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Vertical Field Switching Blue Phase Liquid Crystals For Field Sequential Color Displays, Hui-Chuan Cheng
Vertical Field Switching Blue Phase Liquid Crystals For Field Sequential Color Displays, Hui-Chuan Cheng
Electronic Theses and Dissertations
Low power consumption is a critical requirement for all liquid crystal display (LCD) devices. A field sequential color (FSC) LCD was proposed by using red (R), green (G) and blue (B) LEDs and removing the lossy component of color filters which only transmits ~30% of the incoming white light. Without color filters, FSC LCDs exhibit a ~3X higher optical efficiency and 3X higher resolution density as compared to the conventional color filters-based LCDs. However, color breakup (CBU) is a most disturbing defect that degrades the image quality in FSC displays. CBU can be observed in stationary or moving images. It …
Role Of Internal Degrees Of Freedom In The Quantum Tunneling Of The Magnetization In Single-Molecule Magnets, Hajrah Quddusi
Role Of Internal Degrees Of Freedom In The Quantum Tunneling Of The Magnetization In Single-Molecule Magnets, Hajrah Quddusi
Electronic Theses and Dissertations
The prominent features of single molecule magnets (SMMs), such as the quantum tunneling of the magnetization (QTM), are conventionally understood through the giant spin approximation (GSA) which considers the molecule as a single rigid spin. This model often requires the inclusion of high order anisotropy terms in the Hamiltonian, a manifestation of admixing of low lying excited states that can be more naturally understood by employing a multi-spin (MS) description i.e. considering the individual spins and the interactions between ions within the molecule. However, solving the MS Hamiltonian for high nuclearity molecules is not feasible due to the enormous dimensions …
Computational Methods For Analyzing Rna Folding Landscapes And Its Applications, Yuan Li
Computational Methods For Analyzing Rna Folding Landscapes And Its Applications, Yuan Li
Electronic Theses and Dissertations
Non-protein-coding RNAs play critical regulatory roles in cellular life. Many ncRNAs fold into specific structures in order to perform their biological functions. Some of the RNAs, such as riboswitches, can even fold into alternative structural conformations in order to participate in different biological processes. In addition, these RNAs can transit dynamically between different functional structures along folding pathways on their energy landscapes. These alternative functional structures are usually energetically favored and are stable in their local energy landscapes. Moreover, conformational transitions between any pair of alternate structures usually involve high energy barriers, such that RNAs can become kinetically trapped by …
Investigation Of Breakdown Power During Electrical Breakdown Of Aligned Array Of Carbon Nanotubes, Udai Bhanu
Investigation Of Breakdown Power During Electrical Breakdown Of Aligned Array Of Carbon Nanotubes, Udai Bhanu
Electronic Theses and Dissertations
Massively parallel arrays of single walled carbon nanotubes (SWNT) have attracted significant research interests because of their ability to (i) average out inhomogeneities of individual SWNTs, (ii) provide larger on currents, and (iii) reduce noise to provide higher cutoff frequency for radio frequency applications. However, the array contains both metallic and semiconducting SWNTs and the presence of metallic nanotube in an aligned array negatively affects the device properties. Therefore, it is essential to selectively remove metallic nanotubes to obtain better transistor properties. It was recently found that although such a selective removal can be effective for a low density array, …
Use Of An Activated Magnesium/Cosolvent System For The Desorption And Degradation Of Polycyclic Aromatic Hydrocarbons And Their Oxygenated Derivatives In Contaminated Soils, Marc Elie
Electronic Theses and Dissertations
The contamination of soils, with polycyclic aromatic hydrocarbons (PAHs), remains a widespread environmental concern. In the past two decades, many physical, chemical and biological methods have been developed and evaluated for the degradation of PAHs. However, due to their low aqueous solubility, high sorption affinity, hydrophobicity and recalcitrance, the environmental remediation of PAHs in soil continues to be economically challenging. In addition to PAH contamination, the presence of oxygenated derivatives of PAHs (OPAHs), in soils, has increasingly become a concern due to their greater toxic properties compared to parent PAH compounds. To date, no investigations on OPAH-remediation methods have been …
