mannich reaction and hydroxymethylation were used to prepare analogs of 6-mercaptopurine as possible antimetabolites. Physical and chemical methods were used to elucidate the structures of the compounds prepared.

The Polarizing Effects Of Inhibitors Upon The Reaction Of Iron With Hydrochloric Acid, Duane L. Mickelson

Masters Theses

Introduction

Corrosion inhibitors have been widely studied. Electrical methods of study have been utilized (7) (10) (24) and polarization curves (2) (6) (18) (26) have been plotted by many observers in studying different aspects of corrosion. In this research the measured polarizing currents a.re used strictly in an effort to find out how the corrosion inhibitors affect the anodic and the cathodic reactions.

Nuclear Magnetic Relaxation And Diffusion In Paraffin Oil, David E. Parker

Masters Theses

Introduction

Since the introduction of the spin echoes technique by E. L. Hahn¹ many studies have been made in the determination of the spin relaxation T₂, spin-lattice relaxation T₁, and the diffusion rates in gases, liquids^2-5, and solids^6-10. Hahn's methods were later improved by Carr and Purcell¹¹. The Carr-Purcell method serves as the basic technique for this study.

Several studies have been published on the relaxation and diffusion rates in hydrocarbons¹². These studies have shown:

1. The spin relaxation time T₂, is independent of the …

Reaction Of Dihydropyran With Substituted Benzenesulfonyl Azides, Douglas L. Rector

Masters Theses

Introduction

The intent of this investigation was to study the addition of arylsulfonyl azides to vinyl ethers, specifically 2,3-dihydro-4H-pyran, and to establish by chemical and physical methods the structure of the adduct.

Synthesis Of Potential Anti-Tumor Agents Related To Ethanolamine. I. Phenoxyacetic Acid Derivatives, Kenneth Wayne Rodarmer

Masters Theses

Introduction

Derivatives of phenoxyacetic acid (PAA), because of their activity as synthetic auxins, have long been of interest in the botanical sciences. PAA itself was noted (29) to have some auxin activity. However, real interest in PAA derivatives awaited the establishment of 2,4-dichlorophenoxyacetic acid (2,4-D) as a powerful, selective herbicide (12). An enormous number of PAA analogs and homologs have been investigated for their potential in the herbicide industry, and the statistical evidence from these investigations has been used as the basis for several interesting and sometimes conflicting theories of auxin mechanisms (17, 26, 23, 27).

Physiological effects of PAA …

Helianthus Annuus - The Separation And Identification Of A New Fatty Acid, Donald C. Gruber

Masters Theses

Introduction

The term "fatty acids" was first applied principally to saturated, monobasic carboxylic acids and especially to long chain acids derived from animal and vegetable oils. As time passed and the knowledge of natural fats increased, polyunsaturated, hydroxy, keto and branched chain acids were also found as constituents of these fats and oils and these also came under the heading of fatty acids. Even acids containing alicyclic substituents were found.

More recently the term 11 fatty acid" has been applied to include saturated and unsaturated monobasic carboxylic acids and several other series of substituted acids having carbon skeletons similar to …

I. An Investigation Of The Organic Compounds In The Media And Mycelium Of Naucoria Confragosa. Ii. Study Of The Extra-Cellular Pigments Of An Unknown Fungus, Yueh-Tsun Chen

Masters Theses

"The fungal metabolites excreted into the culture fluid by basidiomycetes growing on synthetic glucose media as well as formed in the mycelia of the organisms were investigated in this thesis. Earlier unpublished work had shown that Maucoria confragosa excreted into the medium compounds which were thought to be phenols. Insufficient material was recovered from an ethyl acetate extract of the medium in the present study for further investigation. Colorimetric methods were employed both for the quantitative estimation of reducing sugar not consumed by the microorganisms as well as for a measure of the total organic solids present in the spent …

Tschebyscheff Fitting With Polynomials And Nonlinear Functions, George F. Luffel

Masters Theses

"It is the purpose of this study to survey the properties of the Tschebyscheff polynomials with particular reference to how they are employed as approximants and interpolants. The survey is extended to include the process known as "Tschebyscheff Approximation" or "Tschebyscheff Fitting" of a function by functions other than polynomials. One such fitting technique which will be of particular interest in this study is that of fitting f(x) by the function ab^x + c where a, b, c are real and b ≠ 1. In addition to a survey of the properties of the Tschebyscheff polynomials and of Tschebyscheff …

A Measurement Of Dead Space And Its Effect On The Homogeneous Nucleation Rate Of Water Vapor In Helium, Michael A. Grayson

Masters Theses

"The existence of a "dead space" surrounding each nucleated water droplet is demonstrated and measurements of its rate of development are made. The effects of this "dead space" are considered to be due to both the removal of vapor from the helium-water vapor mixture and the evolution of heat about the drop due to its growth. The results confirm the usefulness of the concept of a "dead space" and provide a means for its measurement with respect to time. Recommendations for further study and a method of correcting for dead space effects is given"--page [i].

