Digital Commons Network^™

Hamilton-Waterloo Problem With Triangle And C9 Factors, David C. Kamin

Dissertations, Master's Theses and Master's Reports - Open

The Hamilton-Waterloo problem and its spouse-avoiding variant for uniform cycle sizes asks if Kv, where v is odd (or Kv - F, if v is even), can be decomposed into 2-factors in which each factor is made either entirely of m-cycles or entirely of n-cycles. This thesis examines the case in which r of the factors are made up of cycles of length 3 and s of the factors are made up of cycles of length 9, for any r and s. We also discuss a constructive solution to the general (m,n) case which fixes r and s.

Performance Evaluation Of A Novel Asymmetric Capacitor Using A Light-Weight, Carbon Foam Supported Nickel Electrode, Padmanaban Sasthan Kuttipillai

Dissertations, Master's Theses and Master's Reports - Open

Electrochemical capacitors have been an important development in recent years in the field of energy storage. Capacitors can be developed by utilizing either double layer capacitance at the electrode/solution interfaces alone or in combination with a battery electrode associated with a faradic redox process in one electrode. An asymmetric capacitor consisting of electrochemically deposited nickel hydroxide, supported on carbon foam as a positive electrode and carbon sheet as a negative electrode has been successfully assembled and cycled. One objective of this study has been to demonstrate the viability of the nickel carbon foam positive electrode, especially in terms of cycle …

Synthesis Of Chiral Ferrosalen Ligands And Their Applications In Asymmetric Catalysis, Xiang Zhang

Dissertations, Master's Theses and Master's Reports - Open

A new series of chiral ferrosalen ligands was designed and synthesized. The special feature of the ferrosalen ligands is that the chirality originated from the planar chiral ferrocenyl structure. For most known salen ligands, chirality comes from central and axial chiral centers. The key building block for the construction of these ferrosalen ligands was synthesized stereoselectively by a chiral auxiliary approach. This approach does not consume any chiral material, and does not require chiral HPLC resolution. Using this method, nine ligands were prepared using ferrocene as the starting material. In addition, the steric hindrance was modulated by changing the cyclopentadienyl …

Structural Characterization Of Water-Soluble Atmospheric Organic Matter By Ultrahigh-Resolution Mass Spectrometry, Jeffrey P. Leclair

Dissertations, Master's Theses and Master's Reports - Open

Isolated water-soluble analytes extracted from fog water collected during a radiation fog event near Fresno, CA were analyzed using collision induced dissociation and ultrahigh-resolution mass spectrometry. Tandem mass analysis was performed on scan ranges between 100-400 u to characterize the structures of nitrogen and/or sulfur containing species. CHNO, CHOS, and CHNOS compounds were targeted specifically because of the high number of oxygen atoms contained in their molecular formulas. The presence of 22 neutral losses corresponding to fragment ions was evaluated for each of the 1308 precursors. Priority neutral losses represent specific polar functional groups (H2O, CO2, CH3OH, HNO3, SO3, etc., …

Quantum Transport In A Single Molecular Junction, Partha Pratim Pal

Dissertations, Master's Theses and Master's Reports - Open

The craze for faster and smaller electronic devices has never gone down and this has always kept researchers on their toes. Following Moore’s law, which states that the number of transistors in a single chip will double in every 18 months, today “30 million transistors can fit into the head of a 1.5 mm diameter pin”. But this miniaturization cannot continue indefinitely due to the ‘quantum leakage’ limit in the thickness of the insulating layer between the gate electrode and the current carrying channel. To bypass this limitation, scientists came up with the idea of using vastly available organic molecules …

Measuring Energy Spectra Of Tev Gamma-Ray Emission From The Cygnus Region Of Our Galaxy With Milagro, Jessica G. Galbraith-Frew

Dissertations, Master's Theses and Master's Reports - Open

High energy gamma rays can provide fundamental clues to the origins of cosmic rays. In this thesis, TeV gamma-ray emission from the Cygnus region is studied. Previously the Milagro experiment detected five TeV gamma-ray sources in this region and a significant excess of TeV gamma rays whose origin is still unclear. To better understand the diffuse excess the separation of sources and diffuse emission is studied using the latest and most sensitive data set of the Milagro experiment. In addition, a newly developed technique is applied that allows the energy spectrum of the TeV gamma rays to be reconstructed using …

Planar Magneto-Photonic And Gradient-Photonic Structures : Crystals And Metamaterials., Zhuoyuan Wu

Dissertations, Master's Theses and Master's Reports - Open

In the field of photonics, two new types of material structures, photonic crystals and metamaterials, are presently of great interest. Both are studied in the present work, which focus on planar magnetic materials in the former and planar gradient metamaterials in the latter. These planar periodic structures are easy to handle and integrate into optical systems. The applications are promising field for future optical telecommunication systems and give rise to new optical, microwave and radio technologies.

