Digital Commons Network^™

When All Seems Lost: A Discussion On The Implications Of Using Medicine For Scientific Advances, Rebecca Monterusso

Honors Theses

When All is Lost is a creative non-fiction piece following the lives of two fictional characters living during World War" and the Holocaust. It is meant to discuss the moral quandary when human experimentation is used for the purpose of scientific advancement. The two main characters lives' are depicted in a series of modified scenes that describe what happens to them throughout the war. Leo Weinstock is a Jewish man who is chosen for the high-altitude experiments at Dachau after he is imprisoned during Kristallnacht. Erich, on the other hand, is a young, successful Luftwaffe pilot defending his country. Both …

Origin Of High Levels Of Ammonium In Groundwater, Ottawa County, Michigan, Derrick Lingle

Masters Theses

Groundwater from wells located in and around Hemlock Crossing Park in Ottawa County, Michigan has elevated levels of ammonium. High ammonium concentrations in potable water wells are a common indicator of anthropogenic impact, such as landfill leachate or agricultural activity. Ammonium can also occur in groundwater through the decay of natural organic material. Along with the retrieval of a complete glacial sediment core via rotasonic drilling, numerous chemical and isotopic parameters were used to determine the source of ammonium in the impacted aquifer.

Buried organic material, deposited during the Athens subepisode interglacial period, is in contact with groundwater containing elevated …

Stratigraphic Controls On Diagenetic Pathways In The St. Peter Sandstone, Michigan Basin, Stephen A. Zdan

Masters Theses

The Middle Ordovician St. Peter Sandstone in the Michigan Basin is a target for hydrocarbon exploration/production, and carbon sequestration and geologic storage. The St. Peter is predominantly a marine sandstone with four dominant lithofacies. The uppermost facies contains zones of porosity and good reservoir quality. Because of the mostly uniform detrital composition, diagenesis must play a leading role in reservoir quality development. This study tests stratigraphic controls on diagenesis and reservoir quality development. The distribution of diagenetic regimes is believed to result from depositional setting and related geologic processes, including variations in sediment accumulation rate. Early carbonate cements preserve pre-compaction …

Utilizing Persistent Scatterer Interferometry To Investigate The Nature And Factors Controlling Nile Delta Subsidence, El Hachemi Yousef Bouali

Masters Theses

The Nile Delta in Egypt is being threatened by two continuous and relatively slow hazards: encroachment from the Mediterranean Sea as sea levels rise and land subsidence of the delta itself. The magnitude of sea level rise has been actively monitored, while the subsidence of the Nile Delta has not been adequately quantified spatially and temporally. Instead, all previous studies have either focused on measuring average Holocene subsidence rates or modern subsidence rates on local scales (point- or city-scale).

The overall study objective is three-fold: (1) to measure and map the spatial variations in subsidence rates across the entire Nile …

Development Of Polarization Analysis Of Resonant Inelastic X-Ray Scattering, Xuan Gao

Dissertations

Resonant inelastic x-ray scattering (RIXS) is a powerful technique in condensed matter physics for studying the electronic excitations in novel materials of interest. In currently operating hard x-ray RIXS instruments the energy and momentum transfers are measured while the outgoing polarization is not measured due to significant technical challenges. But the outgoing polarization of the scattered photons provides valuable information (excitation symmetry) about the states involved in the scattering which is difficult to determine without polarization analysis. Polarization analysis has proved extremely valuable in soft x-ray RIXS, and so a polarization analysis system is being developed to fill the technical …

Estimation And Inference For Spatial And Spatio-Temporal Mixed Effects Models, Casey M. Jelsema

Dissertations

One of the most common goals of geostatistical analysis is that of spatial prediction, in other words: filling in the blank areas of the map. There are two popular methods for accomplishing spatial prediction. Either kriging, or Bayesian hierarchical models. Both methods require the inverse of the spatial covariance matrix of the data. As the sample size, n, becomes large, both of these methods become impractical. Reduced rank spatial models (RRSM) allow prediction on massive datasets without compromising the complexity of the spatial process. This dissertation focuses on RRSMs, particularly situations where the data follow non-Gaussian distributions.

