Digital Commons Network^™

Caliche As A Geologic Repository For Atmospheric Sulfate, Katie Jane Howell

LSU Master's Theses

Recent studies demonstrate that important information on sulfur source, oxidation pathway, transport pattern, and reaction kinetics of the oxidation reactions of reduced sulfur gases in the atmosphere may be uncovered by measuring multiple sulfur and oxygen isotope compositions of the oxidation product — secondary atmospheric sulfate (SAS). SAS from Earth’s distant past, however, is rarely preserved in the rock record because of its high solubility and small quantity. Caliche, a pedogenic carbonate formed in arid to semi-arid continental settings and common in the geologic record, could serve as a repository for ancient SAS. Two major groups of caliche samples: 1) …