Photochemistry And Applications Of Diels-Alder Adducts And Photoacids In Materials Science, Valentine Johns
Photochemistry And Applications Of Diels-Alder Adducts And Photoacids In Materials Science, Valentine Johns
Electronic Theses and Dissertations
In chapter I Photo-retro-Diels-Alder (PrDA) reactions of a variety of Diels Alder (DA) adducts were studied. Experimental results showed that the photoreactivity (quantum yield) depends on the electron-donating ability of the diene component and the electronwithdrawing ability of the dienophile component. The mechanism was studied by trapping the reaction intermediate, O2 quenching and femtosecond time-resolved absorption spectroscopy. All the results support a mechanism that involves a charge-separated intermediate generated from a singlet excited state. The PrDA reaction may find applications in photoresponsive materials, photolithography, drug delivery and mechanistic research. Chapter II shows two applications of the PrDA reaction. The first, …
Non-Reciprocal Wave Transmission In Integrated Waveguide Array Isolators, Tony Yatming Ho
Non-Reciprocal Wave Transmission In Integrated Waveguide Array Isolators, Tony Yatming Ho
Electronic Theses and Dissertations
Non-reciprocal wave transmission is a phenomenon witnessed in certain photonic devices when the wave propagation dynamics through the device along one direction differs greatly from the dynamics along the counter-propagating direction. Specifically, it refers to significant power transfer occurring in one direction, and greatly reduced power transfer in the opposite direction. The resulting effect is to isolate the directionality of wave propagation, allowing transmission to occur along one direction only. Given the popularity of photonic integrated circuits (PIC), in which all the optical components are fabricated on the same chip so that the entire optical system can be made more …
First Principles Studies Of Pattern Formations And Reactions On Catalyst Surfaces, Duy Le
First Principles Studies Of Pattern Formations And Reactions On Catalyst Surfaces, Duy Le
Electronic Theses and Dissertations
This dissertation undertakes theoretical research into the adsorption, pattern formation, and reactions of atoms, molecules, and layered materials on catalyst surfaces. These investigations are carried out from first-principles calculations of electronic and geometric structures using density functional theory (DFT) for predictions and simulations at the atomic scale. The results should be useful for further study of the catalytic activities of materials and for engineering functional nanostructures. The first part of the dissertation focuses on systematic first-principles simulations of the energetic pathways of CO oxidation on the Cu2O(100) surface. These simulations show CO to oxidize spontaneously on the O-terminated Cu2O(100) surface …
State (Hydrodynamics) Identification In The Lower St. Johns River Using The Ensemble Kalman Filter, Hitoshi Tamura
State (Hydrodynamics) Identification In The Lower St. Johns River Using The Ensemble Kalman Filter, Hitoshi Tamura
Electronic Theses and Dissertations
This thesis presents a method, Ensemble Kalman Filter (EnKF), applied to a highresolution, shallow water equations model (DG ADCIRC-2DDI) of the Lower St. Johns River with observation data at four gauging stations. EnKF, a sequential data assimilation method for non-linear problems, is developed for tidal flow simulation for estimation of state variables, i.e., water levels and depth-integrated currents for overland unstructured finite element meshes. The shallow water equations model is combined with observation data, which provides the basis of the EnKF applications. In this thesis, EnKF is incorporated into DG ADCIRC-2DDI code to estimate the state variables. Upon its development, …
Turtle Cam: Live Multimedia Interaction For Engaging Potential Visitor Population To Canaveral National Seashore, Brian Alfred Tortorelli
Turtle Cam: Live Multimedia Interaction For Engaging Potential Visitor Population To Canaveral National Seashore, Brian Alfred Tortorelli
Electronic Theses and Dissertations
This project expands the outreach of the Canaveral National Seashore to its visitors, potential visitors, and virtual visitors through its goals in conservancy and preservation of its natural resources. This paper is involved with the current iteration of a series of digital media projects, the Sea Turtle Nest Camera, also known as, Turtle Cam. It details how and why this project was designed to be an ongoing initiative to assist in those goals.