The manner in …

Client-Based Qos Monitoring And Evaluation Architecture For Network Infrastructure And Services, Ammar Mohammed Kamel

Dissertations

Providing an efficient Quality-of-Service (QoS) measurement model is a challenging problem in today’s mobile computing and telecommunications networks. Currently, most of QoS techniques utilize service measurements that are collected by the network elements (i.e., network-side monitoring) to evaluate the network performance. However, this process does not take into account the service performance from the clients' perspective and might contradict with the Service Level Agreement (SLA). In order to overcome the limitations of service-side QoS monitoring, a number of research studies have been conducted to present alternative architectures and algorithms for client-side QoS service assessment in computer networks. The client-side QoS …

An Implementation Of Controller Area Network Bus Analyzer Using Microblaze And Petalinux, Tung-Hsun Tsou

Masters Theses

This paper presents a controller area network (CAN) monitor system created in a Field-Programmable Gate Array (FPGA) board, which is Xilinx SP605. The goals of this research are to let the system demonstrate a reliable CAN bus monitor system, and to show the Xilinx MicroBlaze and PetaLinux design flow. This system can be used to observe the CAN bus messages by means of C program and embedded Linux environment.

A Xilinx MicroBlaze soft processor is used to read CAN information from the external CAN bus controller, Microchip MCP2515. Two implementations, a stand-alone system and a Linux system, are built to …

Activated Carbon Preconditioning To Reduce Contaminant Leaching In Cement-Based Stabilization Of Soils, Renee Elizabeth Crane

Masters Theses

Powdered activated carbon (PAC) is often added with cement to enhance the stabilization and solidification (S/S) of materials contaminated with organic compounds. Adsorption of organic contaminants onto PAC can reduce leaching of organic contaminants. Simultaneous addition of PAC and cement reduces soil handling costs, but cement hydration reactions coat PAC with Ca(OH)2 before contaminants can be adsorbed onto PAC. Laboratory studies were done on four aged, contaminated soils from manufactured gas plant sites to compare the performance of S/S treatment with simultaneous addition of PAC and cement vs. cement addition after preconditioning with PAC to enhance contaminant adsorption. Performance was …

Using Soil Organic Matter As An Iron Chelate To Enhance The Efficiency Of Modified Fenton Oxidition Of Diesel Fuel In Arctic Soils, Mary K. Sherwood

Masters Theses

Laboratory experiments were conducted to investigate the use of modified fenton chemistry on the treatment of three soils from the Canadian arctic, all with abundant soil organic matter, iron and manganese oxides, and diesel fuel contamination. The purpose of these studies was to (I) to assess modified fenton chemistry as a treatment option for petroleum-contaminated arctic soils, and (2) to evaluate the impact of soil organic matter on the modified fenton treatment of soils. Modified fenton treatment was compared for reactions in which ethylenediaminetetraacetate was added as a chelate vs. reactions in which the native soil organic matter was the …

A Pattern In The Lusternik-Schnirelmann Category Of Rational Spaces, Julie Dare Houck

Dissertations

The Lusternik-Schnirelmann (or LS) category of a space is one less than the number of contractible open sets with which we can cover the space. If we look at the LS categories of the skeleta of a CW complex, we find a sequence of dimensions where the LS category changes. I discuss whether certain of these "category sequences" (defined in the paper, "Categorical Sequences", by Nendorf, Scoville, and Strom) could be realized as the categorical sequences of rational spaces. I first reduce from looking at all rational spaces to only Postnikov sections of finite wedges of spheres. Using the Leray-Serre …

An Embodied Perspective Of Expertise In Solving The Problem Of Making A Geologic Map, Caitlin Norah Callahan

Dissertations

The task of constructing a geologic map is a cognitively and physically demanding field-based problem. The map produced is understood to be an individual’s two-dimensional interpretation or mental model of the three-dimensional underlying geology. A popular view within the geoscience community is that teaching students how to make a geologic map is valuable for preparing them to deal with disparate and incomplete data sets, for helping them develop problem-solving skills, and for acquiring expertise in geology. Few previous studies have focused specifically on expertise in geologic mapping. Drawing from literature related to expertise, to problem solving, and to mental models, …