The photonic crystal part emphasizes the utilization of magnetic material based photonic crystals due to its remarkable magneto-optical characteristics. Bandgaps tuning by magnetic field …

Applications Of Finite Geometries To Designs And Codes, David C. Clark

Dissertations, Master's Theses and Master's Reports - Open

This dissertation concerns the intersection of three areas of discrete mathematics: finite geometries, design theory, and coding theory. The central theme is the power of finite geometry designs, which are constructed from the points and t-dimensional subspaces of a projective or affine geometry. We use these designs to construct and analyze combinatorial objects which inherit their best properties from these geometric structures.

A central question in the study of finite geometry designs is Hamada’s conjecture, which proposes that finite geometry designs are the unique designs with minimum p-rank among all designs with the same parameters. In this dissertation, we will …

Fixed Block Configuration Gdds With Block Size 6 And (3, R)-Regular Graphs , Melanie R. Laffin

Dissertations, Master's Theses and Master's Reports - Open

Chapter 1 is used to introduce the basic tools and mechanics used within this thesis. Most of the definitions used in the thesis will be defined, and we provide a basic survey of topics in graph theory and design theory pertinent to the topics studied in this thesis.

In Chapter 2, we are concerned with the study of fixed block configuration group divisible designs, GDD(n; m; k; λ₁; λ₂). We study those GDDs in which each block has configuration (s; t), that is, GDDs in which each block has exactly s …

Triggering Of Volcanic Activity By Large Earthquakes, Dulcinea M. Avouris

Dissertations, Master's Theses and Master's Reports - Open

Statistical analyses of temporal relationships between large earthquakes and volcanic eruptions suggest seismic waves may trigger eruptions even over great (>1000 km) distances, although the causative mechanism is not well constrained. In this study the relationship between large earthquakes and subtle changes in volcanic activity was investigated in order to gain greater insight into the relationship between dynamic stresses propagated by surface waves and volcanic response. Daily measurements from the Ozone Monitoring Instrument (OMI), onboard the Aura satellite, provide constraints on volcanic sulfur-dioxide (SO₂) emission rates as a measure of subtle changes in activity. Time series of …

Using Water Balance Models To Approximate The Effects Of Climate Change On Spring Catchment Discharge : Mt. Hanang, Tanzania , Randall E. Fish

Dissertations, Master's Theses and Master's Reports - Open

This project addresses the potential impacts of changing climate on dry-season water storage and discharge from a small, mountain catchment in Tanzania. Villagers and water managers around the catchment have experienced worsening water scarcity and attribute it to increasing population and demand, but very little has been done to understand the physical characteristics and hydrological behavior of the spring catchment. The physical nature of the aquifer was characterized and water balance models were calibrated to discharge observations so as to be able to explore relative changes in aquifer storage resulting from climate changes.

To characterize the shallow aquifer supplying water …

Lineament Mapping For Groundwater Exploration Using Remotely Sensed Imagery In A Karst Terrain : Rio Tanama And Rio De Arecibo Basins In The Northern Karst Of Puerto Rico, Carla A. Alonso-Contes

Dissertations, Master's Theses and Master's Reports - Open

Remote sensing and advanced digital image processing techniques were developed and tested for delineating karst features important for the subterranean hydrology in the Tanamá River and Rio Grande de Arecibo catchments located in the North Coast Tertiary Basin of Puerto Rico, where groundwater contributes to base flow for surface water bodies which in itself is the main supply of drinking water. This aquifer region is a karst platform of carbonate rocks and clastic beds, thought to comprise a confined aquifer beneath and an unconfined aquifer. Products derived from ASTER, Landsat (ETM+ and TM), a NED DEM (30 m), and a …

