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Biogeochemical Cycling In Lake Superior Tributaries: Seasonality, Quantity And Quality Of Export, Ashley Anne Coble Jan 2015

Biogeochemical Cycling In Lake Superior Tributaries: Seasonality, Quantity And Quality Of Export, Ashley Anne Coble

Dissertations, Master's Theses and Master's Reports - Open

Seasonal and spatial variability in environmental factors may affect dissolved organic matter composition and nutrient transformation and retention in streams. The objective of this research was to quantify and describe seasonality, quantity, and quality of nutrient processing and export of ammonium (NH4), soluble reactive phosphate (SRP), and dissolved organic carbon (DOC) into Lake Superior through intensive study in a small 1st order watershed coupled with snapshot measurements across 12 tributaries that varied in size, location, and wetland coverage. Our results suggest biodegradable C is exported from a small headwater stream year-round and that DOC mineralization rates can be …


Impacts Of Climate Change On Soil Microorganisms In Northern Hardwood Forests, Carley Jane Kratz Jan 2014

Impacts Of Climate Change On Soil Microorganisms In Northern Hardwood Forests, Carley Jane Kratz

Dissertations, Master's Theses and Master's Reports - Open

As global climate continues to change, it becomes more important to understand possible feedbacks from soils to the climate system. This dissertation focuses on soil microbial community responses to climate change factors in northern hardwood forests. Two soil warming experiments at Harvard Forest in Massachusetts, and a climate change manipulation experiment with both elevated temperature and increased moisture inputs in Michigan were sampled. The hyphal in-growth bag method was to understand how soil fungal biomass and respiration respond to climate change factors. Our results from phospholipid fatty acid (PLFA) analyses suggest that the hyphal in-growth bag method allows relatively pure …


Parametric Study Of Reaxff Simulation Parameters For Molecular Dynamics Modeling Of Reactive Carbon Gases, Benjamin David Jensen Jan 2013

Parametric Study Of Reaxff Simulation Parameters For Molecular Dynamics Modeling Of Reactive Carbon Gases, Benjamin David Jensen

Dissertations, Master's Theses and Master's Reports - Open

Abstract

The development of innovative carbon-based materials can be greatly facilitated by molecular modeling techniques. Although the Reax Force Field (ReaxFF) can be used to simulate the chemical behavior of carbon-based systems, the simulation settings required for accurate predictions have not been fully explored. Using the ReaxFF, molecular dynamics (MD) simulations are used to simulate the chemical behavior of pure carbon and hydrocarbon reactive gases that are involved in the formation of carbon structures such as graphite, buckyballs, amorphous carbon, and carbon nanotubes. It is determined that the maximum simulation time step that can be used in MD simulations with …


Interactive Controls Of Water Table Position And Plant Functional Types On Peat Porewater Character In Northern Bog Ecosystems: Implications For Carbon Cycling Dynamics, Aleta L. Daniels Jan 2013

Interactive Controls Of Water Table Position And Plant Functional Types On Peat Porewater Character In Northern Bog Ecosystems: Implications For Carbon Cycling Dynamics, Aleta L. Daniels

Dissertations, Master's Theses and Master's Reports - Open

Northern wetlands, and particularly peatlands, have been shown to store around 30% of the world's soil carbon and thus play a significant role in the carbon cycle of our planet. Changes in climate are altering peatland hydrology and vegetation communities. These changes are possibly resulting in declines in the ability of peatlands to sequester carbon because losses through carbon oxidation and mineralization are likely to increase relative to C inputs from net primary production in a warmer, drier climate. However, the consequences of interactive effects of altered hydrology and vegetation on carbon storage are not well understood. This research evaluated …