Study Of Feasability For Phase Difference Extraction Using Software Defined Radio In Location Analysis, Paul Miller

Masters Theses

Here is a method for using the phase of an HF radio signal for use in location analysis. This computation is implemented in a software defined radio processing block in the GNU Radio environment. The signals analyzed are received by an Ettus Research USRP SDR. We created a phase analysis system called WMU Rootsync, which compares the roots of a received signal to the roots of a generated reference signal for the phase analysis. This research describes a prototype method for phase analysis only. Future projects may use these ideas differently than presented here. We intend for future projects to …

Surface Complexation Modeling Of Cr(Vi) Absorption On Mineral Assemblages, Ann M. Gilchrist

Masters Theses

Hexavalent chromium (Cr(VI)) is a waste product of many anthropogenic processes. Because it is highly mobile, the improper disposal of Cr(VI) has caused widespread contamination. Because reduction and adsorption reactions may reduce the bioavailability and mobility of Cr(VI) in environmental systems, a better understanding of Cr(VI) adsorption behavior will improve remediation efforts.

Subsurfaces and soils are heterogeneous, however most studies focus on single sorbate/sorbent interactions to develop surface complexation models (SCM) for prediction of heavy metal adsorption. Theoretically, combining the SCMsdeveloped for single sorbate/sorbent systems should yield accurate predictions of adsorption in more complex systems (i.e., the component additivity approach …

Ultrafast Dynamics And Two-Photon Absorption Properties Of Chromophores At Interfaces, Semere Ghebru Bairu

Dissertations

Materials with large two-photon absorption (2PA) cross-sections found applications in several areas such as sensor protection, 3D micro/nano fabrication, photodynamic therapy, optical data-storage, multi-photon sensing, multi-photon microscopy and imaging. Several successful research strategies were developed in literature to achieve 2PA materials with enhanced cross-sections. However, the obtained cross-sections are far from adequate and there is a need to develop new strategies. In a parallel development, numerous research efforts were focused on studying the dynamics of interfacial charge-transfer (ICT) across chromophoresemiconductor interfaces, especially in the context of dye-sensitized solar cells. While investigating the fundamentals of ICT, it was found that these …

The Geology Of The South Antelope Pass Area Of The Southern Peloncillo Mountains, Hidalgo County, New Mexico, John A. Yellich

Masters Theses

Volcanic activity during the middle and late Tertiary has been recorded in the mountain ranges of the southwestern United States and northern Mexico and the two provinces of prominent volcanic activity, the Sierra Madre Occidental and the Mogollon Plateau, dominantly rhyolitic in composition, are connected by the Peloncillo Range. The predominant rock chemistry of the south Antelope Pass area is “rhyolitic”; however, lava rock types dominate over welded tuff rock types of the two provinces. There is a limited pre-Tertiary rock record of limestones and sandstones in the northeastern part of the study area. The rest of the study area …

Organic Solar Cells Based On High Dielectric Constant Materials: An Approach To Increase Efficiency, Khalil Jumah Tawfiq Hamam

Dissertations

The efficiency of organic solar cells still lags behind inorganic solar cells due to their low dielectric constant which results in a weakly screened columbic attraction between the photogenerated electron-hole system, therefore the probability of charge separating is low. Having an organic material with a high dielectric constant could be the solution to get separated charges or at least weakly bounded electron-hole pairs. Therefore, high dielectric constant materials have been investigated and studied by measuring modified metal-phthalocyanine (MePc) and polyaniline in pellets and thin films. The dielectric constant was investigated as a function of temperature and frequency in the range …

A Robust Estimate For The Bifurcating Autoregressive Model With Application To Cell Lineage Data, Tamer M. E. Elbayoumi

Dissertations

The bifurcating autoregressive model (BAR) is commonly used to model binary tree data. One application for this model relates to cell lineage data in biology. The purpose of studying the cell lineage process is to know whether the observed correlations between related cells are due to similarities in the environmental, inherited effects, or a combination of both of them. Because outliers in this kind of data are quite common, the need for a robust estimation procedure is necessary. A weighted L1 (WL1) estimate for estimating the parameters of the BAR model is considered. When the weights are constant, the estimate …

Theoretical Modeling Of Near-Threshold Shape Resonance Behaviour In Photodetachment Experiments, Laurentiu Dan Dumitriu

Masters Theses

This thesis attempts to better understand the results obtained from photodetachment experiments of Fe-, made by the Western Michigan University experimental atomic physics group at the Advanced Light Source (ALS), Lawrence Berkeley National laboratory.