Hfs Plus File System Exposition And Forensics, Scott Ware
Hfs Plus File System Exposition And Forensics, Scott Ware
Electronic Theses and Dissertations
The Macintosh Hierarchical File System Plus, HFS +, or as it is commonly referred to as the Mac Operating System, OS, Extended, was introduced in 1998 with Mac OS X 8.1. HFS+ is an update to HFS, Mac OS Standard format that offers more efficient use of disk space, implements international friendly file names, future support for named forks, and facilitates booting on non-Mac OS operating systems through different partition schemes. The HFS+ file system is efficient, yet, complex. It makes use of B-trees to implement key data structures for maintaining meta-data about folders, files, and data. The implementation of …
Injection-Locked Semiconductor Lasers For Realization Of Novel Rf Photonics Components, Nazanin Hoghooghi
Injection-Locked Semiconductor Lasers For Realization Of Novel Rf Photonics Components, Nazanin Hoghooghi
Electronic Theses and Dissertations
This dissertation details the work has been done on a novel resonant cavity linear interferometric modulator and a direct phase detector with channel filtering capability using injection-locked semiconductor lasers for applications in RF photonics. First, examples of optical systems whose performance can be greatly enhanced by using a linear intensity modulator are presented and existing linearized modulator designs are reviewed. The novel linear interferometric optical intensity modulator based on an injection-locked laser as an arcsine phase modulator is introduced and followed by numerical simulations of the phase and amplitude response of an injection-locked semiconductor laser. The numerical model is then …
Third Order Nonlinearity Of Organic Molecules, Honghua Hu
Third Order Nonlinearity Of Organic Molecules, Honghua Hu
Electronic Theses and Dissertations
The main goal of this dissertation is to investigate the third-order nonlinearity of organic molecules. This topic contains two aspects: two-photon absorption (2PA) and nonlinear refraction (NLR), which are associated with the imaginary and real part of the third-order nonlinearity (χ (3)) of the material, respectively. With the optical properties tailored through meticulous molecular structure engineering, organic molecules are promising candidates to exhibit large third-order nonlinearities. Both linear (absorption, fluorescence, fluorescence excitation anisotropy) and nonlinear (Z-scan, two-photon fluorescence, pump-probe) techniques are described and utilized to fully characterize the spectroscopic properties of organic molecules in solution or solid-state form. These properties …
On Hall Magnetohydrodynamics: X-Type Neutral Point And Parker Problem, Kyle Reger
On Hall Magnetohydrodynamics: X-Type Neutral Point And Parker Problem, Kyle Reger
Electronic Theses and Dissertations
The framework for the Hall magnetohydrodynamic (MHD) model for plasma physics is built up from kinetic theory and used to analytically solve problems of interest in the field. The Hall MHD model describes fast magnetic reconnection processes in space and laboratory plasmas. Specifically, the magnetic reconnection process at an X-type neutral point, where current sheets form and store enormous amounts of magnetic energy which is later released as magnetic storms when the sheets break up, is investigated. The phenomena of magnetic flux pile-up driving the merging of antiparallel magnetic fields at an ion stagnation-point flow in a thin current sheet, …
Influence Of Topographic Elevation Error On Modeled Storm Surge, Matthew Bilskie
Influence Of Topographic Elevation Error On Modeled Storm Surge, Matthew Bilskie
Electronic Theses and Dissertations
The following presents a method for determining topographic elevation error for overland unstructured finite element meshes derived from bare earth LiDAR for use in a shallow water equations model. This thesis investigates the development of an optimal interpolation method to produce minimal error for a given element size. In hydrodynamic studies, it is vital to represent the floodplain as accurately as possible since terrain is a critical factor that influences water flow. An essential step in the development of a coastal inundation model is processing and resampling dense bare earth LiDAR to a DEM and ultimately to the mesh nodes; …
Detecting And Characterizing Exoplanets: The Gj 436 And Hd 149026 Systems, Kevin Stevenson
