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Physical Sciences and Mathematics

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University of Central Florida

2010

Polarization

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Polarization Dependent Two-Photon Absorption Properties Of Chiral Molecules, Carlos Toro Jan 2010

Polarization Dependent Two-Photon Absorption Properties Of Chiral Molecules, Carlos Toro

Electronic Theses and Dissertations

Molecules that are non-superimposable on their mirror image are named chiral or optically active compound. Over the years, molecular chirality has played an essential role in the understanding of fundamental aspects associated the origin of life, drug and food technologies and, asymmetric catalysis, among others. Moreover, most of the groundbreaking discoveries and advances made in this field have happened due to the development of spectroscopic techniques based on the natural asymmetry of the enantiomers and their ability to preferentially absorb right or left polarized light. For instance, circular dichroism (CD), which measures the difference in absorption between these two states …


Near-Field Optical Interactions And Applications, David Haefner Jan 2010

Near-Field Optical Interactions And Applications, David Haefner

Electronic Theses and Dissertations

The propagation symmetry of electromagnetic fields is affected by encounters with material systems. The effects of such interactions, for example, modifications of intensity, phase, polarization, angular spectrum, frequency, etc. can be used to obtain information about the material system. However, the propagation of electromagnetic waves imposes a fundamental limit to the length scales over which the material properties can be observed. In the realm of near-field optics, this limitation is overcome only through a secondary interaction that couples the high-spatial-frequency (but non-propagating) field components to propagating waves that can be detected. The available information depends intrinsically on this secondary interaction, …