After a relevant description of the quantum mechanics and theoretical atomic physics concepts and formulas involved in this subject, a physically realistic model, based on the square well potential, is developed. Based on this model, the theoretical photodetachment cross section is computed in order to reproduce the qualitative behavior of the experimental photodetachment cross section measured at ALS.

This development, involving programming in Fortran and numerical …

Examining Antarctica From A Geodynamic Perspective: Backstripping, Ice Thickness, Tectonics And Erosion, Travis Gary Hayden

Dissertations

I have applied the principles of basin analysis and geodynamics to several cores recovered from on or near the Antarctic continent to answer 2 independent questions about the tectonic evolution of Antarctica; as well as estimate the thickness of the Antarctic Ice Sheet at the Last Glacial Maximum.

I developed, and applied a modification of the backstripping modeling technique to compensate for the loading and erosion of glacial ice at the AND-1B site by combining a backstripping driven inverse model, with a driven ice-load model. This modification allowed me to identify and constrain the timing of major pulses of subsidence …

"Integration Of Math And Music In The Secondary Classroom", Brian O'Neill

Honors Theses

The disciplines of mathematics and music seem worlds apart at first glance. Harmonious connections can inevitably be created if a deeper appreciation is lent to these stereotypically dissimilar subjects. "Integration of Mathematics and Music in the Secondary Classroom" is a quadratic function unit that utilizes music to aid in teaching mathematical concepts. The unit consists of a compilation of traditional rote mathematics and three main inquiry lessons: Problems Without Polyrhythm, Ma-Thematics, and The Undertones of Overtones. The unique approach of inquiry allows students to construct meaningful learning through a curriculum that is driven by their own mathematical questions. In addition, …

Co And Cr Adsorption On Maghemite, Quartz, And Maghemite-Quartz Mixtures, Amy Troy

Honors Theses

In aquifers and other natural systems, single mineral systems are rare. Solids are commonly heterogeneous, containing multiple minerals, and mineral interactions are expected. Mineral interactions such as formation of coatings and physical blocking of adsorption sites have the potential to significantly change the adsorption of ions onto solids. To investigate such interactions, batch experiments using Co(II) or Cr(VI) were conducted to compare adsorption edges of these sorbates on pure and mixed mineral systems. Specifically, sorption of 10^-5 or 10^-6 M Co(II) and Cr(VI) was measured as a function of pH, with a background electrolyte concentration of 0.01 M …

The Effects Of Eutrophication And Salinization On Methane Production In Urban And Rural Lakes, Rebecca Kiekhaefer

Honors Theses

Asylum lake is an urban lake in Kalamazoo, Michigan. The lake is located near the intersection of two major roadways which are heavily salted during the winter. Wintergreen lake is a rural lake that is on the property of the Kellogg Biological Station in Augusta, Michigan. The lake is surrounded by the Kellogg Bird Sanctuary and is relatively isolated from major roadways. Both lakes are eutrophic, Asylum lake because of high salinity and lack of turnover (Macleod, et aI., 2011) and Wintergreen lake because of high nutrient inputs (Threlkeld, 1979). Previous work suggests that road salt deicers can change the …

Audience Response Clicker Project, Joseph Meyer

Honors Theses

This report will address the feasibility of a software-based audience response system to be implemented, to be known as the Clicker Project. The project seeks to address the growing need for active learning environments at the University level. The primary goal of the project is to construct a web-based system that allows presenters to gather responses from a viewing audience. To this end, presenters can collect and store data dynamically form whomever is in attendance. The following sections will discuss the project in greater detail.