Recurrent Voluminous Sector Collapses At Volcán Barú, Panama, Julie A. Herrick

Dissertations, Master's Theses and Master's Reports - Open

Two volcanic debris avalanche deposits (VDADs), both attributed to sector collapse at Volcán Barú, Panama, have been identified after an investigation of deposits that covered more than a thousand square kilometers. The younger Barriles Deposit is constrained by two radiocarbon ages that are ~9 ka; the older Caisán Deposit is at or beyond the radiocarbon range, >43,500 ybp. The total runout length of the Caisán Deposit was ~50 km and it covers 1190 km². The Barriles Deposit extended to about 45 km and covered an area of 966 km², overlapping most of the Caisán. The VDADs …

Characterization Of Harmonic Tremor At Santiaguito Volcano And Its Implications For Eruption Mechanisms , Kyle Arthur Brill

Dissertations, Master's Theses and Master's Reports - Open

We observed Santiaguito volcano in southwestern Guatemala from March 2008 - March 2010. Seismic and infrasound data collected between January and March of 2009 contain records of many diverse processes occurring at the dacitic dome complex, including the recurrence of short lived (30-200 seconds in duration) harmonic tremor concurrent with ash poor gas emissions from the volcano. We employ several different analytical techniques to examine different portions of the tremor and source mechanisms. We use the parameters derived by this analysis to compare the feasibility of several suggested models of eruption mechanisms, and determine that this type of harmonic tremor …

Automation Of Shear-Wave Splitting Parameter Determination Of Local Earthquakes At Yellowstone : Application As Indicator Of Crustal Stress And Temporal Variation , Nicole D. Mcmahon

Dissertations, Master's Theses and Master's Reports - Open

Shear-wave splitting can be a useful technique for determining crustal stress fields in volcanic settings and temporal variations associated with activity. Splitting parameters were determined for a subset of local earthquakes recorded from 2000-2010 at Yellowstone. Analysis was automated using an unsupervised cluster analysis technique to determine optimum splitting parameters from 270 analysis windows for each event. Six stations clearly exhibit preferential fast polarization values sub-orthogonal to the direction of minimum horizontal compression. Yellowstone deformation results in a local crustal stress field differing from the regional field dominated by NE-SW extension, and fast directions reflect this difference rotating around the …

Sonic Log Prediction In Carbonates , Nayyer Islam

Dissertations, Master's Theses and Master's Reports - Open

This work is conducted to study the complications associated with the sonic log prediction in carbonate logs and to investigate the possible solutions to accurately predict the sonic logs in Traverse Limestone. Well logs from fifty different wells were analyzed to define the mineralogy of the Traverse Limestone by using conventional 4-mineral and 3-mineral identification approaches. We modified the conventional 3-mineral identification approach (that completely neglects the gamma ray response) to correct the shale effects on the basis of gamma ray log before employing the 3-mineral identification. This modification helped to get the meaningful insight of the data when a …

Dynamics And Kinematics Of Eruptive Activity At Fuego Volcano, Guatemala 2005-2009, John J. Lyons

Dissertations, Master's Theses and Master's Reports - Open

Volcanoes are the surficial expressions of complex pathways that vent magma and gasses generated deep in the Earth. Geophysical data record at least the partial history of magma and gas movement in the conduit and venting to the atmosphere. This work focuses on developing a more comprehensive understanding of explosive degassing at Fuego volcano, Guatemala through observations and analysis of geophysical data collected in 2005 – 2009. A pattern of eruptive activity was observed during 2005 – 2007 and quantified with seismic and infrasound, satellite thermal and gas measurements, and lava flow lengths. Eruptive styles are related to variable magma …

"The Need Obliged Us" : Culture As Capacity During The Hurricane Stan Emergency Response. A Case Study From Tectitan, Huehuetenango, Guatemala , Jesse Silverman

Dissertations, Master's Theses and Master's Reports - Open

A major deficiency in disaster management plans is the assumption that pre-disaster civil-society does not have the capacity to respond effectively during crises. Following from this assumption a dominant emergency management strategy is to replace weak civil-society organizations with specialized disaster organizations that are often either military or Para-military and seek to centralize decision-making. Many criticisms have been made of this approach, but few specifically addresses disasters in the developing world. Disasters in the developing world present unique problems not seen in the developed world because they often occur in the context of compromised governments, and marginalized populations. In this …