The Geology Of The Interstate Highway 244 And 44 Exchange, Kirkwood, Missouri, John Neil Thomas

Masters Theses

"During the summer of 1964, construction was completed on the intersection of Interstate Highways 244, 44 and U.S. Highway 66, one mile southwest of Kirkwood, Missouri. during the construction of the interchange, numerous artificial exposures of rocks of the middle Mississippian Meramecian Series were exposed. This provided an excellent opportunity for examining fresh exposures near the type Meramecian Series. The formations of the area were studied, and startigraphic [sic] sections were prepared from three of the more complete sections that were measured and described. The highway cuts expose complete sections of the Warsaw and Salem formations, and the lower part …

Geology, Geochemistry And Genesis Of Selected Skarn Deposits, Northern New Brunswick, Canada, Donald John Bachinski

Masters Theses

"An exhaustive geological and geochemical study is presented of magnetite-chalcopyrite skarn deposits occurring within the thermal aureole of the Nicholas Denys quartz maonzonie-granodiorite stock. The deposits are crudely lenticular and occur in metamorphosed impure limestone and siliceous, in part limy, argillite-greywacke. These are now represented by andradite-epidote-diopside-calcite skarn and cal-silicate to horn-felsic rocks respectively. Both deposits are spatially related to the Main fault of the Rocky Brook-Millstream fault system; late, generally northwest trending transverse faults are conspicuous and are deemed of importance in ore localization"--Abstract, page [ii].

A Second Study Of Homogeneous Nucleation Of Water Vapor In Helium, Raymond J. Schmitt

Masters Theses

"Absolute homogeneous nucleation rates in a supersaturated mixture of water vapor and helium are measured using a long sensitive time expansion chamber and a method devised by Kassner and Allard. A pulse technique is employed to produce the nucleation in an effort to suppress disturbing influences of vapor depletion and droplet growth. The time-varying nature of the supersaturation during the nucleation pulse is taken into account by an Integration over the pulse. Observed and theoretically predicted droplet concentrations are related by an assumed nucleation rate law which is adjusted until the total droplet populations predicted by integration of the assumed …

An X-Ray Study Of The Lead Zirconate-Bismuth Ferrate System, Pen-Chu Chou

Masters Theses

"The lead zirconate-bismuth ferrate system was studied employing x-ray and microscopic analysis. Samples were prepared by sintering stoichiometric mixtures of the corresponding oxides followed by air quenching. The results of the analyses show the system to be probably solid solutions over the entire compositional range, although small amounts of other phases are present in some regions.

X-ray data indicate a multiple cell, orthorhombic phase, to exist over the range 100-30 mole percent PbZrO₃ . From 100-82 mole percent PbZrO₃ , the addition of BiFeO₃ reduces the distortion of the phase such that a nearly cubic x-ray pattern is obtained at …

A Graphical Method Of Estimating Heat Capacities Of Hydrocarbons, Pu-Ying Liu

Masters Theses

"Heat capacity arises because the individual particles comprising a substance are able to move and thus take up kinetic energy and usually also potential energy as the temperature rises. In many substances electrons do not absorb energy until very high temperatures are reached. Thus most heat capacity effects are interpreted in terms of the motion of the atoms neglecting electronic transitions. The total internal energy of a material is, therefore, equal to the sum of the energies due to translational and rotational motion of the molecules and to the vibrational motion of the atoms making up the molecules...The objective of …

Operating Characteristics Of A Cloud Chamber Suited For Condensation Measurements, Donald L. Packwood

Masters Theses

"It is the main purpose of this research to investigate the validity of using the adiabatic laws to determine the temperature from the pressure ratio. Some of the effects which might invalidate the use of the adiabatic laws will be studied. Special consideration will be given to the accurate calculation of [gamma]. Carstens' approximate calculation of the heat flow into the chamber due to conduction will be checked. A measurement will be made of how long the chamber remains adiabatic after an expansion when the continuing expansion technique is used. The static temperature gradient throughout the chamber will be measured …

Carcinostatic Sulfonic Acid Esters Of Selected 1,4-Diols, Robert A. Earl

Masters Theses

Introduction

The purpose of this research was to prepare the bisarylsulfonic acid esters of 1,4-butanediol and 1,4-but-2-ynediol.

This series of compounds is of interest because of the antitumor activity exhibited by the bismethanesulfonates of 1,4-butanediol and 1,4-but-2-ynediol. The compounds which were prepared were submitted to Cancer Chemotherapy National Service Center for evaluation in their anticancer program.