Detecting And Characterizing Exoplanets: The Gj 436 And Hd 149026 Systems, Kevin Stevenson
Electronic Theses and Dissertations
This dissertation investigates two stellar systems known to contain extrasolar planets. It is comprised of five chapters that are readily divided into three independent but related analyses. Chapter 1 reports on the analysis of low signal-to-noise secondary-eclipse observations of the Neptune-sized exoplanet GJ 436b using the Spitzer Space Telescope in multiple infrared channels. The measured wavelength-dependent eclipse depths provide constraints on the planet’s dayside atmospheric composition and thermal profile. The analysis indicates that GJ 436b’s atmosphere is abundant in carbon monoxide and deficient in methane relative to thermochemical equilibrium models for the predicted hydrogen-dominated atmosphere. Chapter 2 discusses the techniques …
Autoregressive Models, Kelly Wade
Autoregressive Models, Kelly Wade
Electronic Theses and Dissertations
Consider a sequence of random variables which obeys a first order autoregressive model with unknown parameter alpha. Under suitable assumptions on the error structure of the model, the limiting distribution of the normalized least squares estimator of alpha is discussed. The choice of the normalizing constant depends on whether alpha is less than one, equals one, or is greater than one in absolute value. In particular, the limiting distribution is normal provided that the absolute value of alpha is less than one, but is a function of Brownian motion whenever the absolute value of alpha equals one. Some general remarks …
An Assessment Of Ecological Processes In The Apalachicola Estuarine System, Florida, Daina Smar
An Assessment Of Ecological Processes In The Apalachicola Estuarine System, Florida, Daina Smar
Electronic Theses and Dissertations
The following is a compilation of field data collected in 2011 and 2012 in Apalachicola, FL as part of a five year study assessing the ecological effects of sea level rise in the northern Gulf of Mexico. Many coastal communities, both natural and developed, will soon be working to mitigate the effects of sea level rise, if they are not already doing so. This thesis investigates the natural patterns of the Apalachicola estuarine system through the collection and analysis of in situ water, sediment, and biomass samples. Additionally, results of the field samples are presented and recommendations for additional sampling …
Online Path Planning And Control Solution For A Coordinated Attack Of Multiple Unmanned Aerial Vehicles In A Dynamic Environment, Juan Vega-Nevarez
Online Path Planning And Control Solution For A Coordinated Attack Of Multiple Unmanned Aerial Vehicles In A Dynamic Environment, Juan Vega-Nevarez
Electronic Theses and Dissertations
The role of the unmanned aerial vehicle (UAV) has significantly expanded in the military sector during the last decades mainly due to their cost effectiveness and their ability to eliminate the human life risk. Current UAV technology supports a variety of missions and extensive research and development is being performed to further expand its capabilities. One particular field of interest is the area of the low cost expendable UAV since its small price tag makes it an attractive solution for target suppression. A swarm of these low cost UAVs can be utilized as guided munitions or kamikaze UAVs to attack …
Convective Heat Transfer In Nanofluids, Steven Schraudner
Convective Heat Transfer In Nanofluids, Steven Schraudner
Electronic Theses and Dissertations
In recent years, the study of fluid flow with nanoparticles in base fluids has attracted the attention of several researchers due to its various applications to science and engineering problems. Recent investigations on convective heat transfer in nanofluids indicate that the suspended nanoparticles markedly change the transport properties and thereby the heat transfer characteristics. Convection in saturated porous media with nanofluids is also an area of growing interest. In this thesis, we study the effects of radiation on the heat and mass transfer characteristics of nanofluid flows over solid surfaces. In Chapter 2, an investigation is made into the effects …
Improving Student Learning In Undergraduate Mathematics, Gabrielle Rejniak
Improving Student Learning In Undergraduate Mathematics, Gabrielle Rejniak
Electronic Theses and Dissertations