Comparisons Between Omi So2 Data And Ground-Based So2 Measurements At Turrialba Volcano , Anieri M. Morales Rivera

Dissertations, Master's Theses and Master's Reports - Open

Turrialba is one of the largest and most active stratovolcanoes in the Central Cordillera of Costa Rica and an excellent target for validation of satellite data using ground based measurements due to its high elevation, relative ease of access, and persistent elevated SO₂ degassing. The Ozone Monitoring Instrument (OMI) aboard the Aura satellite makes daily global observations of atmospheric trace gases and it is used in this investigation to obtain volcanic SO₂ retrievals in the Turrialba volcanic plume. We present and evaluate the relative accuracy of two OMI SO₂ data analysis procedures, the automatic Band Residual Index …

Ultraviolet Digital Imaging Of Volcanic Plumes : Implementation And Application To Magmatic Processes At Basaltic Volcanoes, Patricia Amanda Nadeau

Dissertations, Master's Theses and Master's Reports - Open

Magmatic volatiles play a crucial role in volcanism, from magma production at depth to generation of seismic phenomena to control of eruption style. Accordingly, many models of volcano dynamics rely heavily on behavior of such volatiles. Yet measurements of emission rates of volcanic gases have historically been limited, which has restricted model verification to processes on the order of days or longer.

UV cameras are a recent advancement in the field of remote sensing of volcanic SO₂ emissions. They offer enhanced temporal and spatial resolution over previous measurement techniques, but need development before they can be widely adopted and …

Enumeration Of Inequivalent Cycle Decompositions, William J. Laffin

Dissertations, Master's Theses and Master's Reports - Open

A k-cycle decomposition of order n is a partition of the edges of the complete graph on n vertices into k-cycles. In this report a backtracking algorithm is developed to count the number of inequivalent k-cycle decompositions of order n.

Cyclic Automorphic Graph Decompositions , Michael Li Misson

Dissertations, Master's Theses and Master's Reports - Open

Chapter 1 introduces the tools and mechanics necessary for this report. Basic definitions and topics of graph theory which pertain to the report and discussion of automorphic decompositions will be covered in brief detail. An automorphic decomposition D of a graph H by a graph G is a G-decomposition of H such that the intersection of graph (D) @H. H is called the automorhpic host, and G is the automorphic divisor. We seek to find classes of graphs that are automorphic divisors, specifically ones generated cyclically.

Chapter 2 discusses the previous work done mainly by Beeler. …

Parallel Algorithm For Solving Integer Linear Programs, David O. Torrey Jr.

Dissertations, Master's Theses and Master's Reports - Open

Linear programs, or LPs, are often used in optimization problems, such as improving manufacturing efficiency of maximizing the yield from limited resources. The most common method for solving LPs is the Simplex Method, which will yield a solution, if one exists, but over the real numbers. From a purely numerical standpoint, it will be an optimal solution, but quite often we desire an optimal integer solution. A linear program in which the variables are also constrained to be integers is called an integer linear program or ILP. It is the focus of this report to present a parallel algorithm for …

Characterizing A Single Photon Detector, Paul N. Rojas

Dissertations, Master's Theses and Master's Reports - Open

I will present my work about constructing and characterizing a single photon detector. Using the 1550nm laser and second harmonic light generation, I am able to count single photons on a Multi‐Pixel Photon Counter (MPPC) silicon APD. My results show that upwards of 22% quantum efficiency is achievable with the MPPC. Future work will include coincidence detection of correlated photon‐pair.

Four-Window Technique For Measuring Optical-Phase-Space-Time-Frequency Tomography, Rachel A. Blaser

Dissertations, Master's Theses and Master's Reports - Open

A new approach, the four-window technique, was developed to measure optical phase-space-time-frequency tomography (OPSTFT). The four-window technique is based on balanced heterodyne detection with two local oscillator (LO) fields. This technique can provide independent control of position, momentum, time and frequency resolution. The OPSTFT is a Wigner distribution function of two independent Fourier transform pairs, phase-space and time-frequency. The OPSTFT can be applied for early disease detection.