It was hoped that the compounds synthesized would be of pharmacological value. It was further hoped that the biological test data of these compounds would demonstrate a correlation between types of substituents on the aromatic nucleus and the degree of activity of the compounds. …

Latent Class Analysis And Information Retrieval, George Loyd Jensen

Masters Theses

"Information retrieval may be defined roughly as a procedure to either locate or physically retrieve a document or documents containing information on a given topic with a high degree of reliability. Information retrieval is one of the newest fields in computing science. Being so new there are many unexplored areas. The research that has been done has not been standardized beyond the point of the effort which has been slanted toward solving the "Library Problem" ... Several different information retrieval methods have been suggested and some research done on them to try and solve the "Library Problem". Of these methods …

Geochemical Prospecting For Copper In The Northern Part Of Yuma County, Arizona, Abdul Razak Kasim Al-Hashimi

Masters Theses

"Geochemical prospecting for copper has been carried out in two selected areas in the northern part of Yuma County, Arizona. These areas have a few old copper mines and some other zones of mineralization. The rocks of the area range in age from Precambrian to Quaternary and consist of complex gneiss, lava flows, schists, marble, sandstone, conglomerates and some intrusive dikes. A cold-extractible [sic] field method was used to study the relation between the copper content of stream sediments in washes and the geology, mineralization, and topography of the areas. A few total copper tests were also carried out. Another …

A Study Of The Piezometric Surface Of The Grand Falls Formation In The Duenweg-Oronogo Mining Belt East Of Joplin, Missouri, Renny Roger Nichols

Masters Theses

"The Joplin area of Missouri, which includes the Duenweg-Oronogo belt, was a famous zinc and lead mining district. Many mines were abandoned after World War I and filled with water. These provide a large potential supply of ground water. Expansion of industries and population in the area since World War II has caused a demand for water. In 1964, the Ground Water Branch, Water Resources Division, of the United States Geological Survey began a project to study the surface and ground water resources of the area. As part of his work on this project, the author measured the piezometric level …

Near Optimal Sequencing :N Jobs And M Machines; All Jobs To Be Processed Through The Same Order Of Machines, Larry Glen Clark

Masters Theses

"There is a need, in industry, for an efficient method of determining an optimal sequence for processing a number of jobs through two or more machines. A method which requires a minimum amount of time would be most beneficial. The purpose of this study has been to define such a method. Tests on the method described indicate that although an optimal solution is not always obtained, the solutions obtained are quite good and due to the time factor the method would be beneficial to industry"--Abstract, page ii.

Taxonomic Study Of Fossil And Recent Otoliths Of Certain Cuskeels, Gary Neal Pointer

Masters Theses

"Otoliths are calcareous structures occurring in the auditory labyrinths of teleost (bony) fishes. Three pairs of these earstones normally are found: the sagitta, in the sacculus; the asteriscus, in the lagena; and the lapillus in the utriculus. In fishes other than the Order cypriniformes (carp, catfishes, and related forms), the sagitta is the largest otolith, and it may be used in taxonomic and other studies. Fossil earstones of cuskeels (Family Ophidiiae-Brotulidae), constituting the Preophidion complex, occur in relative abundance at various levels in the Claiborne, Jackson, and Vicksburg groups of the Lower Tertiary on the Gulf Coast. The present study …

A Parameter Perturbation Technique Applied To Multipoint Iteration Functions For The Solution Of Systems Of Nonlinear Equations, Robert N. Delozier

Masters Theses

"The convergence of classical iterative procedures, when applied to a system of nonlinear algebraic or transcendental equations, is highly dependent upon a good initial approximation to the desired roots. Most of the classical iterative schemes have convergence factors between one and two. In this paper iterative schemes of order two and greater are studied in connection with a parameter perturbation process. The parameter perturbation process relaxes the restrictions on the choice of initial values. The procedure divides each problem into a number of subsidiary problems. Each subsidiary system of equations is then solved until a solution is found to the …

Geology Of Cienega Mining District, Northwestern Yuma County, Arizona, Elias Zambrano

Masters Theses

"The purpose of this investigation was to determine the general geology of an unusually complex area containing several small mines and located in the northwest corner of Yuma County, Arizona. This report is the first attempt to work out in detail the lithology, structure, stratigraphy, petrography, and economic geology of the area"--Introduction, Purpose and Scope, page 1.

Drop Growth In A Supersaturated Vapor, Roger Buecher

Masters Theses

"Using kinetic theory and the thermodynamics of phase transitions, a method is derived for finding the growth rate and temperature increase of a droplet in water vapor which has been supersaturated by the expansion of a cloud chamber. Calculations are performed for a specific numerical example and compared to other work in this field"--Abstract, page [2].