Study Of The Insulin Mimetic Sodium Orthovanadate In Glucosamine Induced Insulin Resistnace In Primary Rat Hepatocytes, Kalan Mcpherson

Masters Theses

Insulin resistance and type II diabetes is a disease state characterized by a lack of sensitivity of insulin to provoke a proper response in insulin sensitive tissues. Currently, we utilize glucosamine to increase flux through the Hexosamine Biosynthetic Pathway (HBP) to induce an insulin resistance like state in primary rat hepatocytes. We tested the effectiveness of the insulin mimetic sodium orthovanadate to determine if it could elicit an insulin-like response under these conditions. Mixed results were obtained on the effectiveness of vanadate as an insulin mimetic in this insulin resistant model.

Adsorption Of Hexavalent Chromium On Hydrous Manganese Oxide, Andrew K. Macleod

Masters Theses

Hexavalent chromium is a very common contaminant most often associated with industrial processes, it is quite mobile in the subsurface and a better understanding of its mobility and interactions with soil constituents will help ongoing remediation efforts.

Hydrous manganese oxides (HMO) are a very common soil constituent and thus would be likely to interact with Cr(VI) in contaminated shallow subsurface environments. The goal of this study is to develop a working model that can improve predictions of Cr(VI) mobility in natural systems. A diffuse double layer surface complexation model (DLM) was developed by deriving reaction stoichiometries and stability constants for …

Integrating Depositional Facies And Sequence Stratigraphy In Characterizing Unconventional Reservoirs: Eagle Ford Shale, South Texas, Seth Jordan Workman

Masters Theses

The Mid-to-Late Cretaceous Eagle Ford Shale of South Texas is a mixed siliciclastic/carbonate, unconventional resource play with considerable oil and natural gas. Characterization of Eagle Ford reservoir quality and potential is made difficult by complex, small-scale heterogeneities.

The limited availability of subsurface data constrains previous subsurface Eagle Ford investigations. As a result, the internal variability of depositional facies and reservoir attributes remain poorly understood for these Eagle Ford rocks.

This investigation incorporates a representative group of four Eagle Ford cores, and core data, from within the current play area in order to: 1) determine facies successions, 2) establish a hierarchal …

Analysis Of Depositional Facies And Geological Controls On Reservoir Quality In Lower-Middle Devonian Sylvania Sandstone, Midland County, Michigan, Katherine A. Pollard

Masters Theses

The early-Middle Devonian Sylvania “Sandstone” is considered a target for potential CO₂ geosequestration. In order to develop geostatic models for CO₂ injection simulations, controls on reservoir properties must be addressed. The three objectives of this study involve: 1) develop an overview of depositional lithofacies and their vertical stacking relationships, 2) determine fluid sources and controls of diagenesis (dolomitization and silicification), and 3) examine geological controls on the distribution and character of reservoir facies.

The grossly transgressive Sylvania-Bois Blanc interval is a complex lithologic assemblage. Sylvania “Sandstone” strata transition from high energy, subtidal to lower-intertidal mixed carbonate-siliciclastic facies to …

Late Mississippian (Chesterian) Through Early Pennsylvanian (Atokan) Strata, Michigan Basin, U.S.A., Shannon M. Towne

Masters Theses

Over 2,000 linear feet of core material was analyzed to evaluate the stratigraphy and basin evolution of Carboniferous strata in the Michigan basin. Rock units were evaluated on the basis of lithofacies type, contact relationships, and existing regional geologic interpretations. The recovery of three distinct pollen and spore assemblages from core confirms the timing of deposition during the Late Mississippian Chesterian and Early-Middle Pennsylvanian Morrowan and Atokan regional stages within the Michigan basin.

The deposition of a marine carbonate succession with significant interstratified quartz sandstone occurred during the Chesterian regional stage. The Bayport interval (Bayport Limestone) is composed of seven …

Development And Evaluation Of An Inquiry-Based Unit For Teaching About Paleoclimate And Climate Change, Steven Barone

Masters Theses

The purpose of this action research study is to develop and evaluate a sequence of four lessons for an introductory earth science course taken by future elementary teachers. Action research is a reflective process of data collection and analysis used by teachers to improve their classroom practice. This study’s goal is to produce a series of lessons that align with the course philosophy of student-driven learning through guided-inquiry and are effective at improving students’ understanding of climate change.

Three data sets were used to evaluate the lessons: 1) student knowledge gains on an objective pre- and post-test, 2) students’ self-reported …