The goal of this study was to investigate ways of improving student learning, par- ticularly conceptual understanding, in undergraduate mathematics courses. This study focused on two areas: course design and animation. The methods of study were the following: Assessing the improvement of student conceptual understanding as a result of team project-based learning, individual inquiry-based learning and the modi ed empo- rium model; and Assessing the impact of animated videos on student learning with the emphasis on concepts. For the first part of our study (impact of course design on student conceptual understanding) we began by comparing the following three groups …
Towards Evolving More Brain-Like Artificial Neural Networks, Sebastian Risi
Towards Evolving More Brain-Like Artificial Neural Networks, Sebastian Risi
Electronic Theses and Dissertations
An ambitious long-term goal for neuroevolution, which studies how artificial evolutionary processes can be driven to produce brain-like structures, is to evolve neurocontrollers with a high density of neurons and connections that can adapt and learn from past experience. Yet while neuroevolution has produced successful results in a variety of domains, the scale of natural brains remains far beyond reach. In this dissertation two extensions to the recently introduced Hypercube-based NeuroEvolution of Augmenting Topologies (HyperNEAT) approach are presented that are a step towards more brain-like artificial neural networks (ANNs). First, HyperNEAT is extended to evolve plastic ANNs that can learn …
Networking And Security Solutions For Vanet Initial Deployment Stage, Baber Aslam
Networking And Security Solutions For Vanet Initial Deployment Stage, Baber Aslam
Electronic Theses and Dissertations
Vehicular ad hoc network (VANET) is a special case of mobile networks, where vehicles equipped with computing/communicating devices (called "smart vehicles") are the mobile wireless nodes. However, the movement pattern of these mobile wireless nodes is no more random, as in case of mobile networks, rather it is restricted to roads and streets. Vehicular networks have hybrid architecture; it is a combination of both infrastructure and infrastructure-less architectures. The direct vehicle to vehicle (V2V) communication is infrastructure-less or ad hoc in nature. Here the vehicles traveling within communication range of each other form an ad hoc network. On the other …
Submillisecond-Response Blue Phase Liquid Crystals For Display Applications, Kuan Ming Chen
Submillisecond-Response Blue Phase Liquid Crystals For Display Applications, Kuan Ming Chen
Electronic Theses and Dissertations
With exploding growth of information exchanges between people, display has become indispensable in our daily lives. After decades of intensive research and development in materials and devices, and massive investment in manufacturing technologies, liquid crystal display (LCD) has overcome various obstacles and achieved the performance we need, such as wide viewing angle, high contrast ratio, and high resolution, etc. These excellent performances make LCD prevailed in every perspective. Recently, with the demands of energy conservation, a greener LCD with lower power consumption is desired. In order to achieve this goal, new energy-effective driving methods, such as field sequential color display, …
Setpad: A Sketch-Based Tool For Exploring Discrete Math Set Problems, Travis Cossairt
Setpad: A Sketch-Based Tool For Exploring Discrete Math Set Problems, Travis Cossairt
Electronic Theses and Dissertations
We present SetPad, a new application prototype that lets computer science students explore discrete math problems by sketching set expressions using pen-based input. Students can manipulate the expressions interactively with the tool via pen or multi-touch interface. Likewise, discrete mathematics instructors can use SetPad to display and work through set problems via a projector to better demonstrate the solutions to the students. We discuss the implementation and feature set of the application, as well as results from both an informal perceived usefulness evaluation for students taking a computer science foundation exam in addition to a formal user study measuring the …
Characterization Of Online Archives Of Astronomical Imaging Vis-A-Vis Serendipitous Asteroids, And Their Astrometric Properties, Jean Marc Denis
Characterization Of Online Archives Of Astronomical Imaging Vis-A-Vis Serendipitous Asteroids, And Their Astrometric Properties, Jean Marc Denis
Electronic Theses and Dissertations
The identification of known asteroids on existing CCD pictures would allow us to obtain accurate astrometric and photometric asteroid properties. Some asteroids might have ambiguous orbital elements, thus their identification along with their exact positions on multiple picture frames could significantly improve their orbital elements. Furthermore, the possibility of identifying known asteroids on older pictures, sometimes preceding their discovery date, might allow the study of non-gravitational effects like the Yarkovsky effect. Identifying a potential Yarkovsky effect on asteroids is challenging because it is extremely weak. However, this effect cumulates with time, therefore, it is necessary to find astronomical pictures that …
High-Efficiency Blue Phase Liquid Crystal Displays, Yan Li
High-Efficiency Blue Phase Liquid Crystal Displays, Yan Li
Electronic Theses and Dissertations
Blue phase liquid crystals (BPLCs) have a delicate lattice structure existing between chiral nematic and isotropic phases, with a stable temperature range of about 2 K. But due to short coherent length, these self-assembled nano-structured BPLCs have a fast response time. In the past three decades, the application of BPLC has been rather limited because of its narrow temperature range. In 2002, Kikuchi et al. developed a polymer stabilization method to extend the blue-phase temperature range to more than 60 K. This opens a new gateway for display and photonic applications. In this dissertation, I investigate the material properties of …
Structure, Stability, Vibrational, Thermodynamic, And Catalytic Properties Of Metal Nanostructures: Size, Shape, Support, And Adsorbate Effects, Farzad Behafarid
Structure, Stability, Vibrational, Thermodynamic, And Catalytic Properties Of Metal Nanostructures: Size, Shape, Support, And Adsorbate Effects, Farzad Behafarid
Electronic Theses and Dissertations
Recent advances in nanoscience and technology have provided the scientific community with new exciting opportunities to rationally design and fabricate materials at the nanometer scale with drastically different properties as compared to their bulk counterparts. A variety of challenges related to nanoparticle (NP) synthesis and materials characterization have been tackled , allowing us to make more homogenous, well defined, size- and shape-selected NPs, and to probe deeper and more comprehensively into their distinct properties. In this dissertation, a variety of phenomena relevant to nanosized materials are investigated, including the thermal stability of NPs and coarsening phenomena in different environments, the …
The Effect Of Carbon Nanotube/Organic Semiconductor Interfacial Area On The Performance Of Organic Transistors, Narae Kang
Electronic Theses and Dissertations
Organic field-effect transistors (OFETs) have attracted tremendous attention due to their flexibility, transparency, easy processiblity and low cost of fabrication. High-performance OFETs are required for their potential applications in the organic electronic devices such as flexible display, integrated circuit, and radiofrequency identification tags. One of the major limiting factors in fabricating high-performance OFET is the large interfacial barrier between metal electrodes and OSC which results in low charge injection from the metal electrodes to OSC. In order to overcome the challenge of low charge injection, carbon nanotubes (CNTs) have been suggested as a promising electrode material for organic electronic devices. …
Laser Filamentation Interaction With Materials For Spectroscopic Applications, Matthew Weidman
Laser Filamentation Interaction With Materials For Spectroscopic Applications, Matthew Weidman
Electronic Theses and Dissertations
Laser filamentation is a non-diffracting propagation regime consisting of an intense core that is surrounded by an energy reservoir. For laser ablation based spectroscopy techniques such as Laser Induced Breakdown Spectroscopy (LIBS), laser filamentation enables the remote delivery of high power density laser radiation at long distances. This work shows a quasiconstant filament-induced mass ablation along a 35 m propagation distance. The mass ablated is sufficient for the application of laser filamentation as a sampling tool for plasma based spectroscopy techniques. Within the scope of this study, single-shot ablation was compared with multi-shot ablation. The dependence of ablated mass on …